Synthesis And Characterisation Of Ortho Metallated Platinum Complexes Containing Tertiary Phosphine And Arsine Donor Ligands PDF Download

Aryl group can indeed be transferred into platinum metal having strong phosphine ligand provided that Cu(I) salts used as catalyst. Different ligands were tested to investigate the scope of the reaction, a library of monosubstituted, symmetrically disubstituted and asymmetrically disubstituted platinum complexes were prepared. Basic photophysical properties i.e. ground-state absorption, steady-state emission in both air-saturated and argon purged solutions were studied. Finally, the novel carbon-platinum bond formation reaction was used to synthesize a series of platinum complexes in which 2,1,3-benzothiadiazole was ligated with various electron-rich systems was connected via platinum metal. Extensive photophysical and electrochemical investigation was conducted on these novel platinum complexes.