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Structural Glasses and Supercooled Liquids

Structural Glasses and Supercooled Liquids
Author: Peter G. Wolynes
Publisher: John Wiley & Sons
Total Pages: 422
Release: 2012-04-10
Genre: Science
ISBN: 0470452234

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With contributions from 24 global experts in diverse fields, and edited by world-recognized leaders in physical chemistry, chemical physics and biophysics, Structural Glasses and Supercooled Liquids: Theory, Experiment, and Applications presents a modern, complete survey of glassy phenomena in many systems based on firmly established characteristics of the underlying molecular motions as deduced by first principle theoretical calculations, or with direct/single-molecule experimental techniques. A well-rounded view of a variety of disordered systems where cooperative phenomena, which are epitomized by supercooled liquids, take place is provided. These systems include structural glasses and supercooled liquids, polymers, complex liquids, protein conformational dynamics, and strongly interacting electron systems with quenched/self-generated disorder. Detailed calculations and reasoned arguments closely corresponding with experimental data are included, making the book accessible to an educated non-expert reader.


Structural Glasses and Supercooled Liquids

Structural Glasses and Supercooled Liquids
Author: Peter G. Wolynes
Publisher: John Wiley & Sons
Total Pages: 422
Release: 2012-03-12
Genre: Science
ISBN: 1118202414

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With contributions from 24 global experts in diverse fields, and edited by world-recognized leaders in physical chemistry, chemical physics and biophysics, Structural Glasses and Supercooled Liquids: Theory, Experiment, and Applications presents a modern, complete survey of glassy phenomena in many systems based on firmly established characteristics of the underlying molecular motions as deduced by first principle theoretical calculations, or with direct/single-molecule experimental techniques. A well-rounded view of a variety of disordered systems where cooperative phenomena, which are epitomized by supercooled liquids, take place is provided. These systems include structural glasses and supercooled liquids, polymers, complex liquids, protein conformational dynamics, and strongly interacting electron systems with quenched/self-generated disorder. Detailed calculations and reasoned arguments closely corresponding with experimental data are included, making the book accessible to an educated non-expert reader.


Supercooled Liquids, Glass Transition and Bulk Metallic Glasses: Volume 754

Supercooled Liquids, Glass Transition and Bulk Metallic Glasses: Volume 754
Author: Takeshi Egami
Publisher:
Total Pages: 512
Release: 2003-07-16
Genre: Science
ISBN:

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There has been a renaissance in glass science brought about by the development of concepts such as fragility index and the energy landscape with megabasins. Research on bulk metallic glasses has been explosive since their advent when MRS offered its first book on the topic. In 2000, a second book broadened the scope to include supercooled liquid, bulk glassy and nanocrystalline states. This book enhances the scope to include glass transition in diverse materials such as water, silicate and polymeric melts. Bringing these threads together in an interdisciplinary manner was fruitful and offers proof that while there is much common ground, gaps between various approaches to the glassy state remain to be bridged. Subjects include: the supercooled liquid; glass formability; structural relaxation and dynamics; structure determination and modeling; processing and applications of bulk metallic glasses; mechanical properties; mechanical properties - composites; crystallization; electronic and magnetic structure and properties; and nanoparticles and nonmetallic glasses.


Fundamentals of Inorganic Glasses

Fundamentals of Inorganic Glasses
Author: Arun K. Varshneya
Publisher: Elsevier
Total Pages: 753
Release: 2019-05-09
Genre: Science
ISBN: 0128162260

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Fundamentals of Inorganic Glasses, Third Edition, is a comprehensive reference on the field of glass science and engineering that covers numerous, significant advances. This new edition includes the most recent advances in glass physics and chemistry, also discussing groundbreaking applications of glassy materials. It is suitable for upper level glass science courses and professional glass scientists and engineers at industrial and government labs. Fundamental concepts, chapter-ending problem sets, an emphasis on key ideas, and timely notes on suggested readings are all included. The book provides the breadth required of a comprehensive reference, offering coverage of the composition, structure and properties of inorganic glasses. Clearly develops fundamental concepts and the basics of glass science and glass chemistry Provides a comprehensive discussion of the composition, structure and properties of inorganic glasses Features a discussion of the emerging applications of glass, including applications in energy, environment, pharmaceuticals, and more Concludes chapters with problem sets and suggested readings to facilitate self-study


Jamming and Glass Transitions

Jamming and Glass Transitions
Author: Ada Altieri
Publisher: Springer Nature
Total Pages: 220
Release: 2019-08-28
Genre: Science
ISBN: 3030236005

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The work described in this book originates from a major effort to develop a fundamental theory of the glass and the jamming transitions. The first chapters guide the reader through the phenomenology of supercooled liquids and structural glasses and provide the tools to analyze the most frequently used models able to predict the complex behavior of such systems. A fundamental outcome is a detailed theoretical derivation of an effective thermodynamic potential, along with the study of anomalous vibrational properties of sphere systems. The interested reader can find in these pages a clear and deep analysis of mean-field models as well as the description of advanced beyond-mean-field perturbative expansions. To investigate important second-order phase transitions in lattice models, the last part of the book proposes an innovative theoretical approach, based on a multi-layer construction. The different methods developed in this thesis shed new light on important connections among constraint satisfaction problems, jamming and critical phenomena in complex systems, and lay part of the groundwork for a complete theory of amorphous solids.


