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Transport Processes in Chemically Reacting Flow Systems

Transport Processes in Chemically Reacting Flow Systems
Author: Daniel E. Rosner
Publisher: Butterworth-Heinemann
Total Pages: 571
Release: 2013-10-22
Genre: Technology & Engineering
ISBN: 1483162680

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Transport Processes in Chemically Reacting Flow Systems discusses the role, in chemically reacting flow systems, of transport processes—particularly the transport of momentum, energy, and (chemical species) mass in fluids (gases and liquids). The principles developed and often illustrated here for combustion systems are important not only for the rational design and development of engineering equipment (e.g., chemical reactors, heat exchangers, mass exchangers) but also for scientific research involving coupled transport processes and chemical reaction in flow systems. The book begins with an introduction to transport processes in chemically reactive systems. Separate chapters cover momentum, energy, and mass transport. These chapters develop, state, and exploit useful quantitative ""analogies"" between these transport phenomena, including interrelationships that remain valid even in the presence of homogeneous or heterogeneous chemical reactions. A separate chapter covers the use of transport theory in the systematization and generalization of experimental data on chemically reacting systems. The principles and methods discussed are then applied to the preliminary design of a heat exchanger for extracting power from the products of combustion in a stationary (fossil-fuel-fired) power plant. The book has been written in such a way as to be accessible to students and practicing scientists whose background has until now been confined to physical chemistry, classical physics, and/or applied mathematics.


Chemically Reacting Flow

Chemically Reacting Flow
Author: Robert J. Kee
Publisher: John Wiley & Sons
Total Pages: 884
Release: 2005-02-18
Genre: Science
ISBN: 047146130X

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Complex chemically reacting flow simulations are commonly employed to develop quantitative understanding and to optimize reaction conditions in systems such as combustion, catalysis, chemical vapor deposition, and other chemical processes. Although reaction conditions, geometries, and fluid flow can vary widely among the applications of chemically reacting flows, all applications share a need for accurate, detailed descriptions of the chemical kinetics occurring in the gas-phase or on reactive surfaces. Chemically Reacting Flow: Theory and Practice combines fundamental concepts in fluid mechanics and physical chemistry, assisting the student and practicing researcher in developing analytical and simulation skills that are useful and extendable for solving real-world engineering problems. The first several chapters introduce transport processes, primarily from a fluid-mechanics point of view, incorporating computational simulation from the outset. The middle section targets physical chemistry topics that are required to develop chemically reacting flow simulations, such as chemical thermodynamics, molecular transport, chemical rate theories, and reaction mechanisms. The final chapters deal with complex chemically reacting flow simulations, emphasizing combustion and materials processing. Among other features, Chemically Reacting Flow: Theory and Practice: -Advances a comprehensive approach to interweaving the fundamentals of chemical kinetics and fluid mechanics -Embraces computational simulation, equipping the reader with effective, practical tools for solving real-world problems -Emphasizes physical fundamentals, enabling the analyst to understand how reacting flow simulations achieve their results -Provides a valuable resource for scientists and engineers who use Chemkin or similar software Computer simulation of reactive systems is highly effective in the development, enhancement, and optimization of chemical processes. Chemically Reacting Flow helps prepare both students and professionals to take practical advantage of this powerful capability.


Chemically Reacting Flow

Chemically Reacting Flow
Author: Robert J. Kee
Publisher: John Wiley & Sons
Total Pages: 1013
Release: 2017-09-27
Genre: Science
ISBN: 1119186293

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A guide to the theoretical underpinnings and practical applications of chemically reacting flow Chemically Reacting Flow: Theory, Modeling, and Simulation, Second Edition combines fundamental concepts in fluid mechanics and physical chemistry while helping students and professionals to develop the analytical and simulation skills needed to solve real-world engineering problems. The authors clearly explain the theoretical and computational building blocks enabling readers to extend the approaches described to related or entirely new applications. New to this Second Edition are substantially revised and reorganized coverage of topics treated in the first edition. New material in the book includes two important areas of active research: reactive porous-media flows and electrochemical kinetics. These topics create bridges between traditional fluid-flow simulation approaches and transport within porous-media electrochemical systems. The first half of the book is devoted to multicomponent fluid-mechanical fundamentals. In the second half the authors provide the necessary fundamental background needed to couple reaction chemistry into complex reacting-flow models. Coverage of such topics is presented in self-contained chapters, allowing a great deal of flexibility in course curriculum design. • Features new chapters on reactive porous-media flow, electrochemistry, chemical thermodynamics, transport properties, and solving differential equations in MATLAB • Provides the theoretical underpinnings and practical applications of chemically reacting flow • Emphasizes fundamentals, allowing the analyst to understand fundamental theory underlying reacting-flow simulations • Helps readers to acquire greater facility in the derivation and solution of conservation equations in new or unusual circumstances • Reorganized to facilitate use as a class text and now including a solutions manual for academic adopters Computer simulation of reactive systems is highly efficient and cost-effective in the development, enhancement, and optimization of chemical processes. Chemically Reacting Flow: Theory, Modeling, and Simulation, Second Edition helps prepare graduate students in mechanical or chemical engineering, as well as research professionals in those fields take utmost advantage of that powerful capability.


