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Symmetry in Inorganic and Coordination Compounds

Symmetry in Inorganic and Coordination Compounds
Author: Franca Morazzoni
Publisher: Springer Nature
Total Pages: 196
Release: 2021-04-28
Genre: Science
ISBN: 3030629961

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This book addresses the nature of the chemical bond in inorganic and coordination compounds. In particular, it explains how general symmetry rules can describe chemical bond of simple inorganic molecules. Since the complexity of studying even simple molecules requires approximate methods, this book introduces a quantum mechanical treatment taking into account the geometric peculiarities of the chemical compound. In the case of inorganic molecules, a convenient approximation comes from symmetry, which constrains both the electronic energies and the chemical bonds. The book also gives special emphasis on symmetry rules and compares the use of symmetry operators with that of Hamiltonian operators. Where possible, the reactivity of molecules is also rationalized in terms of these symmetry properties. As practical examples, electronic spectroscopy and magnetism give experimental confirmation of the predicted electronic energy levels. Adapted from university lecture course notes, this book is the ideal companion for any inorganic chemistry course dealing with group theory.


Symmetry in Inorganic and Coordination Compounds

Symmetry in Inorganic and Coordination Compounds
Author: Franca Morazzoni
Publisher:
Total Pages: 0
Release: 2021
Genre:
ISBN: 9783030629977

Download Symmetry in Inorganic and Coordination Compounds Book in PDF, ePub and Kindle

This book addresses the nature of the chemical bond in inorganic and coordination compounds. In particular, it explains how general symmetry rules can describe chemical bond of simple inorganic molecules. Since the complexity of studying even simple molecules requires approximate methods, this book introduces a quantum mechanical treatment taking into account the geometric peculiarities of the chemical compound. In the case of inorganic molecules, a convenient approximation comes from symmetry, which constrains both the electronic energies and the chemical bonds. The book also gives special emphasis on symmetry rules and compares the use of symmetry operators with that of Hamiltonian operators. Where possible, the reactivity of molecules is also rationalized in terms of these symmetry properties. As practical examples, electronic spectroscopy and magnetism give experimental confirmation of the predicted electronic energy levels. Adapted from university lecture course notes, this book is the ideal companion for any inorganic chemistry course dealing with group theory.


symmetry In Coordination Chemistry

symmetry In Coordination Chemistry
Author: John P. Jr. Fackler
Publisher: Elsevier
Total Pages: 152
Release: 2012-12-02
Genre: Science
ISBN: 0323161006

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Symmetry in Coordination Chemistry provides a comprehensive discussion of molecular symmetry. It attempts to bridge the gap between the elementary ideas of bonding and structure learned by freshmen, and those more sophisticated concepts used by the practicing chemist. The book emphasizes the use of symmetry in describing the bonding and structure of transition metal coordination compounds. The book begins with a review of basic concepts such as molecular symmetry, coordination numbers, symmetry classification, and point group symmetry. This is followed by separate chapters on the electronic, atomic, and magnetic properties of d-block transition elements; the representation of orbital symmetries in a manner consistent with the point group of a molecule. Also included are discussions of vibrational symmetry; crystal field theory, ligand field theory, and molecular orbital theory; and the chemistry of a select few d-block transition elements and their compounds. This book is meant to supplement the traditional course work of junior-senior inorganic students. It is for them that the problems and examples have been chosen.


Symmetry and Spectroscopy of Molecules

Symmetry and Spectroscopy of Molecules
Author: K. Veera Reddy
Publisher: New Age International
Total Pages: 28
Release: 2007
Genre: Group theory
ISBN: 8122424511

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Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B

Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B
Author: Kazuo Nakamoto
Publisher: John Wiley & Sons
Total Pages: 400
Release: 2009-01-16
Genre: Science
ISBN: 9780470405871

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The 6th edition of this classic comprises the most comprehensive guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, it is extensively updated. Part B details applications of Raman and IR spectroscopy to larger and complex systems. It covers interactions of cisplatin and other metallodrugs with DNA and cytochrome c oxidase and peroxidase. This is a great reference for chemists and medical professionals working with infrared or Raman spectroscopies and for graduate students.


Low-Frequency Vibrations of Inorganic and Coordination Compounds

Low-Frequency Vibrations of Inorganic and Coordination Compounds
Author: John R. Ferraro
Publisher: Springer Science & Business Media
Total Pages: 316
Release: 2012-12-06
Genre: Science
ISBN: 1468418092

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During the course of far-infrared investigations of inorganic and coordina tion compounds at Argonne National Laboratory in the years 1962-1966, it became apparent that no suitable book existed which correlated and dis cussed the important vibrations occurring in this region for these molecules. Early in 1967 the initial steps were taken to write such a book. Then, in 1968, an excellent text by Professor David M. Adams entitled Metal-Ligand and Related Vibrations was published. At this point serious consideration was given to discontinuing work on this book. However, upon examination of Adams' book, it became clear that the references covered only the period to 1966. This field of research is accelerating so tremendously, and the period 1966-1969 has seen so many new studies, that upon reconsideration it was decided to continue writing this text. The references in this book, particularly in the last several chapters, include many papers published in 1969. However, the proliferation of the far-infrared literature has made it impossible to present all the published material that has any bearing on the subject. Many titles do not pertain primarily to the far-infrared region as such, and some of this research has been omitted for this reason. Organometallic compounds have been neglected since the author feels that adequate reviews of that subject are available. Other studies may be missing simply because, owing to space limitations, only the more important researches could be considered. Of course, "importance" may, in this case, reflect the author's interest and prejudices.


Symmetry in Chemical Theory

Symmetry in Chemical Theory
Author: John P. Fackler
Publisher:
Total Pages: 534
Release: 1973
Genre: Science
ISBN:

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Molecular Symmetry and Group Theory

Molecular Symmetry and Group Theory
Author: Robert L. Carter
Publisher: John Wiley & Sons
Total Pages: 326
Release: 1997-12-16
Genre: Science
ISBN: 0471149551

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A Thorough But Understandable Introduction To Molecular Symmetry And Group Theory As Applied To Chemical Problems! In a friendly, easy-to-understand style, this new book invites the reader to discover by example the power of symmetry arguments for understanding theoretical problems in chemistry. The author shows the evolution of ideas and demonstrates the centrality of symmetry and group theory to a complete understanding of the theory of structure and bonding. Plus, the book offers explicit demonstrations of the most effective techniques for applying group theory to chemical problems, including the tabular method of reducing representations and the use of group-subgroup relationships for dealing with infinite-order groups. Also Available From Wiley: * Concepts and Models of Inorganic Chemistry, 3/E, by Bodie E. Douglas, Darl H. McDaniel, and John J. Alexander 0-471-62978-2 * Basic Inorganic Chemistry, 3/E, by F. Albert Cotton, Paul Gaus, and Geoffrey Wilkinson 0-471-50532-3


Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A

Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A
Author: Kazuo Nakamoto
Publisher: John Wiley & Sons
Total Pages: 350
Release: 2008-12-22
Genre: Science
ISBN: 9780470405796

Download Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A Book in PDF, ePub and Kindle

The Sixth Edition of this classic work comprises the most comprehensive and current guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, this has been extensively updated. New topics include the theoretical calculations of vibrational frequencies (DFT method), chemical synthesis by matrix co-condensation reactions, time-resolved Raman spectroscopy, and more. This volume is a core reference for chemists and medical professionals working with infrared or Raman spectroscopies and an excellent textbook for graduate courses.