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Selenium Reagents & Intermediates in Organic Synthesis

Selenium Reagents & Intermediates in Organic Synthesis
Author: C. Paulmier
Publisher: Elsevier
Total Pages: 478
Release: 2013-10-22
Genre: Science
ISBN: 1483286401

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The explosive growth of organoselenium chemistry over the past 12 years can be attributed to the specific properties of organic selenium molecules, which fit the requirements of modern organic synthesis. Most of them are well adapted to chemo-, regio- and stereo-selectivities. In addition, they can be used in mild experimental conditions which are compatible with the stability of both substrates and products in the preparation of unsaturated and functional complex molecules, especially in the field of natural products. This book describes and illustrates different synthetic routes to organic structures using selenium reagents or intermediates. The approach emphasizes that such transformations are simple, efficient and often carried out at room temperature. The scope ranges from the preparation of both inorganic and organic selenium reagents, through descriptions of structure, toxicity, biological aspects and nuclear magnetic resonance, to applications of specific selenium compounds in various syntheses including natural products and biologically active compounds.


Selenium Reagents and Intermediates in Organic Synthesis

Selenium Reagents and Intermediates in Organic Synthesis
Author: Claude Paulmier
Publisher: Pergamon
Total Pages: 463
Release: 1986
Genre: Science
ISBN: 9780080324852

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The explosive growth of organoselenium chemistry over the past 12 years can be attributed to the specific properties of organic selenium molecules, which fit the requirements of modern organic synthesis. Most of them are well adapted to chemo-, regio- and stereo-selectivities. In addition, they can be used in mild experimental conditions which are compatible with the stability of both substrates and products in the preparation of unsaturated and functional complex molecules, especially in the field of natural products. This book describes and illustrates different synthetic routes to organic structures using selenium reagents or intermediates. The approach emphasizes that such transformations are simple, efficient and often carried out at room temperature. The scope ranges from the preparation of both inorganic and organic selenium reagents, through descriptions of structure, toxicity, biological aspects and nuclear magnetic resonance, to applications of specific selenium compounds in various syntheses including natural products and biologically active compounds.


Selenium and Tellurium Reagents

Selenium and Tellurium Reagents
Author: Risto Laitinen
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 668
Release: 2019-04-01
Genre: Science
ISBN: 311052810X

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Selenium and Tellurium Reagents provides an in-depth overview of recent advances on the chemistry of these elements. Written by internationally recognized experts, it gives insight into the synthesis, structure, analysis and mechanistic studies of these compounds. The book is organized into four parts which reflect the applications of Se and Te reagents in four areas: inorganic chemistry, organic chemistry, materials science and biochemistry.


Novel Selenium-Mediated Rearrangements and Cyclisations

Novel Selenium-Mediated Rearrangements and Cyclisations
Author: Sohail Anjum Shahzad
Publisher: Springer Science & Business Media
Total Pages: 208
Release: 2012-10-11
Genre: Science
ISBN: 3642331734

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In his thesis, Sohail Shahzad carefully investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. After a comprehensive introduction to the element selenium, the author goes on to report the synthesis of several substrates for carbocyclisation reactions and the use of selenium reagents for the preparation of dihydronaphthalenes. Further chapters detail electrophilic selenium-mediated reactions, and novel strategies using selenium catalysts together with stoichiometric amounts of hypervalent iodine reagents as oxidants to convert stilbene carbosylic acids into the corresponding isocoumarins. This thesis outlines some excellent new synthetic routes which will be useful tools for synthetic organic chemistry in the future.


Selenium and Tellurium Reagents

Selenium and Tellurium Reagents
Author: Risto Laitinen
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 466
Release: 2019-04-01
Genre: Science
ISBN: 3110529343

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Selenium and Tellurium Reagents provides an in-depth overview of recent advances on the chemistry of these elements. Written by internationally recognized experts, it gives insight into the synthesis, structure, analysis and mechanistic studies of these compounds. The book is organized into four parts which reflect the applications of Se and Te reagents in four areas: inorganic chemistry, organic chemistry, materials science and biochemistry.


Organoselenium Chemistry

Organoselenium Chemistry
Author: J. Drabowicz
Publisher: Springer Science & Business Media
Total Pages: 265
Release: 2000-02-25
Genre: Medical
ISBN: 3540665161

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Embarking on a new millennium, the book in hands describes the recent developments of organsoselenium chemistry in all facets. Various distinguished scientists have contributed, with their skill and expertise, making this book a valuable source for synthetic oriented organic chemists and for those, who want to get a first insight into the chemistry of selenium.


Organoselenium Chemistry

Organoselenium Chemistry
Author: Thomas Wirth
Publisher: John Wiley & Sons
Total Pages: 441
Release: 2012-01-09
Genre: Science
ISBN: 3527641955

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Selenium-based methods in synthetic chemistry have developed rapidly over the past years and are now offering highly useful tools for organic synthesis. Filling the gap for a comprehensive handbook and ready reference, this book covers all modern developments within the field, including biochemical aspects. The chemistry chapters are organized according to the different reactivities of various selenium compounds and reagents, with each chapter dealing with a special reaction type. Also includes a table with 77Se NMR shifts to aid in practical problems. From the Contents: * Electrophilic and Nucleophilic Selenium * Selenium Compounds in Radical Reactions * Selenium-Stabilized Carbanions * Selenium Compounds with Valency Higher than Two * Selenocarbonyls * Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement * Selenium Compounds as Ligands and Catalysts * Biological and Biochemical Aspects of Selenium Compounds


Advanced Organic Chemistry

Advanced Organic Chemistry
Author: Francis A. Carey
Publisher: Springer Science & Business Media
Total Pages: 1216
Release: 2007-06-27
Genre: Science
ISBN: 0387448993

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The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.