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Strong and Ultrastrong Light-matter Interactions in Multilayer Optical Organic Nanostructures

Strong and Ultrastrong Light-matter Interactions in Multilayer Optical Organic Nanostructures
Author: Bin Liu
Publisher:
Total Pages: 152
Release: 2018
Genre: Nanostructures
ISBN:

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Light-matter interactions in multilayer organic nanostructures give rise to an abundance of interesting phenomena, and provide a functional platform for useful optical devices with sophisticated designs via fine control of the optical properties of the constituent materials and the thicknesses of each layers. This thesis focuses on the theoretical and experimental study of linear and nonlinear optical (NLO) properties of multilayer organic nanostructures in order to characterize the interaction between light and matter within the multilayer structure from a fundamental point of view, and to improve the linear and NLO efficiency of layered devices for practical applications.Metallic Fabry-Perot cavities filled with organic materials, as a typical multilayer structure, demonstrate strong and ultrastrong light-matter interaction, where hybrid quantum states known as cavity polaritons are formed. Moreover, compared to strongly coupled exciton-photon cavities, double organic cavities exhibit interesting optical properties in the ultrastrong coupling regime, yielding a broken degeneracy of vacuum Rabi splittings due to breaking of the rotating wave approximation (RWA). For the NLO properties, resonant third-harmonic generation (THG) can be enhanced by cavity polariton states, and THG intensity is seen to be larger when the polariton state is more exciton-like.Two-dimensional (2D) perovskite-based planar photovoltaic cells, as another typical multilayer structure, exhibit greatly improved environmental stability and photostability under operating conditions comparing with their 3D counterparts. We have investigated and designed devices using optical modeling. The absorption in the photoactive layer can be enhanced due to light-matter interaction in multilayer structures by carefully designing the layer thicknesses. In addition, using a modied drift-diffusion model, charge-carrier recombination is studied, which limits to the device performance of modest-mobility perovskite solar cells, while depending on the layer thickness. Therefore, the thickness optimization is investigated considering both aspects, which guides device fabrication with high power-conversion efficiencies.Coextruded multilayered polymer lms containing a NLO chromophore, a new alignment strategy for NLO chromophore, are studied by the second-harmonic generation (SHG) technique, which give rise to a second-order nonlinear optical response.


Light-Matter Interaction

Light-Matter Interaction
Author: John Weiner
Publisher: Oxford University Press, USA
Total Pages: 277
Release: 2013
Genre: Medical
ISBN: 0198567669

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This book draws together the essential elements of classical electrodynamics, surface wave physics, plasmonic materials, and circuit theory of electrical engineering to provide insight into the essential physics of nanoscale light-matter interaction and to provide design methodology for practical nanoscale plasmonic devices. A chapter on classical and quantal radiation also highlights the similarities (and differences) between the classical fields of Maxwell's equations and the wave functions of Schrödinger's equation. The aim of this chapter is to provide a semiclassical picture of atomic absorption and emission of radiation, lending credence and physical plausibility to the "rules" of standard wave-mechanical calculations. The structure of the book is designed around five principal chapters, but many of the chapters have extensive "complements" that either treat important digressions from the main body or penetrate deeper into some fundamental issue. Furthermore, at the end of the book are several appendices to provide readers with a convenient reference for frequently-occurring special functions and explanations of the analytical tools, such as vector calculus and phasors, needed to express important results in electromagnetics and waveguide theory.


Nano-Optics for Enhancing Light-Matter Interactions on a Molecular Scale

Nano-Optics for Enhancing Light-Matter Interactions on a Molecular Scale
Author: Baldassare Di Bartolo
Publisher: Springer
Total Pages: 470
Release: 2012-12-04
Genre: Science
ISBN: 9400753136

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This volume presents a considerable number of interrelated contributions dealing with the new scientific ability to shape and control matter and electromagnetic fields on a sub-wavelength scale. The topics range from the fundamental ones, such as photonic metamateriials, plasmonics and sub-wavelength resolution to the more applicative, such as detection of single molecules, tomography on a micro-chip, fluorescence spectroscopy of biological systems, coherent control of biomolecules, biosensing of single proteins, terahertz spectroscopy of nanoparticles, rare earth ion-doped nanoparticles, random lasing, and nanocoax array architecture. The various subjects bridge over the disciplines of physics, biology and chemistry, making this volume of interest to people working in these fields. The emphasis is on the principles behind each technique and on examining the full potential of each technique. The contributions that appear in this volume were presented at a NATO Advanced Study Institute that was held in Erice, Italy, 3-18 July, 2011. The pedagogical aspect of the Institute is reflected in the topics presented in this volume.


