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Plasmon-enhanced light-matter interactions

Plasmon-enhanced light-matter interactions
Author: Peng Yu
Publisher: Springer Nature
Total Pages: 348
Release: 2022-03-01
Genre: Science
ISBN: 303087544X

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This book highlights cutting-edge research in surface plasmons, discussing the different types and providing a comprehensive overview of their applications. Surface plasmons (SPs) receive special attention in nanoscience and nanotechnology due to their unique optical, electrical, magnetic, and catalytic properties when operating at the nanoscale. The excitation of SPs in metal nanostructures enables the manipulation of light beyond the diffraction limit, which can be utilized for enhancing and tailoring light-matter interactions and developing ultra-compact high-performance nanophotonic devices for various applications. With clear and understandable illustrations, tables, and descriptions, this book provides physicists, materials scientists, chemists, engineers, and their students with a fundamental understanding of surface plasmons and device applications as a basis for future developments.


Plasmonics and Light–Matter Interactions in Two-Dimensional Materials and in Metal Nanostructures

Plasmonics and Light–Matter Interactions in Two-Dimensional Materials and in Metal Nanostructures
Author: Paulo André Dias Gonçalves
Publisher: Springer Nature
Total Pages: 232
Release: 2020-03-19
Genre: Science
ISBN: 3030382915

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This thesis presents a comprehensive theoretical description of classical and quantum aspects of plasmonics in three and two dimensions, and also in transdimensional systems containing elements with different dimensionalities. It focuses on the theoretical understanding of the salient features of plasmons in nanosystems as well as on the multifaceted aspects of plasmon-enhanced light–matter interactions at the nanometer scale. Special emphasis is given to the modeling of nonclassical behavior across the transition regime bridging the classical and the quantum domains. The research presented in this dissertation provides useful tools for understanding surface plasmons in various two- and three-dimensional nanostructures, as well as quantum mechanical effects in their response and their joint impact on light–matter interactions at the extreme nanoscale. These contributions constitute novel and solid advancements in the research field of plasmonics and nanophotonics that will help guide future experimental investigations in the blossoming field of nanophotonics, and also facilitate the design of the next generation of truly nanoscale nanophotonic devices.


Subwavelength Surface Plasmons Based on Novel Structures and Metamaterials

Subwavelength Surface Plasmons Based on Novel Structures and Metamaterials
Author: Ruoxi Yang
Publisher:
Total Pages: 344
Release: 2013
Genre: Nanophotonics
ISBN:

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"With the rapid development of nanofabrication technology and powerful computational tools over the last decade, nanophotonics has enjoyed tremendous innovation and found wide applications in ultrahigh-speed data transmission, sensitive optical detection, manipulation of ultra-small objects, and visualization of nanoscale patterns. Surface plasmon-based photonics (or plasmonics) merges electronics and photonics at the nanoscale, creating the ability to combine the superior technical advantages of photonics and electronics on the same chip. Plasmonics focuses on the innovation of photonic devices by exploiting the optical property of metals. In particular, the oscillation of free electrons, when properly driven by electromagnetic waves, would form plasmon-polaritons in the vicinity of a metal surface and potentially result in extreme light confinement, which may beat the diffraction limit faced by conventional photonic devices and enable greatly enhanced light-matter interactions at the deep subwavelength scale. The objective of this dissertation is to develop subwavelength or deep subwavelength plasmonic waveguides and explore their integration on conventional dielectric platforms for multiple applications. three novel structures (or mechanisms) are employed to develop and integrate nanoplasmonic waveguides; each consists of one part of the dissertation. The first part of this dissertation covers the design, fabrication, and demonstration of two-dimensional and three-dimensional metal-insulator-metal plasmonic couplers for mode transformation between photonic and nanoplasmonic domains on the silicon-on-insulator platform. In particular, deep subwavelength plasmonic modes under 100-nm are achieved via end-fire coupling and adiabatic mode transformation at telecom wavelengths. The second part studies metallic gratings as spoof plasmonic waveguides hosting deep subwavelength surface propagation modes. Metallic gratings under different dielectric coatings are numerically investigated for terahertz and gigahertz regions. the third part proposes, explores, and experimentally demonstrates the 'metametal' for super surface wave excitation based on multilayered metal-insulator stacks, where the dispersion of the supported surface modes can be engineered by insulator dopant films in a given metal. The final part discusses the potential applications of active plasmonics for optical sensing, modulation and photovoltaics."--Abstract.


