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Oxygen-17 and Silicon-29

Oxygen-17 and Silicon-29
Author:
Publisher: Springer
Total Pages: 238
Release: 2014-03-12
Genre: Science
ISBN: 9783642877636

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Although it was shown very early [1] that the isotope 29Si is very valuable for NMR research, severe technical difficulties had to be overcome before silicon spectra could be recorded. This was due to the low sensitivity of the isotope resulting from its low gyro magnetic ratio, its low abundance and the rather long relaxation times. The introduction of the Fourier-Transform-Technique (FT-NMR) helped to surmount most of these problems, with the result, that more and more papers concerning silicon NMR appear. Thus, it seems now that most of the salient features of 29Si-NMR are known today. Some resume of the state of the art of 29Si_NMR have been reported [1-4]. Although the theory of 29Si-NMR is not yet understood beyond the basic features, it promises to be of value mainly for two reasons: 1. Silicon is strategically located in the Periodic Table of the elements between the elements carbon, aluminum and phosphorus. For an unified theory of chemical shifts and coupling constants of the heavier elements silicon NMR values will be important. 2. The normal coordination number of silicon is four. If the current view of the chemical shifts of the heavier elements is correct, then the paramagnetic part is dominant for the measured shift data. Two of the parameters used for the calcu lation of the paramagnetic part are bond orders and angles. Bond angles are rare ly determined experimentally with high precision.


Oxygen-17 and Silicon-29

Oxygen-17 and Silicon-29
Author:
Publisher: Springer
Total Pages: 238
Release: 2014-08-23
Genre: Science
ISBN: 9783642877643

Download Oxygen-17 and Silicon-29 Book in PDF, ePub and Kindle

Although it was shown very early [1] that the isotope 29Si is very valuable for NMR research, severe technical difficulties had to be overcome before silicon spectra could be recorded. This was due to the low sensitivity of the isotope resulting from its low gyro magnetic ratio, its low abundance and the rather long relaxation times. The introduction of the Fourier-Transform-Technique (FT-NMR) helped to surmount most of these problems, with the result, that more and more papers concerning silicon NMR appear. Thus, it seems now that most of the salient features of 29Si-NMR are known today. Some resume of the state of the art of 29Si_NMR have been reported [1-4]. Although the theory of 29Si-NMR is not yet understood beyond the basic features, it promises to be of value mainly for two reasons: 1. Silicon is strategically located in the Periodic Table of the elements between the elements carbon, aluminum and phosphorus. For an unified theory of chemical shifts and coupling constants of the heavier elements silicon NMR values will be important. 2. The normal coordination number of silicon is four. If the current view of the chemical shifts of the heavier elements is correct, then the paramagnetic part is dominant for the measured shift data. Two of the parameters used for the calcu lation of the paramagnetic part are bond orders and angles. Bond angles are rare ly determined experimentally with high precision.


Oxygen-17 and Silicon-29

Oxygen-17 and Silicon-29
Author: Jean-Pierre Kintzinger
Publisher: Springer
Total Pages: 252
Release: 1981
Genre: Science
ISBN:

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Oxygen-17 and Silicon-29

Oxygen-17 and Silicon-29
Author:
Publisher: Springer Science & Business Media
Total Pages: 242
Release: 2012-12-06
Genre: Science
ISBN: 3642877621

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Although it was shown very early [1] that the isotope 29Si is very valuable for NMR research, severe technical difficulties had to be overcome before silicon spectra could be recorded. This was due to the low sensitivity of the isotope resulting from its low gyro magnetic ratio, its low abundance and the rather long relaxation times. The introduction of the Fourier-Transform-Technique (FT-NMR) helped to surmount most of these problems, with the result, that more and more papers concerning silicon NMR appear. Thus, it seems now that most of the salient features of 29Si-NMR are known today. Some resume of the state of the art of 29Si_NMR have been reported [1-4]. Although the theory of 29Si-NMR is not yet understood beyond the basic features, it promises to be of value mainly for two reasons: 1. Silicon is strategically located in the Periodic Table of the elements between the elements carbon, aluminum and phosphorus. For an unified theory of chemical shifts and coupling constants of the heavier elements silicon NMR values will be important. 2. The normal coordination number of silicon is four. If the current view of the chemical shifts of the heavier elements is correct, then the paramagnetic part is dominant for the measured shift data. Two of the parameters used for the calcu lation of the paramagnetic part are bond orders and angles. Bond angles are rare ly determined experimentally with high precision.


