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The Determination of Epoxide Groups

The Determination of Epoxide Groups
Author: B. Dobinson
Publisher: Elsevier
Total Pages: 88
Release: 2013-10-22
Genre: Science
ISBN: 1483150534

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The Determination of Epoxide Groups describes the advantages and limitations of the methods for determination of 1,2-epoxide groups of various kinds. Chapter 1 examines the chemical reactivities of different epoxides under various conditions, which is of fundamental importance in the choice of the analytical method to be used. Chapter 2 explores most of the analytical work on epoxides involving ring-opening with HCl or HBr. Chapter 3 deals with the alternative techniques involving quantitative rearrangement of epoxides, or ring-opening under non-acidic conditions. This chapter also contains descriptions of various miscellaneous analytical techniques, including very sensitive methods, as well as the use of infrared spectroscopic techniques for analysis of epoxides and the study of their reactions, particularly the cure of epoxy resins. Chapter 4 summarizes the advantages and limitations of the various methods, along with the main factors affecting choice of experimental. This book is of great value to analytical and organic chemists, researchers, and students.


On the Determination of the Distance of a Comet from the Earth

On the Determination of the Distance of a Comet from the Earth
Author: J. W. Lubbock
Publisher: Cambridge University Press
Total Pages: 369
Release: 2014-08-21
Genre: Science
ISBN: 1108068626

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A one-volume reissue of works published between 1832 and 1861, including writings on astronomy, gases and the tides.


Optimization of adaptive test design methods for the determination of steady-state data-driven models in terms of combustion engine calibration

Optimization of adaptive test design methods for the determination of steady-state data-driven models in terms of combustion engine calibration
Author: Sandmeier, Nino
Publisher: Universitätsverlag der TU Berlin
Total Pages: 236
Release: 2022-12-01
Genre: Technology & Engineering
ISBN: 3798332479