Plasmonic Nanoguides and Circuits

Plasmonic Nanoguides and Circuits
Author: Sergey Bozhevolnyi
Publisher: CRC Press
Total Pages: 320
Release: 2019-05-08
Genre: Technology & Engineering
ISBN: 0429533640

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In this book, the authors concentrate on the surface Plasmon (SP) waveguide configurations ensuring nanoscale confinement and review the current status of this rapidly emerging field, considering different configurations being developed for nanoscale plasmonic guides and circuits. Both fundamental physics and application aspects of plasmonics are reviewed in detail by the world's leading experts. A unique feature of this book is its strong focus on a particular subfield of plasmonics dealing with subwavelength (nanoscale) waveguiding, an area which is especially important in view of the explosively growing interest in plasmonic interconnects and nanocircuits.


Plasmonic Devices Employing Extreme Light Concentration

Plasmonic Devices Employing Extreme Light Concentration
Author: Ragip Pala
Publisher: Stanford University
Total Pages: 95
Release: 2010
Genre:
ISBN:

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The development of integrated electronic and photonic circuits has led to remarkable data processing and transport capabilities that permeate almost every facet of our daily lives. Scaling these devices to smaller and smaller dimensions has enabled faster, more power efficient and inexpensive components but has also brought about a myriad of new challenges. One very important challenge is the growing size mismatch between electronic and photonic components. To overcome this challenge, we will need to develop radically new device technologies that can facilitate information transport between nanoscale components at optical frequencies and form a bridge between the world of nano-electronic and micro-photonics. Plasmonics is an exciting new field of science and technology that aims to exploit the unique optical properties of metallic nanostructures to gain a new level of control over light-matter interactions. The use of nanometallic (plasmonic) structures may help bridge the size gap between the two technologies and enable an increased synergy between chip-scale electronics and photonics. In the first part of this dissertation we analyze the performance of a surface plasmon-polariton all-optical switch that combines the unique physical properties of small molecules and metallic (plasmonic) nanostructures. The switch consists of a pair of gratings defined on an aluminum film coated with a thin layer of photochromic (PC) molecules. The first grating couples a signal beam consisting of free space photons to SPPs that interact effectively with the PC molecules. These molecules can reversibly be switched between transparent and absorbing states using a free space optical pump. In the transparent (signal "on") state, the SPPs freely propagate through the molecular layer, and in the absorbing (signal "off") state, the SPPs are strongly attenuated. The second grating serves to decouple the SPPs back into a free space optical beam, enabling measurement of the modulated signal with a far-field detector. We confirm and quantify the switching behavior of the PC molecules by using a surface plasmon resonance spectroscopy. The quantitative experimental and theoretical analysis of the nonvolatile switching behavior guides the design of future nanoscale optically or electrically pumped optical switches. In the second part of the dissertation we provide a critical assessment of the opportunities for use of plasmonic nanostructures in thin film solar cell technology. Thin-film solar cells have attracted significant attention as they provide a viable pathway towards reduced materials and processing costs. Unfortunately, the materials quality and resulting energy conversion efficiencies of such cells is still limiting their rapid large-scale implementation. The low efficiencies are a direct result of the large mismatch between electronic and photonic length scales in these devices; the absorption depth of light in popular PV semiconductors tends to be longer than the electronic (minority carrier) diffusion length in deposited thin-film materials. As a result, charge extraction from optically thick cells is challenging due to carrier recombination in the bulk of the semiconductor. We discuss how light absorption could be improved in ultra-thin layers of active material making use of large scattering cross sections of plasmonic structures. We present a combined computational-experimental study aimed at optimizing plasmon-enhanced absorption using periodic and non-periodic metal nanostructure arrays.


