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Structure and Dynamics of Confined Polymers

Structure and Dynamics of Confined Polymers
Author: John J. Kasianowicz
Publisher: Springer Science & Business Media
Total Pages: 46
Release: 2002-07-31
Genre: Science
ISBN: 9781402006975

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Polymers are essential to biology because they can have enough stable degrees of freedom to store the molecular code of heredity and to express the sequences needed to manufacture new molecules. Through these they perform or control virtually every function in life. Although some biopolymers are created and spend their entire career in the relatively large free space inside cells or organelles, many biopolymers must migrate through a narrow passageway to get to their targeted destination. This suggests the questions: How does confining a polymer affect its behavior and function? What does that tell us about the interactions between the monomers that comprise the polymer and the molecules that confine it? Can we design and build devices that mimic the functions of these nanoscale systems? The NATO Advanced Research Workshop brought together for four days in Bikal, Hungary over forty experts in experimental and theoretical biophysics, molecular biology, biophysical chemistry, and biochemistry interested in these questions. Their papers collected in this book provide insight on biological processes involving confinement and form a basis for new biotechnological applications using polymers. In his paper Edmund DiMarzio asks: What is so special about polymers? Why are polymers so prevalent in living things? The chemist says the reason is that a protein made of N amino acids can have any of 20 different kinds at each position along the chain, resulting in 20 N different polymers, and that the complexity of life lies in this variety.


Structure and Dynamics of Polymer and Colloidal Systems

Structure and Dynamics of Polymer and Colloidal Systems
Author: Redouane Borsali
Publisher: Springer Science & Business Media
Total Pages: 478
Release: 2012-12-06
Genre: Science
ISBN: 9401004420

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This volume is based on lectures given at the NATO-Advanced Study Institute on Structure and Dynamics of Polymer and Colloid Systems held in Les Houches, France from September 14-24, 1999. The meeting arose from a perceived need to bring together scientists studying the polymer and colloid fields. Although these fields are intertwined and share many techniques (e. g. , light, neutron and x-ray scattering), it is remarkable how little the approaches and concepts used by the one field penetrate the other. For instance, the theory of spherical colloids is very highly developed and many of the concepts developed for these systems can be extended to those with non-spherical morphology, such as solutions of rigid rod polymers. In addition, mixtures of polymers and colloids, both in the bulk and at interfaces, are the basis for many industrial products. Methods are now rapidly being developed for understanding the structure and dynamics in polymer/colloid mixtures at the molecular level, but the point of view of the colloid scientist is often rather different from that of the polymer scientist. The NATO-ASI brought together polymer and colloid scientists, including many young researchers, who presented and discussed recent developments in these fields and the possibilities for cross-fertilization This volume contains articles on a wide variety of topics at the research forefront of the polymer and colloid fields by some of the world's foremost experts at a level accessible to graduate students, post-docs and researchers.


Structure and Dynamics of Confined Polymers

Structure and Dynamics of Confined Polymers
Author: John J. Kasianowicz
Publisher: Springer Science & Business Media
Total Pages: 394
Release: 2012-12-06
Genre: Science
ISBN: 9401004013

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Polymers are essential to biology because they can have enough stable degrees of freedom to store the molecular code of heredity and to express the sequences needed to manufacture new molecules. Through these they perform or control virtually every function in life. Although some biopolymers are created and spend their entire career in the relatively large free space inside cells or organelles, many biopolymers must migrate through a narrow passageway to get to their targeted destination. This suggests the questions: How does confining a polymer affect its behavior and function? What does that tell us about the interactions between the monomers that comprise the polymer and the molecules that confine it? Can we design and build devices that mimic the functions of these nanoscale systems? The NATO Advanced Research Workshop brought together for four days in Bikal, Hungary over forty experts in experimental and theoretical biophysics, molecular biology, biophysical chemistry, and biochemistry interested in these questions. Their papers collected in this book provide insight on biological processes involving confinement and form a basis for new biotechnological applications using polymers. In his paper Edmund DiMarzio asks: What is so special about polymers? Why are polymers so prevalent in living things? The chemist says the reason is that a protein made of N amino acids can have any of 20 different kinds at each position along the chain, resulting in 20 N different polymers, and that the complexity of life lies in this variety.


