Synergy Between Chemical Dissolution And Mechanical Abrasion During Chemical Mechanical Polishing Of Copper PDF Download

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Synergy Between Chemical Dissolution and Mechanical Abrasion During Chemical Mechanical Polishing of Copper

Synergy Between Chemical Dissolution and Mechanical Abrasion During Chemical Mechanical Polishing of Copper
Author: Wei Che
Publisher:
Total Pages: 282
Release: 2005
Genre:
ISBN:

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Chemical mechanical planarization (CMP) is becoming a promising mainstream semiconductor processing method because of its demonstrated capability to achieve better local and global planarization for various materials. However, the CMP process is influenced by a set of factors, which lead to a poor understanding of the material removal mechanisms (MRMs) and inhibits the migratability of the lab-scale experiments to industrial practice. This work focuses on the synergistic effects between chemical dissolution and mechanical abrasion to understand the MRMs during CMP. Initial in-situ wear test in chemically active slurry showed an increased material removal rate (MRR) relative to dry wear tests. To understand the synergistic effects, two plausible MRMs; (i) chemical dissolution enhanced mechanical abrasion and (ii) mechanical abrasion accelerated chemical dissolution, were investigated. In addition, a phenomenological MRR model based on scratch-intersections was formulated to understand the role of consumables and the process parameters. For mechanism I, a combined experimental and modeling technique was devised to understand the mechanical properties of the soft layer formed on the surface due to chemical exposure in CMP. The developed approaches utilized nano-scratch tests, nano-dynamic mechanical analysis (DMA) tests, the limit analysis solution of surface plowing under a spherical traveling indenter, and finite element simulation to deconvolute the soft layer thickness, hardness and elastic modulus. For mechanism II, it is found that the residual stress caused by the mechanical wear enhances the chemical etching rate, as manifested by an increase in wear depth. It is also found that the roughness with wavelength above a critical value grows while roughness of lower wavelength decays during etching, in which an established fact for stress-enhanced chemical dissolution is used. The developed understanding would enable understanding the root causes of defect generation mechanism and render remedies for yield improvements. The proposed models, through their mechanistic description, will facilitate an exploration of the design space and identification of realistic CMP process domains, including: (i) particle shape, size and concentration; (ii) adapting slurry chemistry for required rates of chemical dissolution and mechanical abrasion; and (iii) selecting pads with the proper surface morphology and stiffness.


Micromanufacturing Processes

Micromanufacturing Processes
Author: V.K. Jain
Publisher: CRC Press
Total Pages: 429
Release: 2016-04-19
Genre: Technology & Engineering
ISBN: 143985291X

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Increased demand for and developments in micromanufacturing have created a need for a resource that covers both the science and technology of this rapidly growing area. With contributions from eminent professors and researchers actively engaged in teaching, research, and development, Micromanufacturing Processes details the basic principles, tools,


Mechanics of Composite and Multi-functional Materials, Volume 5

Mechanics of Composite and Multi-functional Materials, Volume 5
Author: Raman Singh
Publisher: Springer Nature
Total Pages: 108
Release: 2019-12-04
Genre: Science
ISBN: 3030300285

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Mechanics of Composite, Hybrid, and Multifunctional Materials, Volume 5 of the Proceedings of the 2019 SEM Annual Conference & Exposition on Experimental and Applied Mechanics, the fifth volume of six from the Conference, brings together contributions to this important area of research and engineering. The collection presents early findings and case studies on a wide range of areas, including: Recycled Constituent Composites Damage Detection Advanced Imaging of Composites Multifunctional Materials Composite Interfaces Tunable Composites


Chemical Mechanical Planarization of Microelectronic Materials

Chemical Mechanical Planarization of Microelectronic Materials
Author: Joseph M. Steigerwald
Publisher: John Wiley & Sons
Total Pages: 337
Release: 2008-09-26
Genre: Science
ISBN: 3527617752

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Chemical Mechanical Planarization (CMP) plays an important role in today's microelectronics industry. With its ability to achieve global planarization, its universality (material insensitivity), its applicability to multimaterial surfaces, and its relative cost-effectiveness, CMP is the ideal planarizing medium for the interlayered dielectrics and metal films used in silicon integrated circuit fabrication. But although the past decade has seen unprecedented research and development into CMP, there has been no single-source reference to this rapidly emerging technology-until now. Chemical Mechanical Planarization of Microelectronic Materials provides engineers and scientists working in the microelectronics industry with unified coverage of both the fundamental mechanisms and engineering applications of CMP. Authors Steigerwald, Murarka, and Gutmann-all leading CMP pioneers-provide a historical overview of CMP, explain the various chemical and mechanical concepts involved, describe CMP materials and processes, review the latest scientific data on CMP worldwide, and offer examples of its uses in the microelectronics industry. They provide detailed coverage of the CMP of various materials used in the making of microcircuitry: tungsten, aluminum, copper, polysilicon, and various dielectric materials, including polymers. The concluding chapter describes post-CMP cleaning techniques, and most chapters feature problem sets to assist readers in developing a more practical understanding of CMP. The only comprehensive reference to one of the fastest growing integrated circuit manufacturing technologies, Chemical Mechanical Planarization of Microelectronic Materials is an important resource for research scientists and engineers working in the microelectronics industry. An indispensable resource for scientists and engineers working in the microelectronics industry Chemical Mechanical Planarization of Microelectronic Materials is the only comprehensive single-source reference to one of the fastest growing integrated circuit manufacturing technologies. It provides engineers and scientists who work in the microelectronics industry with unified coverage of both the fundamental mechanisms and engineering applications of CMP, including: * The history of CMP * Chemical and mechanical underpinnings of CMP * CMP materials and processes * Applications of CMP in the microelectronics industry * The CMP of tungsten, aluminum, copper, polysilicon, and various dielectrics, including polymers used in integrated circuit fabrication * Post-CMP cleaning techniques * Chapter-end problem sets are also included to assist readers in developing a practical understanding of CMP.