Transition Metals Second Edition PDF Download
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Author | : Monica Halka |
Publisher | : Infobase Holdings, Inc |
Total Pages | : 158 |
Release | : 2019-12-01 |
Genre | : Science |
ISBN | : 1438182139 |
Download Transition Metals, Second Edition Book in PDF, ePub and Kindle
More so than any of the other major groups of elements in the periodic table, the transition metals have shaped human history and have been the workhorses of industry. The discovery of metallic copper ended the Stone Age and ushered in the Bronze Age. Alloys of iron (especially steel) later took over, and the Iron Age replaced the Bronze Age. Copper, silver, and gold—and, more recently, platinum—have been the precious metals from which coins and jewelry have been made from ancient times to the present. Each chapter in the newly updated, full-color Transition Metals, Second Edition discusses a group of elements, including their similarities and differences and current research and applications. Ideal for high school or college students interested in chemistry and physics, this straightforward resource is devoted to the chemical and physical properties of transition metals and how they are useful in everyday life. Some of the transition metals covered include scandium, titanium, manganese, cobalt, and zinc.
Author | : Roderick Bates |
Publisher | : John Wiley & Sons |
Total Pages | : 5 |
Release | : 2012-04-30 |
Genre | : Science |
ISBN | : 1119978939 |
Download Organic Synthesis Using Transition Metals Book in PDF, ePub and Kindle
Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.
Author | : Louis S. Hegedus |
Publisher | : University Science Books |
Total Pages | : 358 |
Release | : 1999 |
Genre | : Science |
ISBN | : 9781891389047 |
Download Transition Metals in the Synthesis of Complex Organic Molecules Book in PDF, ePub and Kindle
This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Author | : Isaac B. Bersuker |
Publisher | : John Wiley & Sons |
Total Pages | : 658 |
Release | : 2010-12-01 |
Genre | : Science |
ISBN | : 0470920858 |
Download Electronic Structure and Properties of Transition Metal Compounds Book in PDF, ePub and Kindle
With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications. Including ~70 Example-Boxes and summary notes, questions, exercises, problem sets, and illustrations in each chapter, this publication is also suitable for use as a textbook for advanced undergraduate and graduate students. Novel material is introduced in description of multi-orbital chemical bonding, spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems. This is an excellent reference for chemists, researchers and teachers, and advanced undergraduate and graduate students in inorganic, coordination, and organometallic chemistry.
Author | : Robert H. Crabtree |
Publisher | : John Wiley & Sons |
Total Pages | : 600 |
Release | : 2005-06-14 |
Genre | : Science |
ISBN | : 0471718750 |
Download The Organometallic Chemistry of the Transition Metals Book in PDF, ePub and Kindle
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Author | : Ralph G. Wilkins |
Publisher | : Wiley-VCH |
Total Pages | : 480 |
Release | : 1991-08-28 |
Genre | : Science |
ISBN | : 9783527282531 |
Download Kinetics and Mechanism of Reactions of Transition Metal Complexes Book in PDF, ePub and Kindle
This thoroughly revised and updated edition of one of the classics of kinetics text books continues the successful concept of the 1974 edition: In its first part, a simplified approach to the determination of rate laws and mechnisms is given steadily working up to complex situations. In the following chapters the principles developed there are extensively used in a comprehensive account of reactions of transition metal complexes, including reactions of biological signifacance. The text is illustrated by numerous figures and tables. Points of further interest are highlighted in special insets. 140 problems, taken from the original literature, enable the student to apply and deepen his newly acquired knowledge and make the book highly useful for courses in inorganic and organometallic reaction mechanisms. Furthermore, a wealth of over 1700 references renders it an indispensable work for the active researcher.
Author | : Ray Hoff |
Publisher | : John Wiley & Sons |
Total Pages | : 696 |
Release | : 2018-05-08 |
Genre | : Technology & Engineering |
ISBN | : 1119242134 |
Download Handbook of Transition Metal Polymerization Catalysts Book in PDF, ePub and Kindle
Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
Author | : Roderick Bates |
Publisher | : John Wiley & Sons |
Total Pages | : 5 |
Release | : 2012-04-12 |
Genre | : Science |
ISBN | : 1118313666 |
Download Organic Synthesis Using Transition Metals Book in PDF, ePub and Kindle
Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.
Author | : Paul J. Dyson |
Publisher | : CRC Press |
Total Pages | : 190 |
Release | : 2000-11-17 |
Genre | : Science |
ISBN | : 9789056992897 |
Download Transition Metal Carbonyl Cluster Chemistry Book in PDF, ePub and Kindle
Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Author | : Yves Jean |
Publisher | : Oxford University Press |
Total Pages | : 288 |
Release | : 2005-03-24 |
Genre | : Science |
ISBN | : 0198530935 |
Download Molecular Orbitals of Transition Metal Complexes Book in PDF, ePub and Kindle
This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.