Polymer Dynamics and Relaxation

Polymer Dynamics and Relaxation
Author: Richard Boyd
Publisher: Cambridge University Press
Total Pages: 369
Release: 2007-09-13
Genre: Technology & Engineering
ISBN: 1107320259

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Polymers exhibit a range of physical characteristics, from rubber-like elasticity to the glassy state. These particular properties are controlled at the molecular level by the mobility of the structural constituents. Remarkable changes in mobility can be witnessed with temperature, over narrow, well defined regions, termed relaxation processes. This is an important, unique phenomenon controlling polymer transition behaviour and is described here at an introductory level. The important types of relaxation processes from amorphous to crystalline polymers and polymeric miscible blends are covered, in conjunction with the broad spectrum of experimental methods used to study them. In-depth discussion of molecular level interpretation, including atomistic level computer simulations and applications to molecular mechanism elucidation, are discussed. The result is a self-contained approach to polymeric interpretation suitable for researchers in materials science, physics and chemistry interested in the relaxation processes of polymeric systems.


Polyrotaxane and Slide-Ring Materials

Polyrotaxane and Slide-Ring Materials
Author: Kohzo Ito
Publisher: Royal Society of Chemistry
Total Pages: 216
Release: 2016
Genre: Science
ISBN: 1849739331

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The first book to cover the fundamentals and applications of polyrotaxane and slide-ring materials authored by their inventor.


The Theory of Polymer Dynamics

The Theory of Polymer Dynamics
Author: Masao Doi
Publisher: Oxford University Press
Total Pages: 420
Release: 1988
Genre: Science
ISBN: 9780198520337

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This book provides a comprehensive account of the modern theory for the dynamical properties of polymer solutions. The theory has undergone dramatic evolution over the last two decades due to the introduction of new methods and concepts that have extended the frontier of theory from dilute solutions in which polymers move independently to concentrated solutions where many polymers converge. Among the properties examined are viscoelasticity, diffusion, dynamic light scattering, and electric birefringence. Nonlinear viscoelasticity is discussed in detail on the basis of molecular dynamical models. The book bridges the gap between classical theory and new developments, creating a consistent picture of polymer solution dynamics over the entire concentration range.


The Physics of Deformation and Fracture of Polymers

The Physics of Deformation and Fracture of Polymers
Author: A. S. Argon
Publisher: Cambridge University Press
Total Pages: 535
Release: 2013-03-07
Genre: Science
ISBN: 0521821843

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A physical, mechanism-based presentation of the plasticity and fracture of polymers, covering industrial scale applications through to nanoscale biofluidic devices.


Structure and Dynamics of Bulk Polymers by NMR-Methods

Structure and Dynamics of Bulk Polymers by NMR-Methods
Author: Vladimir D. Fedotov
Publisher: Springer
Total Pages: 176
Release: 2011-12-27
Genre: Science
ISBN: 9783642739859

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In recent years the development of the NMR method has been closely linked to the creation of the theory of the NMR in solids and with the elaboration on their basic principles and methods of high resolution in solids. The aim of this volume is to explain simply and clearly the principles for the understanding of the NMR in solid polymers, to show what kind of information can be gained using NMR investigations of bulk polymers, and to demonstrate the ways of obtaining this information, their correctness and their place in comparison with other methods. The discussion is restricted to the most important and typical nuclei 1H, 13C, and (briefly) 2D, and, in connection with that, to the dipolar and quadrupolar interaction and to the chemical shift.


Molecular Dynamics of Additives in Polymers

Molecular Dynamics of Additives in Polymers
Author: A. L. Kovarski
Publisher: VSP
Total Pages: 292
Release: 1997
Genre: Technology & Engineering
ISBN: 9789067642590

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This volume focuses on the dynamical behaviour of low-molecular additives in solid polymer matrixes. It covers: types and models of molecular motion in condensed media; dependence of motional frequency on particle structure and size, temperature, volume and stress; and polymer properties and polymeric structures. Extensive analysis of common regularities of rotational and translational dynamics of molecules introduced into polymers are given. The book also includes experimental techniques for molecular mobility evaluation, and features detailed data on rotational dynamics of additives. It should be of interest to specialists in various fields of polymer physical chemistry and materials science.