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The Chemical Bond in Inorganic Chemistry

The Chemical Bond in Inorganic Chemistry
Author: Ian David Brown
Publisher: Oxford University Press on Demand
Total Pages: 289
Release: 2002
Genre: Science
ISBN: 0198508700

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The bond valence model is a recently developed model of the chemical bond in inorganic chemistry that complements the bond model widely used in organic chemistry. It is simple, quantitative, intuitive, and predictive - no more than a pocket calculator is needed to calculate it. This book focuses on the theory that underlies the model, and shows how it has been used in physics, materials science, chemistry, mineralogy, soil science, and molecular biology.


The Chemical Bond in Inorganic Chemistry

The Chemical Bond in Inorganic Chemistry
Author: I. David Brown
Publisher: Oxford University Press
Total Pages: 352
Release: 2016-09-29
Genre: Science
ISBN: 019109305X

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The bond valence model, a description of acid-base bonding, is widely used for analysing and modelling the structures and properties of solids and liquids. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and is accessible to anyone with a pocket calculator and a secondary school command of chemistry and physics. This new edition of 'The Chemical Bond in Inorganic Chemistry: The Bond Valence Model' shows how chemical properties arise naturally from the conflict between the constraints of chemistry and those of three-dimensional space. The book derives the rules of the bond valence model, as well as those of the traditional covalent, ionic and popular VSEPR models, by identifying the chemical bond with the electrostatic flux linking the bonded atoms. Most of the new edition is devoted to showing how to apply these ideas to real materials including crystals, liquids, glasses and surfaces. The work includes detailed examples of applications, and the final chapter explores the relationship between the flux and quantum theories of the bond.


Chemical Bonds

Chemical Bonds
Author: Jeremy K. Burdett
Publisher: John Wiley & Sons
Total Pages: 182
Release: 1997-05-28
Genre: Science
ISBN: 9780471971306

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Inorganic Chemistry This series reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series covers the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, main group chemistry and bioinorganic chemistry. Chemical Bonds A Dialog Jeremy K. Burdett The University of Chicago, USA Understanding the nature of the chemical bond is the key to understanding all chemistry, be it inorganic, physical, organic or biochemistry. In the form of a question and answer tutorial the fundamental concepts of chemical bonding are explored. These range from the nature of the chemical bond, via the regular hexagonal structure of benzene and the meaning of the term 'metallic bond', to d-orbital involvement in hypervalent compounds and the structure of N_2O. Chemical Bonds: A Dialog provides * a novel format in terms of a dialog between two scientists * insights into many key questions concerning chemical bonds * an orbital approach to quantum chemistry


The VSEPR Model of Molecular Geometry

The VSEPR Model of Molecular Geometry
Author: Ronald J Gillespie
Publisher: Courier Corporation
Total Pages: 274
Release: 2013-03-21
Genre: Science
ISBN: 0486310523

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Valence Shell Electron Pair Repulsion (VSEPR) theory is a simple technique for predicting the geometry of atomic centers in small molecules and molecular ions. This authoritative reference was written by Istvan Hartiggai and the developer of VSEPR theory, Ronald J. Gillespie. In addition to its value as a text for courses in molecular geometry and chemistry, it constitutes a classic reference for professionals. Starting with coverage of the broader aspects of VSEPR, this volume narrows its focus to a succinct survey of the methods of structural determination. Additional topics include the applications of the VSEPR model and its theoretical basis. Helpful data on molecular geometries, bond lengths, and bond angles appear in tables and other graphics.


The Chemical Bond

The Chemical Bond
Author: Gernot Frenking
Publisher: John Wiley & Sons
Total Pages: 450
Release: 2014-07-08
Genre: Science
ISBN: 3527333142

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This is the perfect complement to "Chemical Bonding - Across the Periodic Table" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community. The resulting book is a unique overview of the different approaches used for describing a chemical bond, including molecular-orbital based, valence-bond based, ELF, AIM and density-functional based methods. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers.


Chemical Bond In Inorganic Chemistry,

Chemical Bond In Inorganic Chemistry,
Author: I. David Brown
Publisher:
Total Pages: 288
Release: 2007-10-29
Genre: Chemical bonds
ISBN: 9780195694161

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The Chemical Bond I

The Chemical Bond I
Author: D. Michael P. Mingos
Publisher: Springer
Total Pages: 252
Release: 2016-09-09
Genre: Science
ISBN: 331933543X

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The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors


Chemistry of Chemical Bonding

Chemistry of Chemical Bonding
Author: R. K. Sharma
Publisher: Discovery Publishing House
Total Pages: 362
Release: 2007
Genre: Chemical bonds
ISBN: 9788183562249

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Chemical Bonding and Molecular Geometry

Chemical Bonding and Molecular Geometry
Author: Ronald James Gillespie
Publisher: Oxford University Press on Demand
Total Pages: 268
Release: 2001
Genre: Science
ISBN: 9780195104967

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Ideal for undergraduate and first-year graduate courses in chemical bonding, Chemical Bonding and Molecular Geometry: From Lewis to Electron Densities can also be used in inorganic chemistry courses. Authored by Ronald Gillespie, a world-class chemist and expert on chemical bonding, and Paul Popelier of the University of Manchester Institute of Science and Technology, this text provides students with a comprehensive and detailed introduction to the principal models and theories of chemical bonding and geometry. It also serves as a useful resource and an up-to-date introduction to modern developments in the field for instructors teaching chemical bonding at any level. Features: * Shows students how the concept of the chemical bond has developed from its earliest days, through Lewis's brilliant concept of the electron pair bond and up to the present day * Presents a novel, non-traditional approach that emphasizes the importance of the Pauli principle as a basis for understanding bonding * Begins with the fundamental classical concepts and proceeds through orbital models to recent ideas based on the analysis of electron densities, which help to clarify and emphasize many of the limitations of earlier models * Provides a thorough and up-to-date treatment of the well-known valence-shell electron pair (VSEPR) model (which was first formulated and developed by author Ronald Gillespie) and the more recent ligand close-packing (LCP) model * Presents a unique pictorial and nonmathematical discussion of the analysis of electron density distributions using the atoms in molecules (AIM) theory * Emphasizes the relationships between these various models, giving examples of their uses, limitations, and comparative advantages and disadvantages