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Molecular Electronics

Molecular Electronics
Author: Juan Carlos Cuevas
Publisher: World Scientific
Total Pages: 724
Release: 2010
Genre: Science
ISBN: 9814282588

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This book provides a comprehensive overview of the rapidly developing field of molecular electronics. It focuses on our present understanding of the electrical conduction in single-molecule circuits and provides a thorough introduction to the experimental techniques and theoretical concepts. It will also constitute as the first textbook-like introduction to both the experiment and theory of electronic transport through single atoms and molecules. In this sense, this publication will prove invaluable to both researchers and students interested in the field of nanoelectronics and nanoscience in general. Molecular Electronics is self-contained and unified in its presentation. It may be used as a textbook on nanoelectronics by graduate students and advanced undergraduates studying physics and chemistry. In addition, included are previously unpublished material that will help researchers gain a deeper understanding into the basic concepts involved in the field of molecular electronics.


Handbook of Single-Molecule Electronics

Handbook of Single-Molecule Electronics
Author: Kasper Moth-Poulsen
Publisher: CRC Press
Total Pages: 439
Release: 2016-01-05
Genre: Science
ISBN: 9814463396

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Single-molecule electronics has evolved as a vibrant research field during the last two decades. The vision is to be able to create electronic components at the highest level of miniaturization-the single molecule. This book compiles and details cutting-edge research with contributions from chemists, physicists, theoreticians, and engineers. It cov


Single-Molecule Electronics

Single-Molecule Electronics
Author: Manabu Kiguchi
Publisher: Springer
Total Pages: 239
Release: 2016-05-23
Genre: Science
ISBN: 9811007241

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This book presents a multidisciplinary approach to single-molecule electronics. It includes a complete overview of the field, from the synthesis and design of molecular candidates to the prevalent experimental techniques, complemented by a detailed theoretical description. This all-inclusive strategy provides the reader with the much-needed perspective to fully understand the far-reaching ramifications of single-molecule electronics. In addition, a number of state-of-the-art topics are discussed, including single-molecule spectro-electrical methods, electrochemical DNA sequencing technology, and single-molecule chemical reactions. As a result of this integrative effort, this publication may be used as an introductory textbook to both graduate and advanced undergraduate students, as well as researchers with interests in single-molecule electronics, organic electronics, surface science, and nanoscience.


Design and Control of Highly Conductive Single-Molecule Junctions

Design and Control of Highly Conductive Single-Molecule Junctions
Author: Satoshi Kaneko
Publisher: Springer
Total Pages: 92
Release: 2017-04-04
Genre: Science
ISBN: 9811044120

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This thesis describes improvements to and control of the electrical conductance in single-molecule junctions (SMJs), which have potential applications in molecular electronics, with a focus on the bonding between the metal and molecule. In order to improve the electrical conductance, the π orbital of the molecule is directly bonded to the metal orbital, because anchoring groups, which were typically used in other studies to bind molecule with metal electrodes, became resistive spacers. Using this direct π-binding, the author has successfully demonstrated highly conductive SMJs involving benzene, endohedral metallofullerene Ce@C82, and nitrogen. Subsequently, the author investigated control of the electrical conductance of SMJs using pyrazine. The nitrogen atom in the π-conjugated system of pyrazine was expected to function as an anchoring point, and two bonding states were expected. One originates primarily from the π orbital, while the other originates primarily from an n state of the nitrogen. Measurements of conductance and dI/dV spectra coupled with theoretical calculations revealed that the pyrazine SMJ has bistable conductance states, in which the pyrazine axis is either tilted or parallel with respect to the junction axis. The bistable states were switched by changing the gap size between the metal electrodes using an external force. Notably, it is difficult to change the electrical properties of bulk-state materials using mechanical force. The findings reveal that the electron transport properties of a SMJ can be controlled by designing a proper metal–molecule interface, which has considerable potential for molecular electronics. Moreover, this thesis will serve as a guideline for every step of SMJ research: design, fabrication, evaluation, and control.


Molecular Architectonics

Molecular Architectonics
Author: Takuji Ogawa
Publisher: Springer
Total Pages: 535
Release: 2017-07-06
Genre: Science
ISBN: 331957096X

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This book draws on the main themes covered during the International Workshop on Molecular Architectonics which took place in Shiretoko, Japan from August 3 to 6, 2015. The concepts and results explored in this book relate to the term “molecular architectonics” which stands for electronic, optical and information-processing functions being orchestrated by molecular assemblies. This area is defined as the third stage of single-molecule electronics and builds on stage one, where measurements were performed on single-molecule layered films, and stage two, the resulting quantitative analyses. In this work, experts come together to write about the most important aspects of molecular architectonics. This interdisciplinary, visionary and unique book is of interest to scientists working on electronic materials, surface science and information processing sciences using noise and fluctuation.