Strong Atom-light Interactions Along Nanostructures: Transition from Free-space to Nanophotonic Interfaces

Strong Atom-light Interactions Along Nanostructures: Transition from Free-space to Nanophotonic Interfaces
Author: Akihisa Goban
Publisher:
Total Pages: 288
Release: 2015
Genre: Electronic dissertations
ISBN:

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An exciting frontier in quantum information science is the integration of otherwise "simple'' quantum elements into complex quantum networks. The laboratory realization of even small quantum networks enables the exploration of physical systems that have not heretofore existed in the natural world. Within this context, there is active research to achieve nanoscale quantum optical circuits, for which atoms are trapped near nano-scopic dielectric structures and "wired'' together by photons propagating through the circuit elements. Single atoms and atomic ensembles endow quantum functionality for otherwise linear optical circuits and thereby enable the capability of building quantum networks component by component. Toward these goals, we have experimentally investigated three different systems, from conventional to rather exotic systems : free-space atomic ensembles, optical nano fibers, and photonics crystal waveguides. First, we demonstrate measurement-induced quadripartite entanglement among four quantum memories. Next, following the landmark realization of a nanofiber trap, we demonstrate the implementation of a state-insensitive, compensated nanofiber trap. Finally, we reach more exotic systems based on photonics crystal devices. Beyond conventional topologies of resonators and waveguides, new opportunities emerge from the powerful capabilities of dispersion and modal engineering in photonic crystal waveguides. We have implemented an integrated optical circuit with a photonics crystal waveguide capable of both trapping and interfacing atoms with guided photons, and have observed the collective effect, superradiance, mediated by the guided photons. These advances provide an important capability for engineered light-matter interactions, enabling explorations of novel quantum transport and quantum many-body phenomena.


Light-matter Interactions in Plasmonic Arrays, Two Dimensional Materials and Their Hybrid Nanostructures

Light-matter Interactions in Plasmonic Arrays, Two Dimensional Materials and Their Hybrid Nanostructures
Author:
Publisher:
Total Pages:
Release: 2019
Genre:
ISBN:

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Abstract : The complementary optical properties of metal and semiconductor materials make them attractive for many applications that require the electromagnetic fields down to the nanoscale. The electronic, optical and mechanical properties of metal and semiconductor nanostructures could be controlled by the size, shape and local dielectric environment. In this dissertation, I focus on the study of the light-matter interactions in plasmonic nanostructures, two-dimensional (2D) materials, as well as their hybrid nanostructures. In the plasmonic nanostructures, square and hexagonal Au hollow nanodome film arrays were fabricated by means of anodized alumina oxide (AAO) templates. Both the nanostructures can support surface plasmon polaritons (SPPs) of strong air-Au and weak Au-glass modes in the light dispersions. The periodic geometries of the nanostructures could control the mode crossings of distinct SPPs. Decreasing the cross-sectional heights of the continuous and hierarchical hexagonal hollow nanodome arrays leads to significant linewidth narrowing of SPPs by reducing scattering loss. To achieve a longer propagation length of SPPs in the plasmonic nanostructures, plus taking the variation in intensity of SPPs into account, the optimized surface modulation depth can be found. The light-matter interactions of 2D materials were explored through the measurements of the nonlinear optical properties of the vertical and planar spiral MoS2 nanosheets. The vertical and planar spiral MoS2 were grown by chemical vapor deposition (CVD). The growth mechanism of these nanostructures was also investigated. Both the nanostructures have a polytype 3R stacking with broken inversion symmetry leading to strong second and third harmonic generations. Plasmon-exciton coupling and Fano resonances in hybrid nanostructures of plasmonic nanostructures with 2D materials were investigated. The spectral positions of surface plasmon resonances could be tuned by periodicity of Au nanorod arrays. Excitons with large binding energy are from the monolayer transition-metal dichalcogenides (TMDCs). From the hybrid nanostructures of Au nanorod array with monolayer WS2,the in-plain dipole moment of bright exciton in TMDCs allows only narrow spectral range of the plasmon-exciton coupling in the resonant scattering measurements. In hybrid nanostructures of Au nanorod arrays with hetero-bilayer WS2/WSe2, two Fano resonances in a reflection spectrum are observed due to the interference between the excitons of bilayer WS2-WSe2 and the plasmon continuum. Incident light polarization along the different axes of Au nanorod can tune the Fano resonance parameters.


