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Spectrophotometric Determination of Plutonium-239 Based on the Spectrum of Plutonium(III) Chloride

Spectrophotometric Determination of Plutonium-239 Based on the Spectrum of Plutonium(III) Chloride
Author:
Publisher:
Total Pages: 13
Release: 1994
Genre:
ISBN:

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This report describes a spectrophotometric method for determining plutonium-239 (Pu-239) based on the spectrum of Pu(III) chloride. The authors used the sealed-reflux technique for the dissolution of plutonium oxide with hydrochloric acid (HCl) and small amounts of nitric and hydrofluoric acids. To complex the fluoride, they added zirconium, and to reduce plutonium to Pu(III), they added ascorbic acid. They then adjusted the solution to a concentration of 2 M HCl and measured the absorbances at five wavelengths of the Pu(III) chloride spectrum. This spectrophotometric determination can also be applied to samples of plutonium metal dissolved in HCl.


Energy Research Abstracts

Energy Research Abstracts
Author:
Publisher:
Total Pages: 782
Release: 1995
Genre: Power resources
ISBN:

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Nuclear Science Abstracts

Nuclear Science Abstracts
Author:
Publisher:
Total Pages: 1058
Release: 1975
Genre: Nuclear energy
ISBN:

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Chemical Thermodynamics of Neptunium and Plutonium

Chemical Thermodynamics of Neptunium and Plutonium
Author: Robert J. Lemire
Publisher: Elsevier
Total Pages: 876
Release: 2001-08-26
Genre: Medical
ISBN: 9780444503794

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Unlike earlier books in this series, this review describes the selection of chemical thermodynamic data for species of two elements, neptunium and plutonium. Although this came about more by circumstance than design, it has allowed for a more consistent approach to chemical interpretation than might have occurred in two separate treatments. It has also drawn attention to cases where the available data do not show expected parallels, and where further work may be useful to confirm or refute apparent differences in the behaviour of neptunium and plutonium.


Chemical Thermodynamics of Technetium

Chemical Thermodynamics of Technetium
Author: J.A. Rard
Publisher: North Holland
Total Pages: 578
Release: 1999-12-13
Genre: Science
ISBN:

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This volume in the series Chemical Thermodynamics provides a comprehensive review and critical evaluation of experimental data available for the chemical thermodynamics of inorganic compounds and aqueous species and complexes of technetium. The objective of the reviews in the series Chemical Thermodynamics is to provide a set of reliable thermodynamic data that can be used to describe the behaviour of the elements reviewed under conditions relevant for radioactive waste disposal systems and various geochemical environments. Data and their uncertainty limits are recommended for the formation energies, enthalpies and entropies of selected aqueous complexes, solids and gaseous compounds containing technetium. The data are internally consistent and compatible with the CODATA Key Values, as well as with the data in the earlier volumes in the series Chemical Thermodynamics. The book contains a detailed discussion of the selection procedures used


Actinide Separations

Actinide Separations
Author: James D. Navratil
Publisher:
Total Pages: 632
Release: 1980
Genre: Science
ISBN:

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Transition Metals in Coordination Environments

Transition Metals in Coordination Environments
Author: Ewa Broclawik
Publisher: Springer
Total Pages: 532
Release: 2019-03-16
Genre: Science
ISBN: 3030117146

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This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.