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Studies Toward Uranium(VI) and Chromium(III) Biochemical Speciation

Studies Toward Uranium(VI) and Chromium(III) Biochemical Speciation
Author: Wei Xie
Publisher:
Total Pages: 234
Release: 2009
Genre: Chromium
ISBN:

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This dissertation focuses on the bioinorganic chemistry of two metal ions, uranium(VI), as the uranyl cation, [UO22+], and chromium(III), in conditions designed to explore their biological speciation. The solution thermodynamic interactions of uranyl with amino acids and the kinetics of solvolysis of chromium(III) complexes were investigated. The formation of complexes of the uranyl cation [UO22+] with histidine, cysteine, tyrosine and their derivatives (N-acetylhistidine, N-acetyltyrosine, S-methylcysteine, and N-acetylcysteine) were determined by potentiometric, UV-visible, florescence, and NMR measurements. The interaction between these ligands and the uranyl cation is mainly through carboxylate donors. At 25°C, the cumulative formation constant for the uranyl histidine complex, [UO2(HisH2)(OH)2]+, is 8.53; the stepwise formation constant of the uranyl-histidine interaction is


Solution Studies of Uranium(VI) and Chromium(III) Biological Transport

Solution Studies of Uranium(VI) and Chromium(III) Biological Transport
Author: Huan Huang
Publisher:
Total Pages: 354
Release: 2006
Genre: Chromium
ISBN:

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Fundamental studies of metal-transport biochemistry are presented, with particular emphasis on two metal ions: uranium(VI), as the uranyl cation (UO22), and chromium(III). Solution thermodynamic interactions of uranyl peptide complexes and the kinetics of solvolysis of trinuclear chromium complexes were investigated. Solution studies indicate peptide-carboxylato donors can coordinate to the uranyl biscardonato complex [UO2(CO3)2]2−. The conditional association constants for uranyl carbonate peptide complexes were determined by NMR titration as follows: log K = 3.1 ± 0.4 for the [UO2(CO3)2DAHK]2− species, log K = 2.2 ± 0.4 for the [UO2(CO3)2GGH]− species. The biocoordination chemistry of uranyl cation was assessed utilizing X-ray structural data from the Protein Data Bank. Carboxylate donors from aspartate or glutamate in protein make up the majority of inner-sphere interactions with uranyl. The binding affinity between uranyl cation and histidine and N-acetyl histidine were determined by potentiometry as: log Kml


Biosorption of Heavy Metals

Biosorption of Heavy Metals
Author: Bohumil Volesky
Publisher: CRC Press
Total Pages: 414
Release: 1990-08-15
Genre: Science
ISBN: 9780849349171

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This state-of-the-art volume represents the first comprehensively written book which focuses on the new field of biosorption. This fascinating work conveys essential fundamental information and outlines the perspectives of biosorption. It summarizes the metal-sorbing properties of nonliving bacterial, fungal, and algal biomass, plus highlights relevant metal-binding mechanisms. This volume also discusses the aspects of obtaining and processing microbial biomass and metal-chelating chemicals into industrially applicable biosorbent products. Microbiologists, chemists, and engineers with an interest in new technological and scientific horizons will find this reference indispensable.


Metal Nanocomposites for Energy and Environmental Applications

Metal Nanocomposites for Energy and Environmental Applications
Author: Swatantra P. Singh
Publisher: Springer Nature
Total Pages: 529
Release: 2022-01-11
Genre: Technology & Engineering
ISBN: 9811685991

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This book focuses on recent developments in metal nanomaterials and nanocomposites for energy and environmental application such as pollution control in water, air, and soil pollution. The chapters incorporate carbon-based, metal-based and metal-organic framework based nanomaterials and nanocomposites for emerging contaminants (pharmaceuticals and microplastics) and other traditional pollutants remediation along with energy storage, sensing of air and water polutents and carbon capture & storage (CCS). This book will be of interest to those in academia and industry involved in energy and environmental science & engineering research.


