Photomechanical Materials Composites And Systems PDF Download

Composite photomechanical materials are capable of controlled shape transformation under light illumination and external stimuli. The focus of this thesis is to study the mechanism of light-induced mechanical response of various polymeric materials by measuring their stress response under various controlled conditions such as light polarization, wavelength and temperature to isolate the various possible mechanisms. All devices fall into four classes including logic, information, transmission, actuation, sensing and are powered with light or electricity. The only missing piece to enable an all-optical technology is light induced actuation. This is the focus of this dissertation. Designing photomechnical materials and composites requires the control of photo-chemistry, the material's mechanical properties, and the strength of light-matter interaction. The two known mechanisms responsible for this effect are photo-isomerization of azo dye molecules that are embedded into the polymer matrix and photo-thermal heating due to absorption of light. Both processes are inefficient and slow. In addition, the two effects can couple, thus complicating the analysis. We have developed a protocol to isolate the individual mechanisms using experiments that are guided by and analyzed with theory. The method has been demonstrated inknown materials and is generalizable to study the response of new materials. The ftting functions yield the microscopic parameters that govern the bulk photomechanicalresponse. These parameters, which can be associated with various components of the material, are visualized as a composite made of springs that denes the photomorphon, whose length and spring constant changes upon light excitation. A population model relates the microscopic properties of the photomorphon to the dynamics of the bulk material, making it possible to fully characterize the parameters by measuring the stress as a function of time, temperature, and intensity. The experiments, theory, and method of analysis presented here can be used to study the mechanisms of the response, identify good materials, and to develop new composites with properties that are optimized for a given application.