Palladium In Heterocyclic Chemistry PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Palladium In Heterocyclic Chemistry PDF full book. Access full book title Palladium In Heterocyclic Chemistry.
Author | : Jie Jack Li |
Publisher | : Elsevier |
Total Pages | : 436 |
Release | : 2000 |
Genre | : Science |
ISBN | : 9780080437057 |
Download Palladium in Heterocyclic Chemistry Book in PDF, ePub and Kindle
For this text, Jack Li and Gordon Gribble have compiled an array of referenced examples of the use of palladium in heterocyclic chemistry.
Author | : Jie Jack Li |
Publisher | : Gulf Professional Publishing |
Total Pages | : 660 |
Release | : 2006-10-30 |
Genre | : Science |
ISBN | : 0080914411 |
Download Palladium in Heterocyclic Chemistry Book in PDF, ePub and Kindle
Palladium chemistry, despite its immaturity, has rapidly become an indispensable tool for synthetic organic chemists. Heterocycles are of paramount importance in the pharmaceutical industry and palladium chemistry is one of the most novel and efficient ways of making heterocycles. Today, palladium-catalyzed coupling is the method of choice for the synthesis of a wide range of biaryls and heterobiaryls. The number of applications of palladium chemistry to the syntheses of heterocycles has grown exponentially. These developments highlight the need for a monograph dedicated solely to the palladium chemistry in heterocycles and this book provides a comprehensive explanation of the subject. The principal aim of Palladium in Heterocyclic Chemistry is to highlight important palladium-mediated reactions of heterocycles with emphasis on the unique characteristics of individual heterocycles. 1. Palladium chemistry of heterocycles has its "idiosyncrasies" stemming from their different structural properties from the corresponding carbocyclic aryl compounds. Even activated chloroheterocycles are sufficiently reactive to undergo Pd-catalyzed reactions. As a consequence of &agr and &bgr activation of heteroaryl halides, Pd-catalyzed chemistry may take place regioselectively at the activated positions, a phenomenon rarely seen in carbocyclic aryl halides. In addition, another salient peculiarity in palladium chemistry of heterocycles is the so-called "heteroaryl Heck reaction". For instance, while intermolecular palladium-catalyzed arylations of carbocyclic arenes are rare, palladium-catalyzed arylations of azoles and many other heterocycles readily take place. Therefore, the principal aim of this book is to highlight important palladium-mediated reactions of heterocycles with emphasis on the unique characteristics of individual heterocycles. 2. A myriad of heterocycles are biologically active and therefore of paramount importance to medicinal and agricultural chemists. Many heterocycle-containing natural products (they are highlighted in boxes throughout the text) have elicited great interest from both academic and industrial research groups. Recognizing the similarities between the palladium chemistry of arenes and heteroarenes, a critical survey of the accomplishments in heterocyclic chemistry will keep readers abreast of such a fast-growing field. We also hope this book will spur more interest and inspire ideas in such an extremely useful area. This book comprises a compilation of important preparations of heteroaryl halides, boranes and stannanes for each heterocycle. The large body of data regarding palladium-mediated polymerization of heterocycles in material chemistry is not focused here; neither is coordination chemistry involving palladium and heterocycles. Many heterocycle-containing natural products (highlighted throughout the text) have elicited great interest from both academic and industrial research groups. Recognizing the similarities between the palladium chemistry of arenes and heteroarenes, a critical survey of the accomplishments in heterocyclic chemistry keeps readers abreast of this fast-growing field. It is also hoped that this book will stimulate more interest and inspire new ideas in this exciting field. Contains the most up-to-date developments in this fast-moving field Includes 3 new chapters Contains material from selected well-respected authors on heterocyclic chemistry
Author | : Jiro Tsuji |
Publisher | : Springer Science & Business Media |
Total Pages | : 348 |
Release | : 2005-07-06 |
Genre | : Science |
ISBN | : 9783540239826 |
Download Palladium in Organic Synthesis Book in PDF, ePub and Kindle
with contributions by numerous experts
Author | : Navjeet Kaur |
Publisher | : CRC Press |
Total Pages | : 432 |
Release | : 2019-05-01 |
Genre | : Medical |
ISBN | : 1351242601 |
Download Palladium Assisted Synthesis of Heterocycles Book in PDF, ePub and Kindle
This book is a compilation of the recent applications of palladium catalysts in organic synthesis. The book demonstrates that it is a highly dynamic research field. This methodology has emerged as a powerful tool for the efficient and chemoselective synthesis of heterocyclic molecules. In the past few years, several strategies have been pointed out to pursue more efficient, sustainable, and environment friendly chemical processes. Among those strategies, catalysis and the design of new processes that avoid the use of toxic reagents have been the focus of intense research.