Molecular-Scale Electronics

Molecular-Scale Electronics
Author: Xuefeng Guo
Publisher: Springer
Total Pages: 262
Release: 2018-12-06
Genre: Technology & Engineering
ISBN: 3030033058

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The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.


Photophysics of Molecular Materials

Photophysics of Molecular Materials
Author: Guglielmo Lanzani
Publisher: John Wiley & Sons
Total Pages: 600
Release: 2006-05-12
Genre: Science
ISBN: 3527607390

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Carbon based pi-conjugated materials offer a broad range of applications, going from molecular electronics and single molecule devices to nanotechnology, plastic electronics and optoelectronics. The proper physical description of such materials is in between that of molecular solids and that of low-dimensional covalent semiconductors. This book is a comprehensive review of their elementary excitations processes and dynamics, which merges the two viewpoints, sometimes very different if not contrasting. In each chapter, a broad tutorial introduction provides a solid physical background to the topic, which is further discussed based on recent experimental results obtained via state-of-the-art techniques. Both the molecular, intra-chain character and the solid state, inter-molecular physics is addressed. Reports on single molecule and single polymer chain spectroscopy introduce the on-site phenomena. Several chapters are dedicated to nano-probes, steady state and transient spectroscopies. The highly ordered state, occurring in single crystals, is also discussed thoroughly. Finally, less conventional tools such as THz spectroscopy are discussed in detail. The book provides a useful introduction to the field for newcomers, and a valid reference for experienced researchers in the field.


Single Molecule Electronics and Nanofabrication of Molecular Electronic Devices

Single Molecule Electronics and Nanofabrication of Molecular Electronic Devices
Author: Senthil Arun Rajagopal
Publisher:
Total Pages: 95
Release: 2006
Genre: Microelectronics
ISBN:

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Molecular electronics is an emerging field that makes it possible to build electronic devices with single molecules as their active element. The conductivity of single molecules can be manipulated to perform functions similar to present-day bulk electronic devices. These single molecules, with a size of few nano-meters, can be designed and chemically synthesized with tailored electronic structures. This thesis focuses on the design, fabrication and measurement of nanogap electronic devices. The enabling device to study the conductivity of dimetal paddlewheel inorganic complexes, using electrode pairs with nanometer separation is fabricated. A study of these inorganic complexes would provide more versatile opportunities for tailoring electron transport properties. The molecular complex and its electron transport mechanism are discussed and a detailed description of the fabrication of the nano-gap electrode with a controlled gap size is provided. Electron beam lithography fabrication techniques are discussed in detail. A reliable method to fabricate a controlled nanogap with electrodeposition and electromigration is demonstrated. The results of I-V curves of gaps are used to estimate the nanogap dimensions via comparison to tunneling current theory.


Molecular Electronic Devices

Molecular Electronic Devices
Author: Forrest L. Carter
Publisher:
Total Pages: 386
Release: 1982
Genre:
ISBN: 9780824780586

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Molecular-Scale Electronics

Molecular-Scale Electronics
Author: Xuefeng Guo
Publisher: John Wiley & Sons
Total Pages: 408
Release: 2020-07-15
Genre: Technology & Engineering
ISBN: 3527818901

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Provides in-depth knowledge on molecular electronics and emphasizes the techniques for designing molecular junctions with controlled functionalities This comprehensive book covers the major advances with the most general applicability in the field of molecular electronic devices. It emphasizes new insights into the development of efficient platform methodologies for building such reliable devices with desired functionalities through the combination of programmed bottom-up self-assembly and sophisticated top-down device fabrication. It also helps to develop an understanding of the device fabrication processes and the characteristics of the resulting electrode-molecule interface. Beginning with an introduction to the subject, Molecular-Scale Electronics: Concept, Fabrication and Applications offers full chapter coverage on topics such as: Metal Electrodes for Molecular Electronics; Carbon Electrodes for Molecular Electronics; Other Electrodes for Molecular Electronics; Novel Phenomena in Single-Molecule Junctions; and Supramolecular Interactions in Single-Molecule Junctions. Other chapters discuss Theoretical Aspects for Electron Transport through Molecular Junctions; Characterization Techniques for Molecular Electronics; and Integrating Molecular Functionalities into Electrical Circuits. The book finishes with a summary of the primary challenges facing the field and offers an outlook at its future. * Summarizes a number of different approaches for forming molecular-scale junctions and discusses various experimental techniques for examining these nanoscale circuits in detail * Gives overview of characterization techniques and theoretical simulations for molecular electronics * Highlights the major contributions and new concepts of integrating molecular functionalities into electrical circuits * Provides a critical discussion of limitations and main challenges that still exist for the development of molecular electronics * Suited for readers studying or doing research in the broad fields of Nano/molecular electronics and other device-related fields Molecular-Scale Electronics is an excellent book for materials scientists, electrochemists, electronics engineers, physical chemists, polymer chemists, and solid-state chemists. It will also benefit physicists, semiconductor physicists, engineering scientists, and surface chemists.