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Structural Chemistry of Inorganic Actinide Compounds

Structural Chemistry of Inorganic Actinide Compounds
Author: Sergey Krivovichev
Publisher: Elsevier
Total Pages: 504
Release: 2006-12-08
Genre: Science
ISBN: 9780080467917

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Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions. * Covers over 2,000 actinide compounds including materials, minerals and coordination polymers * Summarizes recent achievements in the field * Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'


The Chemistry of the Actinides

The Chemistry of the Actinides
Author: S. Ahrland
Publisher: Elsevier
Total Pages: 656
Release: 2016-06-07
Genre: Science
ISBN: 1483159345

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The Chemistry of the Actinides contains selected chapters from the Comprehensive Inorganic Chemistry to meet the needs of certain specialists in this field. The book describes the 14 elements after actinium in the Periodic Table, known as the actinide elements or the 5f transition series. The book notes the occurrence, separation, chemical properties, chemical structures, and preparation of the metals. In a discussion of analytical chemistry, the radioactive properties of the actinides and the lanthanides are compared. The text then describes the nuclear or radiochemical records and chemical properties of the different members of the actinide series such as thorium, uranium, plutonium, and einsteinium. The book also explains the differences between the 5f shell and the 4f shell. One paper then discusses the groups of alloy compounds, including rare earths and intra-actinides. Another paper examines the general properties of actinide ions as to their electronic structure and oxidation states; the stability and preparation of the different oxidation states; and the applicability of solvent extraction in separating and purifying various substances. The text is suitable for researchers in organic chemistry, nuclear and atomic physicists, scientists, and academicians whose work involves radioactive materials.


Structural Chemistry across the Periodic Table

Structural Chemistry across the Periodic Table
Author: Thomas CW Mak
Publisher: Oxford University Press
Total Pages: 593
Release: 2023-10-12
Genre: Science
ISBN: 0198872968

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This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).


Lanthanide and Actinide Chemistry

Lanthanide and Actinide Chemistry
Author: Simon Cotton
Publisher: John Wiley & Sons
Total Pages: 308
Release: 2013-03-15
Genre: Science
ISBN: 1118681363

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The only introduction into the exciting chemistry of Lanthanides and Actinides. The book is based on a number of courses on "f elements" The author has a long experience in teaching this field of chemistry Lanthanides have become very common elements in research and technology applications; this book offers the basic knowledge The book offers insights into a vast range of applications, from lasers to synthesis The Inorganic Chemistry: A Textbook series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry. Lanthanide and Actinide Chemistry is a one-volume account of the Lanthanides (including scandium and yttrium), the Actinides and the Transactinide elements, intended as an introductory treatment for undergraduate and postgraduate students. The principal features of these elements are set out in detail, enabling clear comparison and contrast with the Transition Elements and Main Group metals. The book covers the extraction of the elements from their ores and their purification, as well as the synthesis of the man-made elements; the properties of the elements and principal binary compounds; detailed accounts of their coordination chemistry and organometallic chemistry, from both preparative and structural viewpoints, with a clear explanation of the factors responsible for the adoption of particular coordination numbers; spectroscopy and magnetism, especially for the lanthanides, with case studies and accounts of applications in areas like magnetic resonance imaging, lasers and luminescence; nuclear separations and problems in waste disposal for the radioactive elements, particularly in the context of plutonium. Latest developments are covered in areas like the synthesis of the latest man-made elements, whilst there is a whole chapter on the application of lanthanide compounds in synthetic organic chemistry. End-of-chapter questions suitable for tutorial discussions are provided, whilst there is a very comprehensive bibliography providing ready access to further reading on all topics.


Actinide Nanoparticle Research

Actinide Nanoparticle Research
Author: Stepan N. Kalmykov
Publisher: Springer Science & Business Media
Total Pages: 448
Release: 2011-06-17
Genre: Science
ISBN: 3642114326

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This is the first book to cover actinide nano research. It is of interest both for fundamental research into the chemistry and physics of f-block elements as well as for applied researchers such as those studying the long-term safety of nuclear waste disposal and developing remediation strategies. The authors cover important issues of the formation of actinide nano-particles, their properties and structure, environmental behavior of colloids and nanoparticles related to the safe disposal of nuclear wastes, modeling and advanced methods of characterization at the nano-scale.


The Chemistry of the Actinide Elements

The Chemistry of the Actinide Elements
Author: G.T. Seaborg
Publisher: Springer Science & Business Media
Total Pages: 905
Release: 2012-12-06
Genre: Science
ISBN: 9400931557

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The first edition of this work appeared almost thirty years ago, when, as we can see in retrospect, the study of the actinide elements was in its first bloom. Although the broad features of the chemistry of the actinide elements were by then quite well delineated, the treatment of the subject in the first edition was of necessity largely descriptive in nature. A detailed understanding of the chemical consequences of the characteristic presence of Sf electrons in most of the members of the actinide series was still for the future, and many of the systematic features of the actinide elements were only dimly apprehended. In the past thirty years all this has changed. The application of new spectroscopic techniques, which came into general use during this period, and new theoretical insights, which came from a better understanding of chemical bonding, inorganic chemistry, and solid state phenomena, were among the important factors that led to a great expansion and maturation in actinide element research and a large number of new and important findings. The first edition consisted of a serial description of the individual actinide elements, with a single chapter devoted to the six heaviest elements (lawrencium, the heaviest actinide, was yet to be discovered). Less than 15 % of the text was devoted to a consideration of the systematics of the actinide elements.


Structural Crystallography of Inorganic Oxysalts

Structural Crystallography of Inorganic Oxysalts
Author: Sergey V. Krivovichev
Publisher: Oxford University Press
Total Pages: 323
Release: 2009
Genre: Nature
ISBN: 0199213208

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Inorganic oxysalts are chemical compounds that contain oxygen - the most abundant element in the Earth's core. This book is the first systematic survey of structures of inorganic oxysalts considered from the viewpoint of modern scientific methods of description and visualization of complex atomic arrangements.


Structural Chemistry Across the Periodic Table

Structural Chemistry Across the Periodic Table
Author: Emeritus Professor and Wei Lun Research Professor Thomas Cw Mak
Publisher: Oxford University Press
Total Pages: 593
Release: 2023-10-12
Genre: Chemistry, Inorganic
ISBN: 019887295X

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This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).