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Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents

Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents
Author: Victor L. Cherginets
Publisher: Elsevier
Total Pages: 401
Release: 2005-02-15
Genre: Science
ISBN: 0080455247
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The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented. This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry. First book devoted to oxoacids and oxobases Aimed at specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena The perfect handbook for beginners looking for preliminary knowledge about methods of investigation

Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents

Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents
Author: Victor L. Cherginets
Publisher: Elsevier Science
Total Pages: 0
Release: 2005-02-28
Genre: Science
ISBN: 9780444550361
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The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented. This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry.

Molten Salts and Ionic Liquids 19

Molten Salts and Ionic Liquids 19
Author: W. Reichert
Publisher: The Electrochemical Society
Total Pages: 661
Release: 2014
Genre: Ionic solutions
ISBN: 1607685418
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Handbook of Solvents, Volume 1

Handbook of Solvents, Volume 1
Author: George Wypych
Publisher: Elsevier
Total Pages: 997
Release: 2024-02-07
Genre: Technology & Engineering
ISBN: 1774670410
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This 4th edition of Handbook of Solvents, Volume 1, contains the most recent findings and trends in solvent applications. It is a comprehensive survey of the science of solvents and their properties, covering all aspects of solvent behavior that are relevant to their use in chemical and related industries including agricultural and technical processes, inorganic synthesis and materials chemistry, and more. Divided into two volumes, this first volume covers high-level information on the physical chemical properties of the most relevant solvent systems. Each chapter is focused on a specific aspect of solvent properties that determine its selection, such as the effect on properties of solutes and solutions, properties of different groups of solvents, and the summary of their applications’ effect on health and the environment (given in tabulated form). Also covered is swelling of solids in solvents, solvent diffusion and drying processes, nature of the interaction of solvent and solute in solutions, acid-base interactions, the effect of solvents on spectral and other electronic properties of solutions, the effect of solvents on the rheology of the solution, aggregation of solutes, permeability, molecular structure, crystallinity, configuration, conformation of dissolved high molecular weight compounds, and the effect of solvents on chemical reactions and reactivity of dissolved substances. With insight from specialists in a broad array of different areas and written with an interdisciplinary audience in mind, this thoroughly revised 4th edition provides readers with a complete overview of all the organic solvents available for industrial applications today. The book contains numerous references to key sources of more detailed information, and together with Handbook of Solvents Volume 2: Use, Health, and Environment; Databook of Green Solvents; and Databook of Solvents, represents the most comprehensive and up-to-date information ever published on solvents. Provides key insights that will help engineers and scientists select the best solvent for the job Includes practical information and ideas on how to improve existing processes involving solvents Presents the latest advances in solvent technology and their applications

Comprehensive Chemical Kinetics

Comprehensive Chemical Kinetics
Author: C. H. Bamford
Publisher:
Total Pages: 418
Release: 2005
Genre: Chemical kinetics
ISBN:
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Chemistry in Non-Aqueous Solvents

Chemistry in Non-Aqueous Solvents
Author: B. Trémillon
Publisher: Springer Science & Business Media
Total Pages: 291
Release: 2012-12-06
Genre: Science
ISBN: 9401021236
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Arising no doubt from its pre-eminence as a natural liquid, water has always been considered by chemists as the original solvent in which very varied chemical reactions can take place, both for preparational and for analytical purposes. This explains the very long-standing interest shown in the study of aqueous solutions. In this con nection, it must be stressed that the theory of Arrhenius and Ostwald (1887-1894) on electrolytic dissociation, was originally devised solely for solutions in water and that the first true concept of acidity resulting from this is linked to the use of this solvent. The more recent development of numerous physico-chemical measurement methods has made possible an increase of knowledge in this area up to an extremely advanced degree of systematization. Thus today we have available both a very large amount of experimental data, together with very refined methods of deduction and of quantitative treatment of chemical reactions in solution which enable us to make the fullest use of this data. Nevertheless, . it appears quite evident at present that there are numerous chemical processes which cannot take place in water, and that its use as a solvent imposes 2 INTRODUCTION limitations. In order to overcome these limitations, it was natural that interest should be attracted to solvents other than water and that the new possibilities thus opened up should be explored.

Ionic and Electrochemical Equilibria

Ionic and Electrochemical Equilibria
Author: Michel Soustelle
Publisher: John Wiley & Sons
Total Pages: 306
Release: 2016-06-20
Genre: Science
ISBN: 1848218699
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This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been paid to the rigor of mathematical developments. This sixth volume is made up of two parts. The first part focuses on the study of ionic equilibria in water or non-aqueous solvents. The following are then discussed in succession: the dissociation of electrolytes, solvents and solvation, acid-base equilibria, formation of complexes, redox equilibria and the problems of precipitation. Part 2 discusses electrochemical thermodynamics, with the study of two groups: electrodes and electrochemical cells. The book concludes with the study of potential-pH diagrams and their generalization in an aqueous or non-aqueous medium.

Handbook of Solvents

Handbook of Solvents
Author: George Wypych
Publisher: ChemTec Publishing
Total Pages: 1446
Release: 2001
Genre: Science
ISBN: 1895198240
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A comprehensive, extensive textual analysis of the principles of solvent selection and use, the handbook is intended to help formulators select ideal solvents, safety coordinators to protect workers, and legislators and inspectors to define and implement technically correct public safeguards for use, handling, and disposal.

Electronics Engineering

Electronics Engineering
Author:
Publisher: Krishna Prakashan Media
Total Pages: 1740
Release:
Genre:
ISBN: 9788187224709
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