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Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant

Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant
Author: National Research Council
Publisher: National Academies Press
Total Pages: 61
Release: 2013-06-17
Genre: Technology & Engineering
ISBN: 0309263964

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The Pueblo Chemical Depot (PCD) in Colorado is one of two sites that features U.S. stockpile of chemical weapons that need to be destroyed. The PCD features about 2,600 tons of mustard-including agent. The PCD also features a pilot plant, the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP), which has been set up to destroy the agent and munition bodies using novel processes. The chemical neutralization or hydrolysis of the mustard agent produces a Schedule 2 compound called thiodiglycol (TDG) that must be destroyed. The PCAPP uses a combined water recovery system (WRS) and brine reduction system (BRS) to destroy TDG and make the water used in the chemical neutralization well water again. Since the PCAPP is using a novel process, the program executive officer for the Assembled Chemical Weapons Alternatives (ACWA) program asked the National Research Council (NRC) to initiate a study to review the PCAPP WRS-BRS that was already installed at PCAPP. 5 months into the study in October, 2012, the NRC was asked to also review the Biotreatment area (BTA). The Committee on Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant was thus tasked with evaluating the operability, life-expectancy, working quality, results of Biotreatment studies carried out prior to 1999 and 1999-2004, and the current design, systemization approached, and planned operation conditions for the Biotreatment process. Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant is the result of the committee's investigation. The report includes diagrams of the Biotreatment area, the BRS, and WRS; a table of materials of construction, the various recommendations made by the committee; and more.


Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant

Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant
Author: National Research Council
Publisher: National Academies Press
Total Pages: 61
Release: 2013-07-17
Genre: Technology & Engineering
ISBN: 030926393X

Download Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle

The Pueblo Chemical Depot (PCD) in Colorado is one of two sites that features U.S. stockpile of chemical weapons that need to be destroyed. The PCD features about 2,600 tons of mustard-including agent. The PCD also features a pilot plant, the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP), which has been set up to destroy the agent and munition bodies using novel processes. The chemical neutralization or hydrolysis of the mustard agent produces a Schedule 2 compound called thiodiglycol (TDG) that must be destroyed. The PCAPP uses a combined water recovery system (WRS) and brine reduction system (BRS) to destroy TDG and make the water used in the chemical neutralization well water again. Since the PCAPP is using a novel process, the program executive officer for the Assembled Chemical Weapons Alternatives (ACWA) program asked the National Research Council (NRC) to initiate a study to review the PCAPP WRS-BRS that was already installed at PCAPP. 5 months into the study in October, 2012, the NRC was asked to also review the Biotreatment area (BTA). The Committee on Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant was thus tasked with evaluating the operability, life-expectancy, working quality, results of Biotreatment studies carried out prior to 1999 and 1999-2004, and the current design, systemization approached, and planned operation conditions for the Biotreatment process. Review of Biotreatment, Water Recovery, and Brine Reduction Systems for the Pueblo Chemical Agent Destruction Pilot Plant is the result of the committee's investigation. The report includes diagrams of the Biotreatment area, the BRS, and WRS; a table of materials of construction, the various recommendations made by the committee; and more.


Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant

Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant
Author: National Research Council
Publisher: National Academies Press
Total Pages: 150
Release: 2015-03-26
Genre: Technology & Engineering
ISBN: 0309317916

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One of the last two sites with chemical munitions and chemical materiel is the Pueblo Chemical Depot in Pueblo, Colorado. The stockpile at this location consists of about 800,000 projectiles and mortars, all of which are filled with the chemical agent mustard. Under the direction of the Assembled Chemical Weapons Alternative Program (ACWA), the Army has constructed the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP) to destroy these munitions. The primary technology to be used to destroy the mustard agent at PCAPP is hydrolysis, resulting in a secondary waste stream referred to as hydrolysate. PCAPP features a process that will be used to treat the hydrolysate and the thiodiglycol - a breakdown product of mustard - contained within. The process is a biotreatment technology that uses what are known as immobilized cell bioreactors. After biodegradation, the effluent flows to a brine reduction system, producing a solidified filter cake that is intended to be sent offsite to a permitted hazardous waste disposal facility. Water recovered from the brine reduction system is intended to be recycled back through the plant, thereby reducing the amount of water that is withdrawn from groundwater. Although biotreatment of toxic chemicals, brine reduction, and water recovery are established technologies, never before have these technologies been combined to treat mustard hydrolysate. At the request of the U.S. Army, Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant reviews the criteria for successfully treating the hydrolysate. This report provides information on the composition of the hydrolysate and describes the PCAPP processes for treating it; discusses stakeholder concerns; reviews regulatory considerations at the federal, state, and local levels; discusses Department of Transportation regulations and identifies risks associated with the offsite shipment of hydrolysate; establishes criteria for successfully treating the hydrolysate and identifies systemization data that should factor into the criteria and decision process for offsite transport and disposal of the hydrolysate; and discusses failure risks and contingency options as well as the downstream impacts of a decision to ship hydrolysate offsite.


Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant

Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant
Author: National Research Council (U.S.). Committee On Review Criteria for Successful Treatment of Hydrolysate at the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plant
Publisher:
Total Pages: 85
Release: 2015
Genre: TECHNOLOGY & ENGINEERING
ISBN: 9780309367646

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"One of the last two sites with chemical munitions and chemical materiel is the Pueblo Chemical Depot in Pueblo, Colorado. The stockpile at this location consists of about 800,000 projectiles and mortars, all of which are filled with the chemical agent mustard. Under the direction of the Assembled Chemical Weapons Alternative Program (ACWA), the Army has constructed the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP) to destroy these munitions. The primary technology to be used to destroy the mustard agent at PCAPP is hydrolysis, resulting in a secondary waste stream referred to as hydrolysate. PCAPP features a process that will be used to treat the hydrolysate and the thiodiglycol - a breakdown product of mustard - contained within. The process is a biotreatment technology that uses what are known as immobilized cell bioreactors. After biodegradation, the effluent flows to a brine reduction system, producing a solidified filter cake that is intended to be sent offsite to a permitted hazardous waste disposal facility. Water recovered from the brine reduction system is intended to be recycled back through the plant, thereby reducing the amount of water that is withdrawn from groundwater. Although biotreatment of toxic chemicals, brine reduction, and water recovery are established technologies, never before have these technologies been combined to treat mustard hydrolysate. At the request of the U.S. Army, Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant reviews the criteria for successfully treating the hydrolysate. This report provides information on the composition of the hydrolysate and describes the PCAPP processes for treating it; discusses stakeholder concerns; reviews regulatory considerations at the federal, state, and local levels; discusses Department of Transportation regulations and identifies risks associated with the offsite shipment of hydrolysate; establishes criteria for successfully treating the hydrolysate and identifies systemization data that should factor into the criteria and decision process for offsite transport and disposal of the hydrolysate; and discusses failure risks and contingency options as well as the downstream impacts of a decision to ship hydrolysate offsite."--Publisher's description.


Review of Secondary Waste Disposal Planning for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants

Review of Secondary Waste Disposal Planning for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants
Author: National Research Council
Publisher: National Academies Press
Total Pages: 84
Release: 2008-12-14
Genre: Political Science
ISBN: 0309120500

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The U.S. Army Program Manager for Assembled Chemical Weapons Alternatives (PMACWA) is charged with disposing of chemical weapons as stored at two sites: Pueblo, Colorado, and Blue Grass, Kentucky. In accordance with congressional mandates, technologies other than incineration are to be used if they are as safe and as cost effective. The weapons are to be disposed of in compliance with the Chemical Weapons Convention. Although an element of the U.S. Army, the PMACWA is responsible to the Assistant Secretary of Defense for Acquisitions, Technology, and Logistics for completing this mission. This book deals with the expected significant quantities of secondary wastes that will be generated during operations of the facilities and their closure. While there are only estimates for the waste quantities that will be generated, they provide a good basis for planning and developing alternatives for waste disposal while the plants are still in the design phase. Establishing efficient disposal options for the secondary wastes can enable more timely and cost-effective operation and closure of the facilities.


Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot

Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot
Author: National Research Council
Publisher: National Academies Press
Total Pages: 113
Release: 2001-09-27
Genre: Science
ISBN: 0309170516

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The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee's scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo. The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.


