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Thermodynamics of the Glassy State

Thermodynamics of the Glassy State
Author: Luca Leuzzi
Publisher: CRC Press
Total Pages: 368
Release: 2007-10-29
Genre: Science
ISBN: 9781420012439

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In the past thirty years, the area of spin glasses has experienced rapid growth, including the development of solvable models for glassy systems. Yet these developments have only been recorded in the original research papers, rather than in a single source. Thermodynamics of the Glassy State presents a comprehensive account of the modern theory of glasses, starting from basic principles (thermodynamics) to the experimental analysis of one of the most important consequences of thermodynamics-Maxwell relations. After a brief introduction to general theoretical concepts and historical developments, the book thoroughly describes glassy phenomenology and the established theory. The core of the book surveys the crucial technique of two-temperature thermodynamics, explains the success of this method in resolving previously paradoxical problems in glasses, and presents exactly solvable models, a physically realistic approach to dynamics with advantages over more established mean field methods. The authors also tackle the potential energy landscape approach and discuss more detailed theories of glassy states, including mode coupling, avoided critical point, replica, and random first order transition theories. This reference lucidly explores recent theoretical advances in the thermodynamics of slowing-aging (glassy) systems. It details the general properties of glassy states while also demonstrating how these properties are present in specific models, enabling readers to thoroughly understand this fundamental yet challenging area of study.


Encyclopedia of Glass Science, Technology, History, and Culture, 2 Volume Set

Encyclopedia of Glass Science, Technology, History, and Culture, 2 Volume Set
Author: Pascal Richet
Publisher: John Wiley & Sons
Total Pages: 1573
Release: 2021-03-16
Genre: Technology & Engineering
ISBN: 1118799429

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A comprehensive and up-to-date encyclopedia to the fabrication, nature, properties, uses, and history of glass The Encyclopedia of Glass Science, Technology, History, and Culture has been designed to satisfy the needs and curiosity of a broad audience interested in the most varied aspects of material that is as old as the universe. As described in over 100 chapters and illustrated with 1100 figures, the practical importance of glass has increased over the ages since it was first man-made four millennia ago. The old-age glass vessels and window and stained glass now coexist with new high-tech products that include for example optical fibers, thin films, metallic, bioactive and hybrid organic-inorganic glasses, amorphous ices or all-solid-state batteries. In the form of scholarly introductions, the Encyclopedia chapters have been written by 151 noted experts working in 23 countries. They present at a consistent level and in a self-consistent manner these industrial, technological, scientific, historical and cultural aspects. Addressing the most recent fundamental advances in glass science and technology, as well as rapidly developing topics such as extra-terrestrial or biogenic glasses, this important guide: Begins with industrial glassmaking Turns to glass structure and to physical, transport and chemical properties Deals with interactions with light, inorganic glass families and organically related glasses Considers a variety of environmental and energy issues And concludes with a long section on the history of glass as a material from Prehistory to modern glass science The Encyclopedia of Glass Science, Technology, History, and Culture has been written not only for glass scientists and engineers in academia and industry, but also for material scientists as well as for art and industry historians. It represents a must-have, comprehensive guide to the myriad aspects this truly outstanding state of matter.


The Vitreous State

The Vitreous State
Author:
Publisher:
Total Pages: 468
Release: 1995
Genre: Glass
ISBN: 9783662031896

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The vitreous - glassy state is a particularly interesting physical state of solid matter. The authors summarize the experimental evidence and the theoretical approaches to understanding glass: structural, thermodynamic and statistical physics. The broad coverage of the subject and the authors' teaching tradition combine in this unique source for glass scientists and material engineers.


The Physics of Glassy Polymers

The Physics of Glassy Polymers
Author: R. N. Haward
Publisher: Springer Science & Business Media
Total Pages: 635
Release: 2012-12-06
Genre: Science
ISBN: 9401023557

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This work sets out to provide an up-to-date account of the physical properties and structure of polymers in the glassy state. Properties measured above the glass transition temperature are therefore included only in so far as is necessary for the treatment of the glass transition process. This approach to the subject therefore excludes any detailed account of rubber elasticity or melt rheology or of the structure and conformation of the long chain molecule in solution, although knowledge derived from this field is assumed where required. Major emphasis is placed on structural and mechanical properties, although a number of other physical properties are included. Naturally the different authors contributing to the book write mainly from their own particular points of view and where there are several widely accepted theoretical approaches to a subject, these are sometimes provided in different chapters which will necessarily overlap to a significant extent. For example, the main theoretical presentation on the subject of glass transition is given in Chapter 1. This is supplemented by accounts of the free volume theory in Chapter 3 and in the Introduction, and a short account of the work of Gibbs and DiMarzio, also in Chapter 3. Similarly, there is material on solvent cracking in Chapters 7 and 9, though the two workers approach the subject from opposite directions. Every effort has therefore been made to encourage cross-referencing between different chapters.