Active Control of Surface Plasmons in Hybrid Nanostructures

Active Control of Surface Plasmons in Hybrid Nanostructures
Author: Sukanya Randhawa
Publisher:
Total Pages: 176
Release: 2013
Genre:
ISBN:

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Plasmonics nanostructures are becoming remarkably important as tools towards manipulating photons at the nanoscale. They are poised to revolutionize a wide range of applications ranging from integrated optical circuits, photovoltaics, and biosensing. They enable miniaturization of optical components beyond the "diffraction limit'' as they convert optical radiation into highly confined electromagnetic near-fields in the vicinity of subwavelength metallic structures due to excitation of surface plasmons (SPs). These strong electromagnetic fields generated at the plasmonic "hot spots'' raise exciting prospects in terms of driving nonlinear effects in active media. The area of active plasmonics aims at the modulation of SPs supported at the interface of a metal and a nonlinear material by an external control signal. The nonlinear material changes its refractive index under an applied control signal, thereby resulting in an overall altered plasmonic response. Such hybrid nanostructures also allow for the creation of new kinds of hybrid states. This not only provides tools for designing active plasmonic devices, but is also a means of re-examining existing conventional rules of light-matter interactions. Therefore, the need for studying such hybrid plasmonic nanostructures both theoretically and experimentally cannot be understated. The present work seeks to advance and study the control of SPs excited in hybrid systems combining active materials and nanometallics, by an external optical signal or an applied voltage. Different types of plasmonic geometries have been explored via modeling tools such as frequency domain methods, and further investigated experimentally using both near-field and far field techniques such as scanning near field optical microscopy and leakage radiation microscopy respectively. First, passive SP elements were studied, such as the dielectric plasmonic mirrors that demonstrate the ability of gratings made of dielectric ridges placed on top of flat metal layers to open gaps in the dispersion relation of surface plasmon polaritons (SPPs). The results show very good reflecting properties of these mirrors for a propagating SPP whose wavelength is inside the gap. Another passive configuration employed was a plasmonic resonator consisting of dielectric-loaded surface plasmon polariton waveguide ring resonator (WRR). Also, a more robust variant has been proposed by replacing the ring in the WRR with a disk (WDR). The performance in terms of wavelength selectivity and efficiency of the WDRs was evaluated and was shown to be in good agreement with numerical results. Control of SPP signal was demonstrated in the WRR configuration both electro-optically and all-optically. In the case of electro-optical control, the dielectric host matrix was doped with an electro-optical material and combined with an appropriate set of planar electrodes. A 16% relative change of transmission upon application of a controlled electric field was measured. For all-optical control, nonlinearity based on trans-cis isomerization in a polymer material is utilized. More than a 3-fold change between high and low transmission states of the device at milliwatt control powers ( ̃100 W/cm̂2 intensity) was observed. Beyond the active control of propagating surface plasmons, further advancement can be achieved by means of nanoscale plasmonic structures supporting localized surface plasmons (LSP). Interactions of molecular excitations in a pi-conjugated polymer with plasmonic polarizations are investigated in hybrid plasmonic cavities. Insights into the fundamentals of enhanced light-matter interactions in hybrid subwavelength structures with extreme light concentration are drawn, using ultrafast pump-probe spectroscopy. This thesis also gives an overview of the challenges and opportunities that hybrid plasmonic functionalities provide in the field of plasmon nano optics.


