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Solid-State Properties of Transition Metal Complexes

Solid-State Properties of Transition Metal Complexes
Author: L. V. Interrante
Publisher:
Total Pages: 69
Release: 1975
Genre:
ISBN:

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The report describes the work on solid-state properties of transition metal complexes. Several different types of transition metal complex systems with anisotropic solid-state interactions have been prepared and studied using electrical conductivity, magnetic susceptibility, and spectral measurement methods. The results of these measurements and accompanying x-ray structural studies have been used to derive structure-property relationships and to obtain information regarding the nature of the intermolecular interactions occurring in the solid state.


Ligated Transition Metal Clusters in Solid-state Chemistry

Ligated Transition Metal Clusters in Solid-state Chemistry
Author: Jean-François Halet
Publisher: Springer Nature
Total Pages: 201
Release: 2019-08-29
Genre: Science
ISBN: 3030251241

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This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few.


Synthesis and Characterization of Transition Metal Complex Systems with Novel Solid State Properties

Synthesis and Characterization of Transition Metal Complex Systems with Novel Solid State Properties
Author: L. V. Interrante
Publisher:
Total Pages: 27
Release: 1982
Genre:
ISBN:

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The principal focus of this work has been on the preparation and study of pi-donor-acceptor compounds derived from the interaction of planar metal complexes and planar organic molecules. Included among the metal complex system studied are various bis(1,2-ethylenedithiolene) metal complexes, which have been employed as pi-acceptors, and some tetraazamacrocyclic complexes, used as pi-donors. In addition a new planar Ir(I) complex has been prepared using novel redox-active organic ligand system and examined as a source of conductive one-dimensional materials, using iodine to partially oxidize the Ir(I) complex units. These various compounds have been studied using electrical conductivity, magnetic susceptibility, and other solid state property measurement techniques. In addition, their crystal structures have been characterized using single crystal x-ray diffraction methods. The results provide new information regarding the solid state interactions in metal complex-containing systems and suggest the promise of such systems as a soruce of solid state materials with novel magnetic and electronic properties.


Solid State Chemistry

Solid State Chemistry
Author: A. Wold
Publisher: Springer
Total Pages: 270
Release: 1993-06-30
Genre: Science
ISBN:

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The subject matterofsolid state chemistry lies within the spheres ofboth physical and inorganic chemistry. In addition, there is a large overlap with solid state physics and materials engineering. However, solid state chemistry has still to be recognized by the general body ofchemists as a legitimate subfield ofchemistry. The discipline is not even well defined as to content and has many facets that make writing a textbook a formidable task. The early studies carried out in the United States by Roland Ward and his coƯ workers emphasized the synthesisofnew materials and the determination oftheir structure. His work on doped alkaline earth sulfides formed the basis for the development of infrared phosphors and his pioneering studies on oxides were important in understanding the structural features of both the perovskite oxides as well as the magnetoplumbites. In 1945, A.F. Wells published the first edition of Structural Inorganic Chemistry. This work attempts to demonstrate that the synthesis, structure, and properties of solids form an important part of inorganic chemistry. Now, after almost 50 years during which many notable advances have been made in solid state chemistry, it is still evident that the synthesis, structure determination, and properties of solids receive little attention in most treatments of inorganic chemistry. The development of the field since the early studies of Roland Ward (early 1940s) has been rapid.


Solid Compounds of Transition Elements III

Solid Compounds of Transition Elements III
Author: Ernst Bauer
Publisher: Trans Tech Publications Ltd
Total Pages: 232
Release: 2019-04-08
Genre: Technology & Engineering
ISBN: 3035733023

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This volume of the journal contains papers presented at the 21st International Conference on Solid Compounds of Transition Elements, SCTE 2018 which was held in the Technische Universität Wien, Austria, from March 25 to March 29, 2018. The conference was dedicated to fundamental and applied research regarding structure, crystal chemistry, chemical bonding, as well as with magnetic, thermodynamic, phononic and electronic properties of different classes of intermetallic compounds. Hydrides, borides, carbides, silicides and homologues, pnictides, chalcogenides, oxides and halides (especially those of low oxidation states exhibiting metal or semimetal properties) were in the focus of the conference also.


Groups IV, V, and VI Transition Metals and Compounds

Groups IV, V, and VI Transition Metals and Compounds
Author: T. F. Connolly
Publisher: Springer Science & Business Media
Total Pages: 219
Release: 2012-12-06
Genre: Science
ISBN: 1468462040

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responsibility.) To Betty Edwards and Emily Copenhaver my thanks for what must have seemed endless typing, retyping and correcting of these bibliographies over a span of years. Availability of Documents U. S. Government contractor reports, usually identified by an alpha-numeric report number, can be purchased from National Technical Information Service U. S. Department of Commerce Springfield, Virginia 22151 and, often, on request from the issuing installation. USAEC reports are also available from International Atomic Energy Agency Kaerntnerring A 1010 Vienna, Austria National Lending Library Boston Spa England Monographs and reports of the National Bureau of Standards are for sale by Superintendent of Documents U. S. Government Printing Office Washington, D. C. 20402 Theses, listed as Dissertation Abstracts + number, are available in North or South America from University Microfilms Dissertation Copies P. O. Box 1764 Ann Arbor, Michigan 48106 and elsewhere from University Microfilms, Ltd. St. John's Road Tylers Green Penn, Buckinghamshire England Other Information Centers and New Journals New journals Information centers Field and and other sources serials Ultra purification 4, 8, 11, 13, 15, 16,19, 20, 9,11,15, 24, 31, 32 and 21, 28, 30, 32, 33, 42, 58, 59 crystal growth ix Preface Field Information centers New journals and and other -sources serials Characterization Miscellaneous 3,4, 8, 11, 13, 16, 19, 20, 1,3,4,8,11,15,17, 21, 26, 28, 30, 31, 32, 33, 35, 24, 25, 28, 29, 30, 31, 37, 38, 39, 40, 42, 46, 53, 56, 32 58, 60, 61, 62


Transition Metal Sulphides

Transition Metal Sulphides
Author: Th. Weber
Publisher: Springer Science & Business Media
Total Pages: 357
Release: 2013-06-29
Genre: Science
ISBN: 9401735778

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Hydrotreating catalysis with transition metal sulphides is one of the most important areas of industrial heterogeneous catalysis. The present book deals with the chemical and catalytic aspects of transition metal sulphides, focusing on their use in hydrotreating catalysis. The book¿s 12 chapters present reviews of solid-state, coordination and organometallic chemistry, surface science and spectroscopic studies, quantum chemical calculations, catalytic studies with model and real catalysts, as well as refinery processes. A presentation of state-of-the-art background to pertinent work in the field. Can be used as an introduction to the chemical and catalytic properties of transition metal sulphides as well as an advanced level reference.