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The Chemistry of Plutonium

The Chemistry of Plutonium
Author: Jesse M. Cleveland
Publisher:
Total Pages: 688
Release: 1979
Genre: Science
ISBN:

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Dr. Cleveland's monographs is a comprehensive and authoritative treatise on the theory and practice of plutonium chemistry and is of value to all chemists interested in the chemistry of the actinide elements.


Chemistry of Plutonium (V).

Chemistry of Plutonium (V).
Author: K. A. Kraus
Publisher:
Total Pages: 10
Release: 1947
Genre: Plutonium
ISBN:

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Analytical Chemistry of Plutonium

Analytical Chemistry of Plutonium
Author: Institut geokhimii i analiticheskoĭ khimii im. V.I. Vernadskogo
Publisher: Butterworth-Heinemann
Total Pages: 460
Release: 1969
Genre: Science
ISBN:

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Some Observations on the Basic Chemistry of Plutonium

Some Observations on the Basic Chemistry of Plutonium
Author: E. S. Maxwell
Publisher:
Total Pages: 8
Release: 1948
Genre: Plutonium
ISBN:

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On prolonged heating in dilute nitric acid (0.5M to 6.8M) a considerable amount of Pu(+4) is oxidized to Pu(+8). Precipitation of the plus three plutonium oxalate is complete in fifteen minutes. Oxidation of Pu(+4) to Pu(+8) by bromine is quantitative at 105 deg C after 1/2 hour; at 50 deg C the rate of oxidation is slow, but measurable. At room temperature the rate is too slow to measure. A method of converting PuC13 to Pu(NO3)4 is given. A solubility of NaPuO2Ac3 increases with temperature the value at 25 deg C being 19.5 g/iiter and that at 95 deg C, 37.5 g/liter. Supersaturation was observed on slow cooling of a saturated solution. p2.


Structural Chemistry of Inorganic Actinide Compounds

Structural Chemistry of Inorganic Actinide Compounds
Author: Sergey Krivovichev
Publisher: Elsevier
Total Pages: 505
Release: 2006-12-08
Genre: Science
ISBN: 0080467911

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Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions. * Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'