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Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites
Author: Sabu Thomas
Publisher: Elsevier
Total Pages: 578
Release: 2021-03-25
Genre: Technology & Engineering
ISBN: 0128213582

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Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications


Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites
Author: Sabu Thomas
Publisher: Elsevier
Total Pages: 576
Release: 2021-04-07
Genre: Science
ISBN: 0128213477

Download Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites Book in PDF, ePub and Kindle

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications


Polymer/POSS Nanocomposites and Hybrid Materials

Polymer/POSS Nanocomposites and Hybrid Materials
Author: Susheel Kalia
Publisher: Springer
Total Pages: 462
Release: 2018-11-27
Genre: Technology & Engineering
ISBN: 3030023273

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This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS’ role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.


POSS-Based Polymers

POSS-Based Polymers
Author: Ignazio Blanco
Publisher: MDPI
Total Pages: 310
Release: 2019-12-19
Genre: Technology & Engineering
ISBN: 3039219944

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The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.


Polymer Nanocomposites Containing Polyhedral Oligomeric Silsesquioxanes (POSS).

Polymer Nanocomposites Containing Polyhedral Oligomeric Silsesquioxanes (POSS).
Author:
Publisher:
Total Pages: 1
Release: 2004
Genre:
ISBN:

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Polyhedral oligomeric silsesquioxanes (POSS) are being examined for use in many applications. These applications include space-survivable coatings, and ablative and fire-resistant materials. POSS compounds have a rigid, inorganic core and have been produced with a wide range of organic functionality. Due to their physical size, POSS incorporation in polymers generally serves to reduce chain mobility, often improving both thermal and mechanical properties. Herein, we describe the preparation and properties of POSS compounds and their polymer nanocomposites.


Applications of Polyhedral Oligomeric Silsesquioxanes

Applications of Polyhedral Oligomeric Silsesquioxanes
Author: Claire Hartmann-Thompson
Publisher: Springer Science & Business Media
Total Pages: 440
Release: 2011-01-03
Genre: Science
ISBN: 904813787X

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The commercial availability and decreasing cost of polyhedral oligomeric silsesquioxanes in recent years has opened up the field to everybody who wishes to apply these unique properties in their own technologies. This is the first book to provide a comprehensive overview of these applications, and covers the synthesis, characterization and history of polyhedral oligomeric silsesquioxanes, their use as metallasilsesquioxane catalysts, their effect upon polymer properties and plastics performance, and their use in superhydrophobic nanocomposites, and electronics, energy, space and biomedical applications. "Applications of Polyhedral Oligomeric Silsesquioxanes" is a valuable reference for those working across a range of disciplines, including chemists, materials scientists, polymer physicists, plastics engineers, surface scientists, and anybody with a commercial or academic interest in plastics, composite materials, space materials, dental materials, tissue engineering, drug delivery, lithography, fuel cells, batteries, lubricants, or liquid crystal, LED, sensor, photovoltaic or biomedical devices.


Polymer Nanocomposites Designed with Polyhedral Oligomeric Silsesquioxanes (POSS) and Plastics

Polymer Nanocomposites Designed with Polyhedral Oligomeric Silsesquioxanes (POSS) and Plastics
Author:
Publisher:
Total Pages: 2
Release: 2005
Genre:
ISBN:

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Polyhedral oligomeric silsesquioxanes (POSS) are nanoparticles that are used to enhance the thermal and mechanical properties of polymeric systems and are being examined for use in many applications. These applications include space-survivable coatings and fire-resistant materials. Due to their physical size, POSS incorporation in polymers generally serves to reduce chain mobility, thus affecting both thermal and mechanical properties. Polymeric materials are typically tough, lightweight, and easy to process. However, they often lack resistance to oxidation and degrade at high temperatures. Ceramic materials, on the other hand, are thermally stable and have high oxidative resistance, but are brittle and difficult to process. POSS materials contain a thermally robust inorganic core that is surrounded by an organic corona (figure 1), which increases miscibility with a polymer. Because of a wide range of available organic functionalities, POSS have been incorporated into many polymer systems and found to improve the polymer thermo-oxidative stability.


Silicon Containing Hybrid Copolymers

Silicon Containing Hybrid Copolymers
Author: Chaobin He
Publisher: John Wiley & Sons
Total Pages: 286
Release: 2020-01-31
Genre: Technology & Engineering
ISBN: 3527823484

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Combines chemistry and material science in order to provide a complete overview of the design, synthesis, and applications of organo-silica This book offers comprehensive and systematic coverage of the latest developments in functional hybrid silicon copolymers, their applications, and how they were developed in relation to previous works in the preparation of various functional groups terminated silicone materials. Silicon Containing Hybrid Copolymers begins with a chapter that introduces readers to organo-silicon materials. It then presents a chapter on reactive functionally terminated polyorganosiloxanes, and contains a section on the methods and advances of functionalized polyhedral oligomeric silsesquioxanes (POSS) and copolymers. Nanostructured self-assemblies from silicon containing hybrid copolymers are discussed?as are superhydrophobic materials derived from hybrid silicon. Other chapters examine silicone copolymers for healthcare and personal care applications; construction of organic optoelectronic materials by using polyhedral oligomeric silsesquioxanes (POSS); and 3D printing silicone materials and devices. The book also includes an overview of material toughening and fire retardancy in regards to hybrid POSS nanocomposites. This title: -Focuses on design and synthesis strategies, providing a valuable resource for researchers in academia and industry -Presents recent applications, with emphasis on the underlying strategies and the influence from previous designs, in fields such as healthcare and consumer care -Combines synthetic pathways with design specific considerations to provide the reader with greater control over the design process Silicon Containing Hybrid Copolymers is an ideal book for materials scientists, polymer chemists, and bioinorganic chemists.


Nanomaterials and Nanocomposites

Nanomaterials and Nanocomposites
Author: Visakh P. M.
Publisher: John Wiley & Sons
Total Pages: 420
Release: 2016-06-27
Genre: Technology & Engineering
ISBN: 3527337806

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Nanomaterials are defined as materials in which at least one length dimension is below 100 nanometers. In this size regime, these materials exhibit particular - and tunable - optical, electrical or mechanical properties that are not present at the macro-scale. This opens up the possibility for a plethora of applications at the interface of materials, chemistry, physics and biology, many of which have already entered the commercial realm. When nanomaterials are blended with other materials not necessarily in the nanometer regime, the resulting nanocomposites can exhibit dramatically different properties than the bulk material alone, leading to an enhanced performance in terms of, for example, increased thermal and mechanical stability. This book presents the synthesis, characterization and applications of nanomaterials and nanocomposites, covering zero-dimensional, elemental nanoparticles, one-dimensional materials such as nanorods and nanowhiskers, two-dimensional materials such as graphene and boron nitride as well as three-dimensional materials such as fullerenes, polyhedral oligomers and zeolites, complemented by bio-based nanomaterials, e.g., cellulose, chitin, starch and proteins. Introductory chapters on the state-of-the-art of nanomaterial research and the chemistry and physics in nanoscience and nanotechnology round off the book.