Synthesis and Physical Properties of Poly(Perfluoroalkylether)Urethanes
Author | : |
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Total Pages | : 44 |
Release | : 1989 |
Genre | : |
ISBN | : |
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Polyurethane block copolymers were synthesized containing 33 and 50 wt% soft segment, and hard segment based on 4,4-diphenylmethane dissocyanate (MDI) chain extender. The soft segments were mixtures of poly(tetramethylene oxide) (PTMO) and poly(perfluoroalkylether) (PFEG) glycols (Mn=1000 and 1900, respectively), ranging from 4 to 100wt% PFEG. The PMTO polyol in one sample was substituted with a PMTO/ethylene oxide polyol (75:25 mole ratio) (Mn=1140). The MDEA-extended polymer was ionized using 1,3-propane sultone. The morphology, bulk, and surface properties of these polymers were evaluated by a variety of techniques. Differential scanning calorimetry and dynamic mechanical analysis showed that the incorporation of PFEG into the soft segment phase slightly enhanced the degree of phase separation. Polyurethanes; Poly(perfluoroalkylether); Mixed soft segment; Polymers; Organic chemistry.