Cavity-coupled Plasmonic Systems for Enhanced Light-matter Interactions

Cavity-coupled Plasmonic Systems for Enhanced Light-matter Interactions
Author: Abraham Vázquez-Guardado
Publisher:
Total Pages: 136
Release: 2018
Genre:
ISBN:

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Light-matter interaction is a pivotal effect that involves the synergetic interplay of electromagnetic fields with fundamental particles. In this regard localized surface plasmons (LSP) arise from coherent interaction of the electromagnetic field with the collective oscillation of free electrons in confined sub-wavelength environments. Their most attractive properties are strong field enhancements at the near field, highly inhomogeneous, peculiar temporal and spatial distributions and unique polarization properties. LSP systems also offer a unique playground for fundamental electromagnetic physics where micro-scale systemic properties can be studied in the macro-scale. These important properties and opportunities are brought up in this work where I study hybrid cavity-coupled plasmonic systems in which the weak plasmonic element is far-field coupled with the photonic cavity by properly tuning its phase. In this work I preset the fundamental understanding of such a complex systems from the multi-resonance interaction picture along experimental demonstration. Using this platform and its intricate near fields I further demonstrate a novel mechanism to generate superchiral light: a field polarization property that adds a degree of freedom to light-matter interactions at the nanoscale exploited in advanced sensing applications and surface effect processes. Finally, the detection of non-chiral analytes, such as proteins, neurotransmitters or nanoparticles, and more complex chiral analytes, such as proteins and its conformation states, amino acids or chiral molecules at low concentrations is demonstrated in several biosensing applications. The accompanied experiential demonstrations were accomplished using the nanoimprinting technique, which places the cavity-coupled hybrid plasmonic system as a unique platform towards realistic applications not limited by expensive lithographic techniques.


Collective Plasmon-Modes in Gain Media

Collective Plasmon-Modes in Gain Media
Author: V.A.G. Rivera
Publisher: Springer
Total Pages: 147
Release: 2014-09-03
Genre: Science
ISBN: 3319095250

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This book represents the first detailed description, including both theoretical aspects and experimental methods, of the interaction of rare-earth ions with surface plasmon polariton from the point of view of collective plasmon-photon interactions via resonance modes (metal nanoparticles or nanostructure arrays) with quantum emitters (rare-earth ions). These interactions are of particular interest for applications to optical telecommunications, optical displays, and laser solid state technologies. Thus, our main goal is to give a more precise overview of the rapidly emerging field of nanophotonics by means of the study of the quantum properties of light interaction with matter at the nanoscale. In this way, collective plasmon-modes in a gain medium result from the interaction/coupling between a quantum emitter (created by rare-earth ions) with a metallic surface, inducing different effects such as the polarization of the metal electrons (so-called surface plasmon polariton - SPP), a field enhancement sustained by resonance coupling, or transfer of energy due to non-resonant coupling between the metallic nanostructure and the optically active surrounding medium. These effects counteract the absorption losses in the metal to enhance luminescence properties or even to control the polarization and phase of quantum emitters. The engineering of plasmons/SPP in gain media constitutes a new field in nanophotonics science with a tremendous technological potential in integrated optics/photonics at the nanoscale based on the control of quantum effects. This book will be an essential tool for scientists, engineers, and graduate and undergraduate students interested not only in a new frontier of fundamental physics, but also in the realization of nanophotonic devices for optical telecommunication.


Plasmonics: Fundamentals and Applications

Plasmonics: Fundamentals and Applications
Author: Stefan Alexander Maier
Publisher: Springer Science & Business Media
Total Pages: 234
Release: 2007-05-16
Genre: Technology & Engineering
ISBN: 0387378251

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Considered a major field of photonics, plasmonics offers the potential to confine and guide light below the diffraction limit and promises a new generation of highly miniaturized photonic devices. This book combines a comprehensive introduction with an extensive overview of the current state of the art. Coverage includes plasmon waveguides, cavities for field-enhancement, nonlinear processes and the emerging field of active plasmonics studying interactions of surface plasmons with active media.