Non-Equilibrium Reacting Gas Flows

Non-Equilibrium Reacting Gas Flows
Author: Ekaterina Nagnibeda
Publisher: Springer Science & Business Media
Total Pages: 255
Release: 2009-07-09
Genre: Technology & Engineering
ISBN: 3642013902

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In the present monograph, we develop the kinetic theory of transport phenomena and relaxation processes in the flows of reacting gas mixtures and discuss its applications to strongly non-equilibrium conditions. The main attention is focused on the influence of non-equilibrium kinetics on gas dynamics and transport properties. Closed systems of fluid dynamic equations are derived from the kinetic equations in different approaches. We consider the most accurate approach taking into account the state-to-state kinetics in a flow, as well as simplified multi-temperature and one-temperature models based on quasi-stationary distributions. Within these approaches, we propose the algorithms for the calculation of the transport coefficients and rate coefficients of chemical reactions and energy exchanges in non-equilibrium flows; the developed techniques are based on the fundamental kinetic theory principles. The theory is applied to the modeling of non-equilibrium flows behind strong shock waves, in the boundary layer, and in nozzles. The comparison of the results obtained within the frame of different approaches is presented, the advantages of the new state-to-state kinetic model are discussed, and the limits of validity for simplified models are established. The book can be interesting for scientists and graduate students working on physical gas dynamics, aerothermodynamics, heat and mass transfer, non-equilibrium physical-chemical kinetics, and kinetic theory of gases.


Chemical And Biological Processes In Fluid Flows: A Dynamical Systems Approach

Chemical And Biological Processes In Fluid Flows: A Dynamical Systems Approach
Author: Zoltan Neufeld
Publisher: World Scientific
Total Pages: 305
Release: 2009-09-29
Genre: Science
ISBN: 1908979488

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Many chemical and biological processes take place in fluid environments in constant motion — chemical reactions in the atmosphere, biological population dynamics in the ocean, chemical reactors, combustion, and microfluidic devices. Applications of concepts from the field of nonlinear dynamical systems have led to significant progress over the last decade in the theoretical understanding of complex phenomena observed in such systems.This book introduces the theoretical approaches for describing mixing and transport in fluid flows. It reviews the basic concepts of dynamical phenomena arising from the nonlinear interactions in chemical and biological systems. The coverage includes a comprehensive overview of recent results on the effect of mixing on spatial structure and the dynamics of chemically and biologically active components in fluid flows, in particular oceanic plankton dynamics./a


Transport Phenomena and Interfacial Kinetics in Multiphase Combustion Systems

Transport Phenomena and Interfacial Kinetics in Multiphase Combustion Systems
Author: Daniel E. Rosner
Publisher:
Total Pages: 11
Release: 1987
Genre:
ISBN:

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This annual report summarizes Yale High Temperature Chemical Reaction Engrg. Laboratory research methods/results (Grant AFOSR 84-0034) for the ca one-year period ending 12/31/86. Our techniques and results are outlined in phoretic diffusitives, and vapor and/or particle-deposition rates onto cooled surfaces in combustion gases, (2) role of thermophoresis in the capture of soot particles and the use of this phenomenon to infer both local soot volume fractions and logical gas temperatures, (3) boundary layer computational methods and correlations for thermophoretically-modified vapor and small particle transport, including high mass-loading and dopant redistribution effects, and, (4) use of a micro-wave-induced plasma emission spectroscopic (MIPES) method to follow boron surface gasification kinetics in stream containing oxygen (g). Presentation and archive publications describing these techniques/findings are documented, including the publication of a more comprehensive textbook: Transport Processes in Chemically Reacting Flow Systems (Butter-worths, Stoneham MA) by the Principal Investigator. Keywords: Aerosols, Convective diffusion, Chemical vapor deposition, Energy transfer, Catalysis, Fouling, Soot.


Research Directions in Computational Mechanics

Research Directions in Computational Mechanics
Author: National Research Council
Publisher: National Academies Press
Total Pages: 145
Release: 1991-02-01
Genre: Technology & Engineering
ISBN: 0309046483

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Computational mechanics is a scientific discipline that marries physics, computers, and mathematics to emulate natural physical phenomena. It is a technology that allows scientists to study and predict the performance of various productsâ€"important for research and development in the industrialized world. This book describes current trends and future research directions in computational mechanics in areas where gaps exist in current knowledge and where major advances are crucial to continued technological developments in the United States.