Control of Scattering and Absorption of Light by Multilayer Nanowires

Control of Scattering and Absorption of Light by Multilayer Nanowires
Author: Ali Mirzaei
Publisher:
Total Pages: 0
Release: 2017
Genre:
ISBN:

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In recent decades, nanotechnology has become one of the biggest steps forward in expanding the horizons of science and engineering. Nanotechnology progressively plays more important roles in various modern technologies that are revolutionising human lifestyle. Nano-photonics as one of the fastest growing fields in nanotechnology, is finding its way to become a key tool in various applications. This involves variety of scientific and technological problems, from medical diagnosis and cancer therapy to ultrafast computation and data communication. However, continuously improving cutting-edge technology of optical nanostructures, requires further development of analysis for designing more advanced nanostructures for future generations of optical nano-devices. The reported progress in nanophotonics, is mainly based on advances in theoretical optics and experimental techniques. Numerical simulations and experiments have made a significant progress in analysing and designing optical nanostructures for various applications. However, they both become considerably expensive in terms of time and material especially when they have to be repeated for several times to optimise a set of parameters. Furthermore, repeatability and measurement challenges in experiments, and robustness and finite precision complications in simulations, yet remain. These restrictions, consequently, limit the exploration possibility for new ideas and solutions for future nanophotonics. To address this, I introduce a novel, fast and exact approach by employing analytical/semianalytical solutions and powerful optimisation techniques without the mentioned restrictions. This approach suggests a novel platform for wide exploration of unique possibilities for developing new ideas. I discuss the details of my approach by employing multilayer nanostructures for example applications in optics. To achieve optimal performance, I develop a smart optimisation process that employs the fast analytical solutions within a genetic algorithm. I explain the details of this process that can optimise complicated structures by exploring multi-dimensional parameter space in both linear and nonlinear regimes. My proposed approach, can generally be applied for different types of nanostructures with different geometries. However, among various introduced components, nanowires have proven themselves to be appropriate candidates for taking important roles in optical devices for different applications. In addition, by studying long nanowires, I analyse optical nanostructures using the developed semi-analytical approach in a two-dimensional platform. Therefore, we can concentrate on developing the main concepts by avoiding unnecessary complications. In this thesis I provide the complete analysis of nanowire with large aspect ratios, however our further studies prove that the developed design solution and achieved results are not restricted to two-dimensional platform, and are also applicable for three-dimensional structures. I briefly discuss this with some examples, such as nanodisks and nanospheres, even in more complicated configurations and by presence of substrates. To discuss the details, after a brief introduction in Chapter 1, I first discuss two parallel approaches in Chapter 2: (i) a semi-analytical method to analyse the scattering and absorption of light with single and interfering multilayer nanowires, and (ii) a smart genetic optimisation algorithm, employing the fast semi-analytical solution to search for optimal set of designing parameters. Then, I focus on developing specific structures based on multilayer nanowire systems. Controlling the light-matter interaction in nanowires allows to engineer the scattering and absorption efficiencies, with the possibility to enhance or suppress the corresponding cross section. As examples, I discuss invisibility cloaking and superscattering of light as two oppositely different effects in Chapter 3. Enhancing the absorption of light on the other hand, is important for improving the efficiency of many optical devices which in its extremum case, can cause superabsorption effect. This is also discussed in detail by the use of single multilayer nanowires in Chapter 3. By bringing more nanowires together and constructing more complicated systems, the interference between the nanowires can lead to remarkable effects. In Chapters 2 and 4, I explain the analytical solution of multiple scattering problems in nanowire systems. Example structures in Chapter 4 demonstrate that carefully controlling the behaviour of light in nanowire dimer systems can lead us to manage electric and magnetic hotspots, and a complex nanowire system to electromagnetically shield non-isolated areas. Finally, going beyond the linear regime, I discuss nonlinear effects in multilayer nanowires in Chapter 5, by introducing my novel semi-analytical recipe. By studying an example of nonlinear superscattering of light by a core-shell nanowire and its hysteresis loop and bistability, I demonstrate that my approach is accurate and more than 100,000 times faster than finite difference time domain.


Polariton Chemistry

Polariton Chemistry
Author: Joel Yuen-Zhou
Publisher:
Total Pages: 452
Release: 2023-05-09
Genre:
ISBN: 9781119783299

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This book provides a pedagogical introduction to the emerging field of Polariton Chemistry, where optical cavities are utilized to control the physicochemical properties and dynamics of molecular systems. Given the early stages of this interdisciplinary research area, it is important to provide a common language and starting point for interested researchers across Chemistry, Physics, and Engineering This edited compendium fills a void given that there is currently no analogue in the current literature. Topics covered include Single-Molecule Strong Light-Matter Coupling; Collective Strong Light-Matter Coupling; and Ultrastrong Light-Matter Coupling