Vibrational And Electronic Energy Levels Of Polyatomic Transient Molecules PDF Download

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Patterns of Energy Levels and Spectra for Polyatomic Molecules

Patterns of Energy Levels and Spectra for Polyatomic Molecules
Author:
Publisher:
Total Pages:
Release: 1983
Genre:
ISBN:

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Laser spectroscopy has revealed a remarkable intricacy in the rotational, vibrational, and electronic energy levels for polyatomic molecules. The infrared spectra of SF6, CF4, and related molecules contain several levels of structure on top of structure which resembles a fractal in some ways. The purpose of this article will be to exhibit some of this structure and introduce the simplest theoretical interpretations of it which are presently available.


Spectra of Atoms and Molecules

Spectra of Atoms and Molecules
Author: Peter F. Bernath
Publisher: Oxford University Press, USA
Total Pages: 542
Release: 2020
Genre: Science
ISBN: 0190095407

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"This book is designed as a textbook to introduce advanced undergraduates and, particularly, new graduate students to the vast field of spectroscopy. It presumes that the student is familiar with the material in an undergraduate course in quantum mechanics. I have taken great care to review the relevant mathematics and quantum mechanics as needed throughout the book. Considerable detail is provided on the origin of spectroscopic principles. My goal is to demystify spectroscopy by showing the necessary steps in a derivation, as appropriate in a textbook. The digital computer has permeated all of science including spectroscopy. The application of simple analytical formulas and the nonstatistical graphical treatment of data are long dead. Modern spectroscopy is based on the matrix approach to quantum mechanics. Real spectroscopic problems can be solved on the computer more easily if they are formulated in terms of matrix operations rather than di erential equations. I have tried to convey the spirit of modern spectroscopy, through the extensive use of the language of matrices"--


Energy Levels of Polyatomic Molecules. Part One

Energy Levels of Polyatomic Molecules. Part One
Author: G. Amat
Publisher:
Total Pages: 84
Release: 1966
Genre:
ISBN:

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The rotation-vibration energies of polyatomic molecules were computed to the fourth order of approximation. These energies are used to obtain the frequencies of lines in rotation and rotation-vibration spectra. Such very accurate calculations are necessary in order to explain many effects observed in very high resolution spectra. The following topics are emphasized: the quartic anharmonic potential function; the rotation spectrum of axially symmetric molecules in an excited vibrational state; the rotation-vibration spectra of spherical top molecules; anomalous rotational structure of level 03(1)1 in the rotation-vibration spectrum of C(13) O2(16); rotational structure of the fundamental NU6 of methyl cyanide; a general discussion of Fermi resonance in CO2 with a new assignment of vibrational levels. (Author).