Fundamentals of Inorganic Glasses

Fundamentals of Inorganic Glasses
Author: Arun K. Varshneya
Publisher: Elsevier
Total Pages: 753
Release: 2019-05-09
Genre: Science
ISBN: 0128162260

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Fundamentals of Inorganic Glasses, Third Edition, is a comprehensive reference on the field of glass science and engineering that covers numerous, significant advances. This new edition includes the most recent advances in glass physics and chemistry, also discussing groundbreaking applications of glassy materials. It is suitable for upper level glass science courses and professional glass scientists and engineers at industrial and government labs. Fundamental concepts, chapter-ending problem sets, an emphasis on key ideas, and timely notes on suggested readings are all included. The book provides the breadth required of a comprehensive reference, offering coverage of the composition, structure and properties of inorganic glasses. Clearly develops fundamental concepts and the basics of glass science and glass chemistry Provides a comprehensive discussion of the composition, structure and properties of inorganic glasses Features a discussion of the emerging applications of glass, including applications in energy, environment, pharmaceuticals, and more Concludes chapters with problem sets and suggested readings to facilitate self-study


The Glass Transition

The Glass Transition
Author: E. Donth
Publisher: Springer Science & Business Media
Total Pages: 433
Release: 2013-04-17
Genre: Science
ISBN: 3662043653

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Describes and interrelates the following processes: cooperative alpha processes in a cold liquid, structural relaxation in the glass near Tg, the Johari-Goldstein beta process, the Williams-Götze process in a warm liquid, fast nonactivated cage rattling and boson peak, and ultraslow Fischer modes.


From glass to crystal

From glass to crystal
Author: Daniel R. Neuville
Publisher:
Total Pages: 645
Release: 2017
Genre: Education
ISBN: 9782759817832

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Glass-ceramics are now commonplace in our daily lives, despite having only been discovered for less than a century. It presents an update on the recent developments concerning the mechanisms of nucleation, crystal growth and phase separation, bringing together theoretical aspects and characterization methods.


Gas Transport in Glassy Polymers

Gas Transport in Glassy Polymers
Author: Maria Grazia De Angelis
Publisher: MDPI
Total Pages: 256
Release: 2021-04-22
Genre: Technology & Engineering
ISBN: 3036502122

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This Special Issue of Membranes focuses on several new aspects of fluid transport in glassy polymers, with application in relevant membrane separations such as gas purification, VOC removal and CO2 capture. In particular, the focus lies on novel experimental techniques, and detailed characterization of specific phenomena like polar and multicomponent interactions during transport. The properties of novel materials, such as mixed matrix membranes based on glassy polymers and different selective fillers, are also presented. A critical review of existing modeling approaches to describe the sorption and transport in glassy polymers suitable for membrane separations is provided, including both macroscopic and atomistic models, and relying both on the standard solution–diffusion process and on the facilitated transport mechanism.


Conductor Insulator Quantum Phase Transitions

Conductor Insulator Quantum Phase Transitions
Author: Vladimir Dobrosavljevic
Publisher: Oxford University Press
Total Pages: 583
Release: 2012-06
Genre: Science
ISBN: 0199592594

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When many particles come together how do they organize themselves? And what destroys this organization? Combining experiments and theory, this book describes intriguing quantum phases - metals, superconductors and insulators - and transitions between them. It captures the excitement and the controversies on topics at the forefront of research.


Thermodynamic and Kinetic Aspects of the Vitreous State

Thermodynamic and Kinetic Aspects of the Vitreous State
Author: S.V. Nemilov
Publisher: CRC Press
Total Pages: 214
Release: 2018-01-18
Genre: Science
ISBN: 1351094181

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This is the first book to logically present the major problems of the vitreous state within the framework of irreversible thermodynamics. Filled with elementary explanations for difficult problems, this easily understood text/reference treats in detail the criteria of glass transition, the peculiarities of relaxing structural parameters, and the Prigogine-Defay ratio. Based on the author's rigorous generalization of the Second Law for non-equilibrium, the book systematizes all known thermodynamic data for glasses and melts. The thermodynamic essence of structural relaxation and memory effects are considered. The viscous flow theories are treated as a constituent of the kinetic description. All theoretical questions are illustrated by comparison of calculations with the experiments for glasses of inorganic and organic nature, with special attention to structural classification. An informative review of modern structural investigations is included. The bibliography follows the history of the main problems from the nineteenth century.