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Stereoselectivity of Pesticides

Stereoselectivity of Pesticides
Author: Everhardus Jacobus Ariëns
Publisher: Elsevier Publishing Company
Total Pages: 564
Release: 1988
Genre: Technology & Engineering
ISBN:

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Recently there has been growing concern about the hazards for man and his environment due to exposure to chemicals. One aspect receiving particular attention is that of the neglect of stereoselectivity in bioactive agents such as pesticides, drugs, etc. Mixtures of stereoisomers often contain 50 percent inactive material in the form of isomeric ballast. This ballast is pure environmental pollutant. Decisions as to whether the use of mixtures of stereoisomers is acceptable are only possible and acceptable if they are based on sound scientific information. It is the purpose of this volume to contribute to, and to disseminate, knowledge in this field. Written for workers in the field of pesticides, the book contains concise and basic information on stereoselectivity as a notable source of problems. Attention is paid to the involvement of stereoselectivity in important classes of pesticides as well as to pheromones and compounds derived from insect hormones with potential use in crop protection. Fundamentals of stereochemistry, stereoselective analytical methods, stereoselective synthesis and stereochemical aspects of the design of new compounds are also discussed.


Chiral Pesticides

Chiral Pesticides
Author: A. Wayne Garrison
Publisher: OUP USA
Total Pages: 0
Release: 2012-07-12
Genre: Science
ISBN: 9780841226791

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An examination of chirality as an environmental phenomenon


The Pesticide Encyclopedia

The Pesticide Encyclopedia
Author: Kalyani Paranjape
Publisher: CABI
Total Pages: 727
Release: 2014-12-22
Genre: Technology & Engineering
ISBN: 1780640145

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In today's world, food security is an important issue. Food shortages push prices up, impacting upon the health and well-being of hundreds of millions of rural poor across the globe. One way to increase food security is to decrease the amount of yield lost to pests. The Pesticide Encyclopedia provides a comprehensive overview of the fight against pests, covering chemical pesticides, biocontrol agents and biopesticides. It also covers interrelated topics such as pesticide toxicity, legislation and regulation, handling, storage and safety aspects, IPM techniques, resistance management, interaction of pesticides with soil and the environment. An important reference for policy makers, advisers and students and researchers of crop science, this book also includes useful notes on commonly known plant diseases and pests.


Stereochemistry of Organic Compounds

Stereochemistry of Organic Compounds
Author: Ernest L. Eliel
Publisher: John Wiley & Sons
Total Pages: 1296
Release: 1994-09-28
Genre: Science
ISBN: 0471016705

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Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.


Comprehensive Analytical Profiles of Important Pesticides

Comprehensive Analytical Profiles of Important Pesticides
Author: Joseph Sherma
Publisher: CRC Press
Total Pages: 324
Release: 1992-12-07
Genre: Technology & Engineering
ISBN: 9780849379925

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Comprehensive Analytical Profiles of Important Pesticides provides detailed information on the properties and analytical methodology for nine prominent pesticides, including one insecticide, two fungicides, five herbicides, and one plant growth regulator. An analysis of various fumigants in foods is also provided. An overview for each pesticide covers formulation and uses; chemical and physical properties; analytical methods and toxicological data; fish and wildlife toxicity studies; and tolerances on various foods and feeds. General properties including toxicity data, procedures and ramifications for formulation analysis, low level residue analysis, and modifications and occurrences are listed for each compound. Experimental details of procedures are reviewed together with a critical evaluation leading to a recommended procedure. The wealth of information found in Comprehensive Analytical Profiles of Important Pesticides makes it an essential reference volume for analytical chemists, laboratory managers, environmental chemists, residue chemists, toxicologists, and other professionals who require access to concise reports illustrating the latest successful approaches to analyzing these important pesticides.


Pesticides in Soils

Pesticides in Soils
Author: M. Sonia Rodríguez-Cruz
Publisher: Springer Nature
Total Pages: 380
Release: 2022-02-07
Genre: Science
ISBN: 3030905462

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This book reviews the occurrence and fate of pesticides in soils, their impact on soil quality and soil ecosystems, and it also provides a comprehensive overview of the latest prevention and remediation strategies of soil contamination. Chapters from expert contributors cover topics such as soil pollution monitoring, the role of dissolved organic matter on the environmental fate of pesticides in soils, the effects of pesticides on soil microbial communities, plant uptake of pesticides from soils, and nano-based pesticides. Particular attention is given to the latest physicochemical and biological technologies developed to immobilize or degrade pesticides, preventing soil and water pollution. Given its scope, the book will appeal to researchers, professionals, including environmental chemists, engineers, ecologists, and policy-makers responsible for soil management.


Drug Stereochemistry

Drug Stereochemistry
Author: Irving Wainer
Publisher: CRC Press
Total Pages: 450
Release: 1993-02-24
Genre: Science
ISBN: 9780824788193

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Maintaining and enhancing its focus on key issues in the development, regulatory approval and use of stereoisomeric compounds, this edition continues to cover in detail all aspects of chiral drugs from the academic, governmental, industrial and clinical points of view.;Completely rewritten and updated throughout, Drug Stereochemistry: illustrates current indirect chromatographic methods for the resolution of drug enantiomers; treats the rapidly growing area of enantioselective gas chromatography; discusses the latest in HPLC resolution of enantiomeric drugs; uses verapamil as a model to show how stereoselective pharmacokinetics affect pharmacodynamics; and supplies an in-depth study on the effect of stereoselective plasma protein binding.;This edition offers entirely new chapters that: discuss the recent decisions and present position of the US Food and Drug Administration on the development of stereoisomeric drugs; explicate enzymatic synthesis of stereochemically pure drugs; review the toxicological, pharmacokinetic and pharmacodynamic differences found among stereoisomers; elucidate the stereoselective transport of drugs across epithelia; and give a physician's perspective on the questions and problems caused by stereoisomeric drugs in practice as well as the pharmaceutical industry's collective viewpoint based on a national survey.


Chirotechnology

Chirotechnology
Author: Roger A. Sheldon
Publisher: CRC Press
Total Pages: 456
Release: 1993-05-27
Genre: Science
ISBN: 9780824791438

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This reference provides an introduction to the phenomenon of chirality and its importance in conjunction with biological activity and offers an easy-to-read examination of practical, industrially relevant methods for the synthesis of optically active compounds.;Furnishing hands-on guidelines for the development of economically viable synthetic compounds, Chirotechnology: explains optical isomerism and stereochemistry; gives a general overview of various methods of synthesis; supplies detailed explications of specific techniques, including fermentation, crystallization, the chirality pool, enzymatic methods, and catalytic asymmetric synthesis; illustrates and compares approaches with examples taken directly from industry such as the synthesis of pharmaceuticals, agrochemicals, flavours, and fragrances; and clarifies the importance of determining which approach to use for the synthesis of particular molecules.;With over 1100 literature citations, tables and figures, Chirotechnology is a reference for chemical engineers; industrial, organic and medicinal chemists; and bioprocess technologists, as well as a text for upper-level undergraduate, graduate and continuing-education students in these disciplines.