Oxygen-17 and silicon-29

Oxygen-17 and silicon-29
Author: Jean-Pierre Kinitzinger
Publisher:
Total Pages:
Release: 1981
Genre:
ISBN:

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17 0 NMR Spectroscopy in Organic Chemistry

17 0 NMR Spectroscopy in Organic Chemistry
Author: David W. Boykin
Publisher: CRC Press
Total Pages: 336
Release: 2020-08-27
Genre: Science
ISBN: 1000141594

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This book provides a comprehensive review of the application of 17O NMR spectroscopy to organic chemistry. Topics include the theoretical aspects of chemical shift, quadrupolar and J coupling; 17O enrichment; the effect of steric interactions on 17O chemical shifts of functional groups in flexible and rigid systems; the application of 17O NMR spectroscopy to hydrogen bonding investigations; mechanistic problems in organic and bioorganic chemistry; and 17O NMR spectroscopy of oxygen monocoordinated to carbon in alcohols, ethers, and derivatives. Recent results that show correlations between molecular geometry, determined by X-ray studies and estimated by molecular mechanics calculations, and 17O chemical shifts are also covered. 17O Spectroscopy in Organic Chemistry provides important reference information for organic chemists and other scientists interested in 17O NMR spectroscopy as a tool for obtaining new structural and chemical data about organic molecules.


Structure and Bonding in Noncrystalline Solids

Structure and Bonding in Noncrystalline Solids
Author: George E. Walrafen
Publisher: Springer Science & Business Media
Total Pages: 444
Release: 2012-12-06
Genre: Science
ISBN: 1461594774

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Noncrystalline (NC) solids, as is well known, lack the long range order of crystals. Accordingly, they exhibit scattering, e.g., x-ray, electron, and neutron, but not the diffraction patterns characteristic of crystals. The intensity distributions from NC solids are usually transformed into radial distribution functions (RDF), but the interpretation of the RDF's is not unique. The lack of long-range order, and the non-uniqueness of the structural interpretation, have constituted the main obstacles to the usual solid state physics approach which has been so successful in dealing with crystals. As a corrolary, questions of local order and structure have frequently been de-emphasized. This monograph contains a collection of chapters many of which emphasize local-structure and chemical bonding as opposed to long-range order. Most of the chapters were chosen from talks given at the international symposium, "Structure and Bonding in Noncrystalline Solids," held in Reston, Virginia in May of 1983. Other chapters, however, were simply submitted independently of the Reston conference. Thus, this book is not a proceedings of that conference, nor was it ever intended to be. The chapters presented here range from theory of bonding and structure, to structurally oriented measurements of various kinds, e.g., ESR, Raman, to more applied chapters. Our goal was to produce a monograph that enhances understanding of the structures of NC solids.


ERDA Subject Indexing and Retrieval Thesaurus

ERDA Subject Indexing and Retrieval Thesaurus
Author: United States. Energy Research and Development Administration
Publisher:
Total Pages: 580
Release: 1975
Genre: Indexing
ISBN:

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A thesaurus for use by the Energy Research and Development Administration, allowing consistent cataloging and storage of information.


Nuclear Science Abstracts

Nuclear Science Abstracts
Author:
Publisher:
Total Pages: 1216
Release: 1976-06
Genre: Nuclear energy
ISBN:

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Gas Phase NMR

Gas Phase NMR
Author: Michał Jaszuński
Publisher: Royal Society of Chemistry
Total Pages: 418
Release: 2016-02-18
Genre: Medical
ISBN: 178262161X

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