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This thesis deals with the development of a model-based adaptive test design strategy with a focus on steady-state combustion engine calibration. The first research topic investigates the question how to handle limits in the input domain during an adaptive test design procedure. The second area of scope aims at identifying the test design method providing the best model quality improvement in terms of overall model prediction error. To consider restricted areas in the input domain, a convex hull-based solution involving a convex cone algorithm is developed, the outcome of which serves as a boundary model for a test point search. A solution is derived to enable the application of the boundary model to high-dimensional problems without calculating the exact convex hull and cones. Furthermore, different data-driven engine modeling methods are compared, resulting in the Gaussian process model as the most suitable one for a model-based calibration. To determine an appropriate test design method for a Gaussian process model application, two new strategies are developed and compared to state-of-the-art methods. A simulation-based study shows the most benefit applying a modified mutual information test design, followed by a newly developed relevance-based test design with less computational effort. The boundary model and the relevance-based test design are integrated into a multicriterial test design strategy that is tailored to match the requirements of combustion engine test bench measurements. A simulation-based study with seven and nine input parameters and four outputs each offered an average model quality improvement of 36 % and an average measured input area volume increase of 65 % compared to a non-adaptive space-filling test design. The multicriterial test design was applied to a test bench measurement with seven inputs for verification. Compared to a space-filling test design measurement, the improvement could be confirmed with an average model quality increase of 17 % over eight outputs and a 34 % larger measured input area. Diese Arbeit befasst sich mit der Entwicklung einer modellbasierten adaptiven Versuchsplanungsstrategie für die Anwendung in der Applikation des Stationärverhaltens von Verbrennungsmotoren. Der erste Forschungsteil untersucht, wie sich Grenzen im Eingangsraum in die Versuchsplanung eines adaptiven Prozesses einbinden lassen. Ein weiterer Fokus liegt auf der Identifikation einer modellbasierten Versuchsplanung, die eine bestmögliche Verbesserung der globalen Modellqualität hinsichtlich des Prädiktionsfehlers ermöglicht. Es wird ein Grenzraummodell auf Basis der konvexen Hülle unter Zuhilfenahme eines Algorithmus zur Bestimmung eines konvexen Konus entwickelt, das als Grundlage für eine Versuchsplanung in beschränkten Eingangsräumen verwendet wird. Um die Anwendbarkeit bei hochdimensionalen Problemstellungen zu gewährleisten, wird ein Verfahren vorgestellt, das eine Berechnung auch ohne die Bestimmung der exakten konvexen Hülle und konvexen Konen ermöglicht. Des Weiteren werden verschiedene Methoden zur datengetriebenen Modellbildung des Verbrennungsmotors verglichen, wobei das Gauß-Prozess Modell als die geeignetste Modellierungsmethode hervorgeht. Um die bestmögliche Versuchsplanungsmethode bei der Anwendung des Gauß-Prozess Modells zu ermitteln, werden zwei neue Strategien entwickelt und mit verfügbaren Methoden aus der Literatur verglichen. Eine simulationsbasierte Studie zeigt, dass eine angepasste Mutual Information Methode die besten Ergebnisse liefert. Ein neu entwickeltes relevanzbasiertes Verfahren erreicht die zweitbesten Ergebnisse, bietet aber einen geringeren Berechnungsaufwand als das Mutual Information Verfahren. Das Grenzmodell und das relevanzbasierte Verfahren werden in einem multikriteriellen Versuchsplanungsverfahren zusammengeführt, das an die Anforderungen von Messungen an einem Verbrennungsmotorenprüfstand angepasst ist. In einer simulationsbasierten Studie mit sieben bzw. neun Eingangsparametern und jeweils vier Ausgängen konnte eine durchschnittliche Modellqualitätsverbesserung von 36 % und eine mittlere Vergrößerung des vermessenen Eingangsraumvolumens von 65 % im Vergleich zu einer nichtadaptiven raumfüllenden Versuchsplanung gezeigt werden. Das multikriterielle Versuchsplanungsverfahren wurde anhand von Prüfstandsmessungen mit sieben Eingangsparametern verifiziert. Im Vergleich zu einer raumfüllenden Versuchsplanung konnte eine mittlere Modellqualitätsverbesserung über alle acht Ausgänge von 17 % und ein um 34 % vergrößertes vermessenes Eingangsraumvolumen erreicht werden, wodurch die Ergebnisse der Simulationen bestätigt werden konnten.


The Determination of Ionization Constants

The Determination of Ionization Constants
Author: Adrien Albert
Publisher: Springer Science & Business Media
Total Pages: 223
Release: 2012-12-06
Genre: Science
ISBN: 9400955480

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This practical manual is devised for organic chemists and biochemists who, in the course of their researches and without previous experience, need to determine an ionization constant. We are gratified that earlier editions were much used for this purpose and that they also proved adequate for the in service training of technicians and technical officers to provide a Department with a pK service. The features of previous editions that gave this wide appeal have been retained, but the subject matter has been revised, extended, and brought up to date. We present two new chapters, one of which describes the determination of the stability constants of the complexes which organic ligands form with metal cations. The other describes the use of more recently introduced techniques for the determination of ionization constants, such as Raman and nuclear magnetic resonance spectroscopy, thermometric titrations, and paper electro phoresis. Chapter 1 gives enhanced help in choosing between alternative methods for determining ionization constants. The two chapters on potentiometric methods have been extensively revised in the light of newer understanding of electrode processes and of the present state of the art in instrumen tation.


Precision and Accuracy in the Determination of Organics in Water by Fused Silica Capillary Column Gas Chromatography/mass Spectrometry and Packed Column Gas Chromatography/mass Spectrometry

Precision and Accuracy in the Determination of Organics in Water by Fused Silica Capillary Column Gas Chromatography/mass Spectrometry and Packed Column Gas Chromatography/mass Spectrometry
Author:
Publisher:
Total Pages: 702
Release: 1983
Genre: Organic water pollutants
ISBN:

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