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Silicon in Organic Synthesis

Silicon in Organic Synthesis
Author: Ernest W. Colvin
Publisher: Butterworth-Heinemann
Total Pages: 361
Release: 2013-10-22
Genre: Science
ISBN: 148314223X

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Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.


Progress in Organosilicon Chemistry

Progress in Organosilicon Chemistry
Author: Bogdan Marciniec
Publisher: Taylor & Francis
Total Pages: 620
Release: 1995
Genre: Chemical reactions
ISBN: 9782884491228

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Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.


Silicon Reagents for Organic Synthesis

Silicon Reagents for Organic Synthesis
Author: William P. Weber
Publisher: Springer Science & Business Media
Total Pages: 446
Release: 2012-12-06
Genre: Science
ISBN: 3642686613

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Silicon Reagents in Organic Synthesis

Silicon Reagents in Organic Synthesis
Author: Ernest W. Colvin
Publisher:
Total Pages: 184
Release: 1988
Genre: Science
ISBN:

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This work provides a full coverage of organosilicon chemistry, with pertinent references to more detailed treatment given at appropriate points in the book.


Reagents for Silicon-Mediated Organic Synthesis

Reagents for Silicon-Mediated Organic Synthesis
Author: Philip L. Fuchs
Publisher: John Wiley & Sons
Total Pages: 816
Release: 2013-05-30
Genre: Technology & Engineering
ISBN: 1118636139

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Over the last three decades the importance of organosiliconchemistry has greatly increased because it has opened a number ofnew synthetic strategies. Silicon reagents are usually low-cost,versatile and allow a wide range of reactions. This is the firstHandbook to compile essential Silicon containing reagents and makesuse of the leading reagent database e-EROS. Another hotvolume in the series Handbooks of Reagents for OrganicSynthesis, this is a must-have resource for all syntheticchemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key syntheticapproaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactivepair of functional groups and taking advantage of theirtemplate-biased intramolecular cyclization. 2. The specific use of the silane functionality as a heterot-butyl group, often colloquially referred to as the use ofsilicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relaystratagem'. A new feature in this Handbook is the reagent finder, analphabetically organized lookup table arranged by organicfunctionality and specific structure of the silicon atom to whichit is bound.


Silicon in Organic Synthesis

Silicon in Organic Synthesis
Author: Ernest W. Colvin
Publisher:
Total Pages: 348
Release: 1985
Genre: Organosilicon compounds
ISBN:

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Silicon in Organic, Organometallic, and Polymer Chemistry

Silicon in Organic, Organometallic, and Polymer Chemistry
Author: Michael A. Brook
Publisher: Wiley-Interscience
Total Pages: 704
Release: 1999-12-28
Genre: Science
ISBN: 9780471196587

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A comprehensive, up-to-date reference to synthetic applications of organosilicon chemistry Organic, organometallic, and polymer chemistry as well as materials science all utilize silicon in various forms, yet there is little cross-fertilization of ideas and applications among the disciplines. This book presents a much-needed overview of silicon chemistry, allowing fundamental and applied scientists to take full advantage of progress made within and outside their primary fields of expertise. With an emphasis on the preparation and reactivity of silicon compounds in organic, organometallic, and polymer chemistry, the author examines a broad range of useful topics-from mechanisms to syntheses of and syntheses using different organofunctional silanes. Numerous schemes as well as up-to-date examples from academia and industry will help readers to solve current synthetic problems and explore ideas for future research. Clear, concise coverage includes: * The mechanistic basis for the development of new silicon-based reactions * Formation and cleavage of silane reagents and functional siliconheteroatom compounds * Silicones, silica, polysilanes, and other silicon-containing polymers * Properties of molecules containing silicon, including bioactivity * Methods for the preparation of Si-C compounds * Silicon in organic synthesis * An extensive functional group index for easy access to functional group transformations


Organosilicon Chemistry

Organosilicon Chemistry
Author: Tamejiro Hiyama
Publisher: John Wiley & Sons
Total Pages: 566
Release: 2020-02-18
Genre: Science
ISBN: 3527344535

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Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.


The Chemistry of Organic Silicon Compounds, Volume 2, Parts 1, 2, and 3 (3 Part Set)

The Chemistry of Organic Silicon Compounds, Volume 2, Parts 1, 2, and 3 (3 Part Set)
Author: Zvi Rappoport
Publisher: John Wiley & Sons
Total Pages: 968
Release: 1998-09-16
Genre: Science
ISBN:

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Organosilicon compounds are key organometallic compounds (R-Si)which have many uses in materials science and in metallurgy. Theirapplications include the synthesis of sugars and in the synthesisof organic compounds for the pharmaceutical industry. This volumewill contain both updated chapters on key topics included in theoriginal volumes as well as a number of new chapters reflecting therapid developments made in silicon chemistry and its applicationsto organometallic chemistry, materials science, and semiconductors,over the last five years. As for the majority of volumes in thisseries, chapters will be prepared by leading scientists in thefield. This volume is now available in electronic format from BooksOnline.