Cellular Effects of Heavy Metals

Cellular Effects of Heavy Metals
Author: Gaspar Banfalvi
Publisher: Springer Science & Business Media
Total Pages: 348
Release: 2011-03-02
Genre: Medical
ISBN: 9400704283

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The term “heavy metals” is used as a group name of toxic metals and metalloids (semimetals) causing contaminations and ecotoxicity. In strict chemical sense the density of heavy metals is higher than 5 g/cm3. From biological point of view as microelements they can be divided into two major groups. a. For their physiological function organisms and cells require essential microelements such as iron, chromium (III), cobalt, copper, manganese, molidenium, zinc. b. The other group of heavy metals is toxic to the health or environment. Of highest concern are the emissions of As, Cd, Co, Cu, Hg, Mn, Ni, Pb, Sn, Tl. The toxicity of heavy metals is well known at organizational level, while less attention has been paid to their cellular effects. This book describes the toxicity of heavy metals on microorganisms, yeast, plant and animal cells. Other chapters of the book deal with their genotoxic, mutagenic and carcinogenic effects. The toxicity of several metals touch upon the aspects of environmental hazard, ecosystems and human health. Among the cellular responses of heavy metals irregularities in cellular mechanisms such as gene expression, protein folding, stress signaling pathways are among the most important ones. The final chapters deal with biosensors and removal of heavy metals. As everybody is eating, drinking and exposed to heavy metals on a daily basis, the spirit of the book will attract a wide audience.


Supramolecular Chemistry in the 3rd Millennium

Supramolecular Chemistry in the 3rd Millennium
Author: Catherine E. Housecroft
Publisher: MDPI
Total Pages: 264
Release: 2021-08-18
Genre: Science
ISBN: 3036514635

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This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as 'chemistry beyond the molecule' (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.


Practical Applications of Medical Geology

Practical Applications of Medical Geology
Author: Malcolm Siegel
Publisher:
Total Pages: 0
Release: 2021
Genre:
ISBN: 9783030538941

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This edited volume provides a framework for integrating methods and information drawn from geological and medical sciences and provides case studies in medical geology to illustrate the usefulness of this framework for crafting environmental and public health policies related to natural materials. The relevance of medical geology research to policy decisions is a topic rarely discussed, and this volume attempts to be a unique source for researchers and policy makers in the field of medical geology in addressing this gap in practical medical geology applications. The book's four sections establish this framework in detail using risk assessment, case studies, data analyses and specific medical geology techniques. Following an introduction to medical geology in the context of risk assessment and risk management, the second section discusses specific methods used in medical geology in the categories of geoscience, biomedicine, and data sources. The third section discusses the medical geology of natural materials, energy use, and environmental and workplace impacts. This section includes specific case studies in medical geology, and describes how the methods and data from the previous section are used in a medical geology analysis. The fourth section includes a guide to the medical geology literature and provides some examples of medical geology programs in Asia and Africa.


Low-Temperature Geochemistry

Low-Temperature Geochemistry
Author: Tu Guangzhi
Publisher: VSP
Total Pages: 224
Release: 1996-12
Genre: Science
ISBN: 9789067642309

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Low-temperature geochemistry -- a 'hot topic' in geochemistry at present -- deals with geological and chemical processes and the geochemical evolution of elements in nature below 200C, including the geochemical behaviour of elements in the processes of their extraction, remobilization, transport and mineralization at room temperature and below 0C. This book focuses on the low-temperature geochemical behaviour of precious metals, REE, some individual dispersed elements and some non-metallic elements and their minergenesis at low-temperatures. The book deals with the following topics: 1) geochemistry of selected low-temperature deposits or prospects (horizons); 2) geochemistry of elements during diagenesis, buried metamorphism and low-grade metamorphism; 3) remobilization, transport and precipitation of some ore-forming elements under low-temperature conditions; 4) water/rock interactions in low-temperature open systems


Heavy Metals and Other Pollutants in the Environment

Heavy Metals and Other Pollutants in the Environment
Author: Gennady E. Zaikov
Publisher: CRC Press
Total Pages: 438
Release: 2017-07-20
Genre: Science
ISBN: 177188438X

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This important new volume presents a plethora of research on the distribution of heavy metals in soils and rocks of natural habitats, farmlands, and urbanized areas along with the factors influencing their bioavailability. The authors evaluate the content of organic matter, soil acidity, mineral fertilizers, and more. Developed for ecologists and specialists in the field of environmental protection and the conservation of biological diversity, the book presents the problems of reducing the anthropogenic load on the surrounding countryside and focuses on sustainable agricultural development.


Ion Exchange Technology I

Ion Exchange Technology I
Author: Inamuddin Dr.
Publisher: Springer Science & Business Media
Total Pages: 561
Release: 2012-06-02
Genre: Science
ISBN: 9400717008

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Ion-exchange Technology I: Theory and Materials describes the theoretical principles of ion-exchange processes. More specifically, this volume focuses on the synthesis, characterization, and modelling of ion-exchange materials and their associated kinetics and equilibria. This title is a highly valuable source not only to postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology as well as to engineers and industrialists.