The Diels Alder Reaction PDF Download
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Author | : Francesco Fringuelli |
Publisher | : John Wiley & Sons |
Total Pages | : 364 |
Release | : 2002-01-21 |
Genre | : Science |
ISBN | : 9780471803430 |
Download The Diels-Alder Reaction Book in PDF, ePub and Kindle
70 Jahre Forschung an der Diels-Alder-Reaktion: Dieses Buch fasst die wichtigsten und beeindruckendsten Ergebnisse in einzigartiger Weise zusammen! Zunächst werden die Grundprinzipien der Reaktion klar und verständlich anhand übersichtlicher Graphiken erläutert. Spezielle Vorschriften und gegebenenfalls ihre industrielle Umsetzung werden anschließend erklärt. Einen Schwerpunkt bilden auch physikalische und katalytische Verfahren zur Steigerung der Selektivität der Reaktion. Cycloadditionen in konventionellen und unkonventionellen Medien werden vorgestellt. Mit über 1.000 Literaturverweisen!
Author | : |
Publisher | : Elsevier |
Total Pages | : 379 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 008091697X |
Download Hetero Diels-Alder Methodology in Organic Synthesis Book in PDF, ePub and Kindle
Organic Chemistry: A Series of Monographs, Volume 47: Hetero Diels-Alder Methodology in Organic Synthesis focuses on the use of hetero Diels-Alder reactions as pivotal steps in natural product total syntheses. The publication first offers information on N-sulfinyl compounds and sulfur diimides and imino dienophiles. Discussions focus on sulfur dioxide and related compounds, selenium dioxide, sulfur diimide cycloadditions, regiochemical, stereochemical, and mechanistic aspects, iminium salts and neutral imines, oximino compounds, and intramolecular cycloadditions. The text then takes a look at nitroso and thionitroso dienophiles and carbonyl dienophiles. The manuscript elaborates on thiocarbonyl and selenocarbonyl dienophiles and miscellaneous dienophiles. Topics include nitriles, azo compounds, selenoaldehydes, thioketones, thioesters, dithioesters, and related compounds, and thiophosgene and related compounds. The text also ponders on oxabutadienes, thiabutadienes, and azabutadienes. The publication is a valuable reference for chemists and readers interested in the Hetero Diels-Alder methodology.
Author | : Douglass F. Taber |
Publisher | : Springer Science & Business Media |
Total Pages | : 106 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 3642692338 |
Download Intramolecular Diels-Alder and Alder Ene Reactions Book in PDF, ePub and Kindle
The Diels-Alder reaction has long been a powerful tool in organic synthesis. In recent years, the Alder ene reaction has also achieved some prominence. From the beginning, it was apparent that the intramolecular variants of these reactions would be feasible. Many such have been reported, but the results are widely scattered in the chemical literature. This volume is an attempt to synthesize results observed to date, and to suggest directions for future development. One of the limiting factors in the application of the intramolecular Diels Alder reaction has been the development of methods for the preparation of the requisite trienes. The fIrst chapter of this volume summarizes methods for the preparation of dienes and dienophiles. Examples representative of every general approach to 1,3-dienes and to dienophilic functional group combinations have been included. There are two questions one might ask in considering the prospective cyclization of a given triene: what are the factors that govern the rate of cyclization? and, for cyclizations that lead to the creation of one or more new chiral centers, what are the factors that govern diastereoselectivity? These questions are addressed in Chapter Two. The third chapter is devoted to the all-carbon intramolecular Alder ene reaction. The tables in that chapter summarize all examples that could be found in the literature through 1981, with several additional examples from 1982. Leading references to heterocyclic ene reactions are also included in this chapter.
Author | : Jie Jack Li |
Publisher | : Springer Science & Business Media |
Total Pages | : 435 |
Release | : 2013-11-11 |
Genre | : Science |
ISBN | : 3662048353 |
Download Name Reactions Book in PDF, ePub and Kindle
This book differs from others on name reactions in organic chemistry by focusing on their mechanisms. It covers over 300 classical as well as contemporary name reactions. Biographical sketches for the chemists who discovered or developed those name reactions have been included. Each reaction is delineated by its detailed step-by-step, electron-pushing mechanism, supplemented with the original and the latest references, especially review articles. This book contains major improvements over the previous edition and the subject index is significantly expanded.
Author | : R. B. Woodward |
Publisher | : Elsevier |
Total Pages | : 185 |
Release | : 2013-10-22 |
Genre | : Science |
ISBN | : 148328204X |
Download The Conservation of Orbital Symmetry Book in PDF, ePub and Kindle
The Conservation of Orbital Symmetry examines the principle of conservation of orbital symmetry and its use. The central content of the principle was that reactions occur readily when there is congruence between orbital symmetry characteristics of reactants and products, and only with difficulty when that congruence does not obtain—or to put it more succinctly, orbital symmetry is conserved in concerted reaction. This principle is expected to endure, whatever the language in which it may be couched, or whatever greater precision may be developed in its application and extension. The book opens with a review of the elementary aspects of the molecular orbital theory of bonding. This is followed by separate chapters on correlation diagrams, the conservation of orbital symmetry, theory of electrocyclic reactions, theory of cycloadditions and cycloreversions, and theory of sigmatropic reactions. Subsequent chapters deal with group transfers and eliminations; secondary conformational effects in concerted cycloaddition reactions; and generalized selection rules for pericyclic reactions.