Alternatives for the Demilitarization of Conventional Munitions

Alternatives for the Demilitarization of Conventional Munitions
Author: National Academies of Sciences, Engineering, and Medicine
Publisher: National Academies Press
Total Pages: 133
Release: 2019-01-11
Genre: Technology & Engineering
ISBN: 0309477352

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The U.S. military has a stockpile of approximately 400,000 tons of excess, obsolete, or unserviceable munitions. About 60,000 tons are added to the stockpile each year. Munitions include projectiles, bombs, rockets, landmines, and missiles. Open burning/open detonation (OB/OD) of these munitions has been a common disposal practice for decades, although it has decreased significantly since 2011. OB/OD is relatively quick, procedurally straightforward, and inexpensive. However, the downside of OB and OD is that they release contaminants from the operation directly into the environment. Over time, a number of technology alternatives to OB/OD have become available and more are in research and development. Alternative technologies generally involve some type of contained destruction of the energetic materials, including contained burning or contained detonation as well as contained methods that forego combustion or detonation. Alternatives for the Demilitarization of Conventional Munitions reviews the current conventional munitions demilitarization stockpile and analyzes existing and emerging disposal, treatment, and reuse technologies. This report identifies and evaluates any barriers to full-scale deployment of alternatives to OB/OD or non-closed loop incineration/combustion, and provides recommendations to overcome such barriers.


Environmental Pollution and Control

Environmental Pollution and Control
Author: J. Jeffrey Peirce
Publisher: Butterworth-Heinemann
Total Pages: 409
Release: 1998-01-15
Genre: Science
ISBN: 0080531113

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Complex environmental problems are often reduced to an inappropriate level of simplicity. While this book does not seek to present a comprehensive scientific and technical coverage of all aspects of the subject matter, it makes the issues, ideas, and language of environmental engineering accessible and understandable to the nontechnical reader. Improvements introduced in the fourth edition include a complete rewrite of the chapters dealing with risk assessment and ethics, the introduction of new theories of radiation damage, inclusion of environmental disasters like Chernobyl and Bhopal, and general updating of all the content, specifically that on radioactive waste. Since this book was first published in 1972, several generations of students have become environmentally aware and conscious of their responsibilities to the planet earth. Many of these environmental pioneers are now teaching in colleges and universities, and have in their classes students with the same sense of dedication and resolve that they themselves brought to the discipline. In those days, it was sometimes difficult to explain what indeed environmental science or engineering was, and why the development of these fields was so important to the future of the earth and to human civilization. Today there is no question that the human species has the capability of destroying its collective home, and that we have indeed taken major steps toward doing exactly that. And yet, while, a lot has changed in a generation, much has not. We still have air pollution; we still contaminate our water supplies; we still dispose of hazardous materials improperly; we still destroy natural habitats as if no other species mattered. And worst of all, we still continue to populate the earth at an alarming rate. There is still a need for this book, and for the college and university courses that use it as a text, and perhaps this need is more acute now than it was several decades ago. Although the battle to preserve the environment is still raging, some of the rules have changed. We now must take into account risk to humans, and be able to manipulate concepts of risk management. With increasing population, and fewer alternatives to waste disposal, this problem is intensified. Environmental laws have changed, and will no doubt continue to evolve. Attitudes toward the environment are often couched in what has become known as the environmental ethic. Finally, the environmental movement has become powerful politically, and environmentalism can be made to serve a political agenda. In revising this book, we have attempted to incorporate the evolving nature of environmental sciences and engineering by adding chapters as necessary and eliminating material that is less germane to today's students. We have nevertheless maintained the essential feature of this book -- to package the more important aspects of environmental engineering science and technology in an organized manner and present this mainly technical material to a nonengineering audience. This book has been used as a text in courses which require no prerequisites, although a high school knowledge of chemistry is important. A knowledge of college level algebra is also useful, but calculus is not required for the understanding of the technical and scientific concepts. We do not intend for this book to be scientifically and technically complete. In fact, many complex environmental problems have been simplified to the threshold of pain for many engineers and scientists. Our objective, however, is not to impress nontechnical students with the rigors and complexities of pollution control technology but rather to make some of the language and ideas of environmental engineering and science more understandable.