Encyclopedia of Glass Science, Technology, History, and Culture, 2 Volume Set

Encyclopedia of Glass Science, Technology, History, and Culture, 2 Volume Set
Author: Pascal Richet
Publisher: John Wiley & Sons
Total Pages: 1573
Release: 2021-03-16
Genre: Technology & Engineering
ISBN: 1118799429

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A comprehensive and up-to-date encyclopedia to the fabrication, nature, properties, uses, and history of glass The Encyclopedia of Glass Science, Technology, History, and Culture has been designed to satisfy the needs and curiosity of a broad audience interested in the most varied aspects of material that is as old as the universe. As described in over 100 chapters and illustrated with 1100 figures, the practical importance of glass has increased over the ages since it was first man-made four millennia ago. The old-age glass vessels and window and stained glass now coexist with new high-tech products that include for example optical fibers, thin films, metallic, bioactive and hybrid organic-inorganic glasses, amorphous ices or all-solid-state batteries. In the form of scholarly introductions, the Encyclopedia chapters have been written by 151 noted experts working in 23 countries. They present at a consistent level and in a self-consistent manner these industrial, technological, scientific, historical and cultural aspects. Addressing the most recent fundamental advances in glass science and technology, as well as rapidly developing topics such as extra-terrestrial or biogenic glasses, this important guide: Begins with industrial glassmaking Turns to glass structure and to physical, transport and chemical properties Deals with interactions with light, inorganic glass families and organically related glasses Considers a variety of environmental and energy issues And concludes with a long section on the history of glass as a material from Prehistory to modern glass science The Encyclopedia of Glass Science, Technology, History, and Culture has been written not only for glass scientists and engineers in academia and industry, but also for material scientists as well as for art and industry historians. It represents a must-have, comprehensive guide to the myriad aspects this truly outstanding state of matter.


Glass Transition on Cooling and Aging for Structural Glasses

Glass Transition on Cooling and Aging for Structural Glasses
Author: Hiroshi Kobayashi
Publisher: Eliva Press
Total Pages: 0
Release: 2023-01-12
Genre:
ISBN: 9789994985494

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Glass is out of equilibrium and reduces into an equilibrium solid. This whole process is a thermodynamical phase transition, while the so-called glass transition is an observable transition with no changes in structure. We describe that the glass transition is a purely kinetic phenomenon due to strong fluctuations in molecular configurations in supercooled liquid. Intermediate-range orders (IROs) have important roles on the glass transition process which is explained by the embryo and freezing of IROs. We conclude that the glass transition is an emergence of a new system of glass in a nonequilibrium state and a glass is a nanomaterial which is composed of a periodic nano-structure of IROs. The mean field theory introduced the random first order transition (RFOT) as the ideal glass transition which prevents the Kauzmann paradox. Recently, an ideal glass was realized using silicate glass during long aging below the Kauzmann temperature. An ideal glass is a nanomaterial which is composed of a periodic nano-structure of intermediate-range orders in an amorphous phase. The results identified the (spontaneous) dissipative structure as an equilibrium state of an ideal glass. An ideal glass is a temporal steady state toward the ground state of materials, which is a polycrystal.


Metastable Glassy States Under External Perturbations

Metastable Glassy States Under External Perturbations
Author: Corrado Rainone
Publisher: Springer
Total Pages: 209
Release: 2017-06-27
Genre: Science
ISBN: 3319604236

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This thesis presents a theoretical analysis of the behavior of glasses under external perturbations, i.e. compression and shear straining. Written in a pedagogical style, it explains every facet of the problem in detail, including many crucial steps that cannot be found in the existing literature—making it particularly useful for students and as an introduction to the subject of glassy physics. In glassy systems the behavior under external compression and shear-strain is quite peculiar. Many complex phenomena are observed and grasping them fully would be a major step toward a complete theory of the glass transition. This thesis makes important advances in this direction, analyzing the behavior of glassy states in painstaking detail and reproducing it in the framework of a recently developed mean field theory for glasses that has proven extremely successful for jamming, demonstrating its predictive power in the context of metastable glassy states obtained through nonequilibrium protocols.


Dynamical Heterogeneities in Glasses, Colloids, and Granular Media

Dynamical Heterogeneities in Glasses, Colloids, and Granular Media
Author: Ludovic Berthier
Publisher: OUP Oxford
Total Pages: 464
Release: 2011-07-14
Genre: Science
ISBN: 0191621307

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Most of the solid materials we use in everyday life, from plastics to cosmetic gels exist under a non-crystalline, amorphous form: they are glasses. Yet, we are still seeking a fundamental explanation as to what glasses really are and to why they form. In this book, we survey the most recent theoretical and experimental research dealing with glassy physics, from molecular to colloidal glasses and granular media. Leading experts in this field present broad and original perspectives on one of the deepest mysteries of condensed matter physics, with an emphasis on the key role played by heterogeneities in the dynamics of glassiness.