Author | : Francesco Fringuelli |
Publisher | : Wiley-Interscience |
Total Pages | : 376 |
Release | : 1990-05-31 |
Genre | : Science |
ISBN | : |
Download Dienes in the Diels-Alder Reaction Book in PDF, ePub and Kindle
Dealing with the intermolecular Diels-Alder reaction, this book focuses on one of the reactants - the diene. Following an examination of the fundamental principles of the reaction are descriptions of the salient features of the different classes of dienes.
Author | : W. Russ Algar |
Publisher | : John Wiley & Sons |
Total Pages | : 923 |
Release | : 2017-03-17 |
Genre | : Technology & Engineering |
ISBN | : 352768347X |
Download Chemoselective and Bioorthogonal Ligation Reactions Book in PDF, ePub and Kindle
This timely, one-stop reference is the first on an emerging and interdisciplinary topic. Covering both established and recently developed ligation chemistries, the book is divided into two didactic parts: a section that focuses on the details of bioorthogonal and chemoselective ligation reactions at the level of fundamental organic chemistry, and a section that focuses on applications, particularly in the areas of chemical biology, biomaterials, and bioanalysis, highlighting the capabilities and benefits of the ligation reactions. With chapters authored by outstanding scientists who range from trailblazers in the field to young and emerging leaders, this book on a highly interdisciplinary topic will be of great interest for biochemists, biologists, materials scientists, pharmaceutical chemists, organic chemists, and many others.
Author | : W. Carruthers |
Publisher | : Elsevier |
Total Pages | : 382 |
Release | : 2013-10-22 |
Genre | : Science |
ISBN | : 008091232X |
Download Cycloaddition Reactions in Organic Synthesis Book in PDF, ePub and Kindle
Demonstrates the wide scope of cycloaddition reactions, including the Diels-Alder reaction, the ene reaction, 1,3-dipolar cycloadditions and [2+2] cycloadditions in organic synthesis. The author, a leading exponent of the subject, illustrates the ways in which they can be employed in the synthesis of a wide range of carbocyclic and heterocyclic compounds, including a variety of natural products of various types. Special attention is given to intramolecular reactions, which often provide a rapid and efficient route to polycyclic compounds, and to the stereochemistry of the reactions, including recent and developing work on enantioselective synthesis.
Author | : Pei-Qiang Huang |
Publisher | : John Wiley & Sons |
Total Pages | : 512 |
Release | : 2018-07-24 |
Genre | : Science |
ISBN | : 1118940210 |
Download Efficiency in Natural Product Total Synthesis Book in PDF, ePub and Kindle
Uniting the key organic topics of total synthesis and efficient synthetic methodologies, this book clearly overviews synthetic strategies and tactics applied in total synthesis, demonstrating how the total synthesis of natural products enables scientific and drug discovery. • Focuses on efficiency, a fundamental and important issue in natural products synthesis that makes natural product synthesis a powerful tool in biological and pharmaceutical science • Describes new methods like organocatalysis, multicomponent and cascade reactions, and biomimetic synthesis • Appeals to graduate students with two sections at the end of each chapter illustrating key reactions, strategies, tactics, and concepts; and good but unfinished total synthesis (synthesis of core structure) before the last section • Compiles examples of solid phase synthesis and continuing flow chemistry-based total synthesis which are very relevant and attractive to industry R&D professionals
Author | : Bruno Filipe Carmelino Cardoso Sarmento |
Publisher | : Elsevier |
Total Pages | : 0 |
Release | : 2018-03-03 |
Genre | : Science |
ISBN | : 9780323508780 |
Download Biomedical Applications of Functionalized Nanomaterials Book in PDF, ePub and Kindle
Biomedical Applications of Functionalized Nanomaterials: Concepts, Development and Clinical Translation presents a concise overview of the most promising nanomaterials functionalized with ligands for biomedical applications. The first section focuses on current strategies for identifying biological targets and screening of ligand to optimize anchoring to nanomaterials, providing the foundation for the remaining parts. Section Two covers specific applications of functionalized nanomaterials in therapy and diagnostics, highlighting current practice and addressing major challenges, in particular, case studies of successfully developed and marketed functionalized nanomaterials. The final section focuses on regulatory issues and clinical translation, providing a legal framework for their use in biomedicine. This book is an important reference source for worldwide drug and medical devices policymakers, biomaterials scientists and regulatory bodies.