Author | : Xiao-feng Wu |
Publisher | : World Scientific |
Total Pages | : 390 |
Release | : 2016-06-24 |
Genre | : Science |
ISBN | : 1783269251 |
Download Noble Metal Noble Value: Ru-, Rh-, Pd-catalyzed Heterocycle Synthesis Book in PDF, ePub and Kindle
Heterocyclic chemistry constitutes the largest branch of chemistry, covering almost two-thirds of literature in the field. In addition, around 90% of naturally-occurring molecules have heterocycles as their core structure. Therefore, as a central part of organic chemistry, the discovery of new methodologies in synthesizing heterocyclic compounds is essential to their continued application and development. Transition metal catalysts offer a low cost and often low toxicity pathway for heterocycles synthesis, while the use of noble metals represents an alternative form of experimentation which is discussed in the book.Noble Metals, Noble Value provides the first comprehensive analysis of the applications of the noble metals of ruthenium (Ru), rhodium (Rh) and palladium (Pd) catalysts in heterocycles synthesis. Pairs of chapters are dedicated to summarizing each of the metals when applied to either five- or six-membered heterocyclic syntheses. An introduction to the importance of heterocycles and possible procedures for the preparation of heterocyclic compounds is also given.With up to date research and findings, this review is excellently suited to academics and professionals in the field of chemistry, with a particular focus on the specialities of biological, catalytic and organic chemistry.
Author | : John A. Joule |
Publisher | : John Wiley & Sons |
Total Pages | : 332 |
Release | : 2012-08-06 |
Genre | : Science |
ISBN | : 1118380193 |
Download Heterocyclic Chemistry At A Glance Book in PDF, ePub and Kindle
This expanded second edition provides a concise overview of the main principles and reactions of heterocyclic chemistry for undergraduate students studying chemistry and related courses. Using a successful and student-friendly "at a glance" approach, this book helps the student grasp the essence of heterocyclic chemistry, ensuring that they can confidently use that knowledge when required. The chapters are thoroughly revised and updated with references to books and reviews; extra examples and student exercises with answers online; and color diagrams that emphasize exactly what is happening in the reaction chemistry depicted.
Author | : Jiro Tsuji |
Publisher | : John Wiley & Sons |
Total Pages | : 670 |
Release | : 2006-02-08 |
Genre | : Science |
ISBN | : 0470021195 |
Download Palladium Reagents and Catalysts Book in PDF, ePub and Kindle
Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.
Author | : Peter Joseph Bonk |
Publisher | : |
Total Pages | : 852 |
Release | : 1985 |
Genre | : |
ISBN | : |
Download Net [3+2]-type Heterocyclic Synthesis Via Organostannanes and Palladium Chemistry Book in PDF, ePub and Kindle
Author | : F. R. Hartley |
Publisher | : |
Total Pages | : 568 |
Release | : 1973 |
Genre | : Science |
ISBN | : |
Download The Chemistry of Platinum and Palladium: with Particular Reference to Complexes of the Elements Book in PDF, ePub and Kindle
Author | : Hyung Yoon |
Publisher | : Springer Nature |
Total Pages | : 236 |
Release | : 2020-09-02 |
Genre | : Science |
ISBN | : 3030540774 |
Download Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles Book in PDF, ePub and Kindle
This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon–carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C–H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.