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The History, Deterioration and Conservation of Cellulose Nitrate and Their Early Plastic Objects

The History, Deterioration and Conservation of Cellulose Nitrate and Their Early Plastic Objects
Author:
Publisher:
Total Pages: 63
Release: 1982
Genre: Nitrocellulose
ISBN:

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Represents a detailed study of the complex history, deterioration and conservation problems of objects made of cellulose nitrate, followed by a brief description of other early plastics which the museum conservators may encounter.


Cellulose Nitrate in Conservation

Cellulose Nitrate in Conservation
Author: Charles M. Selwitz
Publisher: Getty Publications
Total Pages: 75
Release: 1988-04-01
Genre: Art
ISBN: 0892360984

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This report attempts to isolate and separately examine each of the factors known to lead to cellulose nitrate decomposition, and then relate their contribution to the instability of the polymer when it is used as a bonding agent for ceramics and as a lacquer for metal objects. These factors include deterioration caused by heat, radiation, or acid impurities, or through the loss of plasticizer. There is, moreover, decomposition caused autocatalytically by the initial breakdown products. In particular, the publication examines new information on chemical changes under ambient conditions that has been developed recently through advances in analytical procedures such as chemiluminescence, X-ray scanning spectroscopy (ESCA), and more sophisticated viscometry. This new information will be added to the large body of data, collected over the past 150 years, on the instability of cellulose nitrate under more severe conditions.


Conservation of Plastics

Conservation of Plastics
Author: Yvonne Shashoua
Publisher: Routledge
Total Pages: 302
Release: 2012-06-25
Genre: Antiques & Collectibles
ISBN: 1136415157

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Plastic objects are included more than ever in museums and galleries collections these days, but these items can start to deteriorate when they a just a few years old. In this book Yvonne Shashoua provides the essential knowledge needed to keep plastic pieces in the best possible condition so that they can continue to be enjoyed for many years. The historical development of plastics, as well as the technology, their physical and chemical properties, identification, degradation and conservation are all clearly and concisely covered within this single volume, making it an invaluable reference for the increasing number of conservators and curators that are encountering plastics in their day to day work.


When Dolls Cry

When Dolls Cry
Author: Anel C. Rodriguez
Publisher:
Total Pages: 308
Release: 2003
Genre: Historical museums
ISBN:

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The purpose of this project is to inform general collections personnel working with historical museums, historical society and historic house collections in the United States about proper storage procedures to promote the longevity of plastic artifacts as well as protect them from inevitable degradation. I have chosen to focus on cellulose nitrate, cellulose acetate, and polyurethane foam because they are among the most fragile plastics in museum collections. Taking the form of jewelry, eyeglasses, dental plates, and other personal effects, plastic has become as ubiquitous to our popular cultural history as television. However, the museum community has only recently discovered the need for its care. Far from being "indestructible", artifacts made of early plastics in museum collections have not only begun to degrade but are also endangering other collection items through off-gassing. Many of the dangers have been researched in recent years, but only by and among conservators who have put forward a number of preventive conservation standards for plastics. Proper storage is noted throughout the literature as the number one method of care. Unfortunately, for collections personnel, storage of plastics not only involves knowing how to store the different types of plastics but also being able to distinguish one plastic from the other. Traditionally, conservators, who have an extensive knowledge of chemistry, are able to make such distinctions. This project makes this information easily accessible and discernible for collections staff who are the individuals ultimately responsible for storage. I accomplished my research through a review of the literature discussing plastic and American culture, preventive conservation standards, and specific scientific properties of cellulose nitrate, cellulose acetate, and polyurethane foam. Combined with interviews and survey results from historical institutions throughout the United States, I was able to create a manual that teaches collections professionals how to identify cellulose acetate, cellulose nitrate, and polyurethane foam and provides the appropriate storage recommendations for each plastic.


Preservation of Plastic Artefacts in Museum Collections

Preservation of Plastic Artefacts in Museum Collections
Author: B. Lavédrine (ed.)
Publisher: Comité des travaux historiques et scientifiques - CTHS
Total Pages: 340
Release: 2012
Genre: Art objects
ISBN:

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This book is created for the conservation community interested in the preservation of art and design works that happen to be made out of a wide variety of plastic formulations. It gathers a bulk of knowledge that is a record of the latest conservation science and technology as applied to plastic works of art, gained during the POPART project - the Preservation Of Plastic ARTefacts in museum collections: a forty two-month international research project part-funded by the European Commission.


Evaluation of Cellulose Ethers for Conservation

Evaluation of Cellulose Ethers for Conservation
Author: Robert L. Feller
Publisher: Getty Publications
Total Pages: 173
Release: 1991-03-21
Genre: Art
ISBN: 0892360992

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This report is the result of a three-year research program. It describes the chemical character of cellulose ethers as a general class of polymers and establishes an approximate ranking of the relative stability of each generic chemical subclass. Ranking the thermal stability of the polymers with respect to color change and loss in degree of polymerization led to the conclusion that as generic chemical classes, methylcellulose and carboxymethylcellulose appear to be the most stable of the cellulose ethers. Water-soluble ethylhydroxyethylcellulose apparently also possesses good stability. Of questionable long-term stability are hydroxyethylcellulose and hydroxy- propylcellulose. Ethylcellulose and organic-soluble ethylhydroxyethylcellulose proved to be of poor stability, potentially undergoing marked changes in twenty years or less under normal museum conditions. An important additional conclusion reached here, as well as in an earlier investigation, is that considerable variations in stability can occur within a generic chemical class from differences in the basic raw material, a natural product from plants, which is not a uniform, manufactured, chemical substance. Further variations can exist due to different manufacturing processes or commercial sources. Hence, commercial products must be evaluated individually to determine the most stable of a given generic type. Nonetheless, the authors believe the conclusions expressed here to be valid with regard to the relative stability of the generic chemical classes of cellulose ethers.


Accelerated Aging

Accelerated Aging
Author: Robert L. Feller
Publisher: Getty Publications
Total Pages: 292
Release: 1995-03-02
Genre: Art
ISBN: 0892361255

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Accelerated Aging: Photochemical and Thermal Aspects represents the culmination of more than 40 years of research by noted scientist Robert L. Feller. The book focuses on the long-term performance of materials such as wool, dyes, and organic compounds; their resistance to change when exposed to environmental factors such as oxygen, ozone, moisture, heat, and light; and their physical durability with handling and use over time. Processes of deterioration are discussed based on speeded-up laboratory studies designed to clarify the chemical reactions involved and their physical consequences.


Pioneer Plastic

Pioneer Plastic
Author: Robert Douglas Friedel
Publisher:
Total Pages: 184
Release: 1983
Genre: Technology & Engineering
ISBN:

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In 1869, an Albany printer discovered how to mix nitrocellulose with camphor under high pressure to yield a hard, shiny, moldable substance which he and his brother called celluloid. This discovery was the dawn of the Plastics Age, but it represented only the first step in establishing a new technology. Examines the 20 years of laboratory trial and error that produced the first artificial plastic, as well as the equally difficult challenge of selling the product to a public that wasn't sure what to use it for. He shows how the struggle to find uses for the new material and to create markets for it was as significant as solving the problems of making it. Illustrated.


Coatings on Photographs

Coatings on Photographs
Author: Constance McCabe
Publisher: American Institute for Conservation of Historic & Artistic W
Total Pages: 392
Release: 2005
Genre: Photography
ISBN:

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