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| Author | : Mats Hillert |
| Publisher | : Cambridge University Press |
| Total Pages | : 525 |
| Release | : 2007-11-22 |
| Genre | : Technology & Engineering |
| ISBN | : 1139465864 |
Download Phase Equilibria, Phase Diagrams and Phase Transformations Book in PDF, ePub and Kindle
Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
| Author | : Stanley M. Walas |
| Publisher | : Butterworth-Heinemann |
| Total Pages | : 689 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483145085 |
Download Phase Equilibria in Chemical Engineering Book in PDF, ePub and Kindle
Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.
| Author | : Andreas L. Muhlbauer |
| Publisher | : Taylor & Francis |
| Total Pages | : 486 |
| Release | : 2023-02-03 |
| Genre | : Science |
| ISBN | : 1351425064 |
Download Phase Equilibria Book in PDF, ePub and Kindle
This work provides coverage of experimental and theoretical procedures for vapour-liquid equilibria (VLE). A survey of the different models and approaches in recent literature enables the reader to choose the appropriate action.
| Author | : Andre Muhlbauer |
| Publisher | : CRC Press |
| Total Pages | : 490 |
| Release | : 1997-09-01 |
| Genre | : Science |
| ISBN | : 9781560325505 |
Download Phase Equilibria Book in PDF, ePub and Kindle
This new book provides, for the first time, a thorough survey of the techniques and equipment for both high- and low-pressure phase equilibrium measurement and addresses the equally challenging task of accurately modeling or predicting the equilibria. The book is unique because it combines in depth and authoritative coverage of both experimental and theoretical procedures in a single volume. Written as a reference for practicing engineers and scientists in the chemical engineering field, this book will also be useful as an advanced graduate-level text.
| Author | : Esteban Alberto Brignole |
| Publisher | : Newnes |
| Total Pages | : 347 |
| Release | : 2013-04-02 |
| Genre | : Technology & Engineering |
| ISBN | : 044459471X |
Download Phase Equilibrium Engineering Book in PDF, ePub and Kindle
Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. Methodologies are discussed using relevant industrial examples The molecular nature and composition of the process mixture is given a key role in process decisions Phase equilibrium diagrams are used as a drawing board for process implementation
| Author | : Arnold Reisman |
| Publisher | : Elsevier |
| Total Pages | : 560 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483265846 |
Download Phase Equilibria Book in PDF, ePub and Kindle
Phase Equilibria: Basic Principles, Applications, Experimental Techniques presents an analytical treatment in the study of the theories and principles of phase equilibria. The book is organized to afford a deep and thorough understanding of such subjects as the method of species model systems; condensed phase-vapor phase equilibria and vapor transport reactions; zone refining techniques; and nonstoichiometry. Physicists, physical chemists, engineers, and materials scientists will find the book a good reference material.
| Author | : Ismail Tosun |
| Publisher | : Newnes |
| Total Pages | : 736 |
| Release | : 2012-10-17 |
| Genre | : Science |
| ISBN | : 0444594973 |
Download The Thermodynamics of Phase and Reaction Equilibria Book in PDF, ePub and Kindle
This book provides you with a sound foundation for understanding abstract concepts (eg physical properties such as fugacity, etc or chemical processes, ie distillation, etc) of phase and reaction equilibria and shows you how to apply these concepts to solve practical problems using numerous and clear examples.
| Author | : Bruno Predel |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 357 |
| Release | : 2013-03-09 |
| Genre | : Science |
| ISBN | : 366209276X |
Download Phase Diagrams and Heterogeneous Equilibria Book in PDF, ePub and Kindle
This advanced comprehensive textbook introduces the practical application of phase diagrams to the thermodynamics of materials consisting of several phases. It describes the fundamental physics and thermodynamics as well as experimental methods, treating all material classes: metals, glasses, ceramics, polymers, organic materials, aqueous solutions. With many application examples and realistic cases from chemistry and materials science, it is intended for students and researchers in chemistry, metallurgy, mineralogy, and materials science as well as in engineering and physics. The authors treat the nucleation of phase transitions, the production and stability of technologically important metastable phases, and metallic glasses. Also concisely presented are the thermodynamics and composition of polymer systems. This innovative text puts this powerful analytical approach into a readily understandable and practical context, perhaps for the first time.
| Author | : Ulrich K Deiters |
| Publisher | : Elsevier |
| Total Pages | : 363 |
| Release | : 2012-04-26 |
| Genre | : Technology & Engineering |
| ISBN | : 0444563547 |
Download High-Pressure Fluid Phase Equilibria Book in PDF, ePub and Kindle
The book begins with an overview of the phase diagrams of fluid mixtures (fluid = liquid, gas, or supercritical state), which can show an astonishing variety when elevated pressures are taken into account; phenomena like retrograde condensation (single and double) and azeotropy (normal and double) are discussed. It then gives an introduction into the relevant thermodynamic equations for fluid mixtures, including some that are rarely found in modern textbooks, and shows how they can they be used to compute phase diagrams and related properties. This chapter gives a consistent and axiomatic approach to fluid thermodynamics; it avoids using activity coefficients. Further chapters are dedicated to solid-fluid phase equilibria and global phase diagrams (systematic search for phase diagram classes). The appendix contains numerical algorithms needed for the computations. The book thus enables the reader to create or improve computer programs for the calculation of fluid phase diagrams. introduces phase diagram classes, how to recognize them and identify their characteristic features presents rational nomenclature of binary fluid phase diagrams includes problems and solutions for self-testing, exercises or seminars
| Author | : Tarek Ahmed |
| Publisher | : Gulf Professional Publishing |
| Total Pages | : 149 |
| Release | : 2009-08-27 |
| Genre | : Technology & Engineering |
| ISBN | : 1856179028 |
Download Working Guide to Vapor-Liquid Phase Equilibria Calculations Book in PDF, ePub and Kindle
Working Guide to Vapor-Liquid Phase Equilibria Calculations offers a practical guide for calculations of vapor-phase equilibria. The book begins by introducing basic concepts such as vapor pressure, vapor pressure charts, equilibrium ratios, and flash calculations. It then presents methods for predicting the equilibrium ratios of hydrocarbon mixtures: Wilson's correlation, Standing's correlation, convergence pressure method, and Whitson and Torp correlation. The book describes techniques to determine equilibrium ratios of the plus fraction, including Campbell's method, Winn's method, and Katz's method. The remaining chapters cover the solution of phase equilibrium problems in reservoir and process engineering; developments in the field of empirical cubic equations of state (EOS) and their applications in petroleum engineering; and the splitting of the plus fraction for EOS calculations. Includes explanations of formulas Step by step calculations Provides examples and solutions
