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Organic Reactions in Water

Organic Reactions in Water
Author: U. Marcus Lindstrom
Publisher: John Wiley & Sons
Total Pages: 424
Release: 2008-04-15
Genre: Science
ISBN: 047099424X
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Volatile organic solvents are the normal media used in both research scale and industrial scale synthesis of organic chemicals. Their environmental impact is significant, however, and so the development of alternative reaction media has become of great interest. Developments in the use of water as a solvent for organic synthesis have reached the point where it could now be considered a viable solvent for many organic reactions. Organic Reactions in Water demonstrates the underlying principles of using water as a reaction solvent and, by reference to a range of reaction types and systems, it’s effective use in synthetic organic chemistry. Written by an internationally respected team of contributors, and with a strong focus on the practical use of water as a reaction medium, this book illustrates the enormous potential of water for the development of new and unique chemistries and synthetic strategies, while at the same time offering a much reduced environmental impact.

Organic Synthesis in Water

Organic Synthesis in Water
Author: P.A. Grieco
Publisher: Springer Science & Business Media
Total Pages: 321
Release: 2012-12-06
Genre: Science
ISBN: 940114950X
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The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.

Solvents as Reagents in Organic Synthesis

Solvents as Reagents in Organic Synthesis
Author: Xiao-Feng Wu
Publisher: John Wiley & Sons
Total Pages: 552
Release: 2018-01-03
Genre: Science
ISBN: 352734196X
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Written by highly renowned and experienced authors, this is the only reference on the application of solvents as reagents. Clearly structured, the text describes various methods for the activation and reaction of these small molecules, highlighting the synthetic opportunities as well as process-oriented advantages. To this end, all relevant types of solvents are covered separately and emphasized with numerous synthetic examples, while taking care to explain applications so as to avoid undesired side reactions. The result is a unique resource for every synthetic chemist and reaction engineer in industry and academia working on the methodical optimization of synthetic transformations.

Green Organic Reactions

Green Organic Reactions
Author: Gopinathan Anilkumar
Publisher: Springer Nature
Total Pages: 349
Release: 2021-03-27
Genre: Technology & Engineering
ISBN: 9813368977
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This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.

Modern Solvents in Organic Synthesis

Modern Solvents in Organic Synthesis
Author: Paul Knochel
Publisher: Springer
Total Pages: 217
Release: 2003-07-01
Genre: Science
ISBN: 354048664X
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In recent years the choice of a given solvent for performing a reaction has become increasingly important. More and more, selective reagents are used for chemical transformations and the choice of the solvent may be determining for reaching high reaction rates and high selectivities. The toxicity and recycling considerations have also greatly influenced the nature of the solvents used for industrial reactions. Thus, the development of reactions in water is not only important on the laboratory scale but also for industrial applications. The p- formance of metal-catalyzed reactions in water for example has led to several new hydrogenation or hydroformylation procedures with important industrial applications. The various aspects of organic chemistry in water will be prese- ed in this book. Recently, novel reaction media such as perfluorinated solvents or supercritical carbon dioxide has proven to have unique advantages leading to more practical and more efficient reactions. Especially with perfluorinated solvents, new biphasic catalyses and novel approaches to perform organic reactions have been developed. These aspects will be examined in detail in this volume. Finally, the performance of reactions in the absence of solvents will show practical alternatives for many reactions. More than ever before, the choice of the solvent or the solvent system is ess- tial for realizing many chemical transformations with the highest efficiency. This book tries to cover the more recent and important new solvents or solvent systems for both academic and industrial applications.

Basic Techniques of Preparative Organic Chemistry

Basic Techniques of Preparative Organic Chemistry
Author: William Sabel
Publisher: Elsevier
Total Pages: 207
Release: 2013-09-03
Genre: Science
ISBN: 1483213773
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Basic Techniques of Preparative Organic Chemistry covers a detailed guide for carrying out the procedures commonly needed in preparative organic chemistry. The book discusses the nature of organic reactions; the basic principles of preparative organic chemistry; unit operations; and good laboratory practice. The text then provides a review of apparatus and equipment and describes the potential hazards involved in a chemical operation, such as toxicity, bodily injuries, smoking, fire, explosion, and implosion. Techniques and unit operations for carrying out a reaction and for isolating and purifying a reaction product; and the criteria for and methods of assessing purity are also considered. The book further tackles packing and storing products and samples and making reports and communications. Students taking organic chemistry courses will find the text useful.

Organic Synthesis in Water

Organic Synthesis in Water
Author: P.A. Grieco
Publisher: Springer
Total Pages: 310
Release: 2014-04-20
Genre: Science
ISBN: 9789401060776
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The use of water as a medium for promoting organic reactions has, for the most part, been non-existent, despite the fact that water has served, and continues to serve, as the solvent in which the vast majority of biochemical processes take place. Chemists have only recently come to appreciate the enormous potential that water holds for those engaged in synthetic organic and organometallic chemistry, in part because of water's unique enthalpic and entropic properties. In this volume, an international team of authors, each taking advantage of the unique properties of water for carrying out organic transformations, is brought together in order to provide a timely and concise overview of current research. The chapters focus on the practical use of water in synthetic organic chemistry, with special emphasis on Diels-Alder reactions, Claisen rearrangements, organometallic chemistry, transition-metal catalysis, oxida tions and reductions. I am grateful to my colleagues, J. Auge, I. Beletskaya, A. Cheprakov, F. Fringuelli, J. Gajewski, P. Gamer, S. Kobayashi, A. Lubineau, D. Parker, O. Piermatti, F. Pizzo and Y. Queneau, for participating in this venture. Their knowledge and experience have been invaluable in putting this volume together.

Comprehensive Organic Reactions in Aqueous Media

Comprehensive Organic Reactions in Aqueous Media
Author: Chao-Jun Li
Publisher: John Wiley & Sons
Total Pages: 435
Release: 2007-06-04
Genre: Science
ISBN: 0470131438
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An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.

Green Approaches in Medicinal Chemistry for Sustainable Drug Design

Green Approaches in Medicinal Chemistry for Sustainable Drug Design
Author: Bimal Krishna Banik
Publisher: Elsevier
Total Pages: 699
Release: 2024-05-31
Genre: Science
ISBN: 0443161674
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Extensive experimentation and high failure rates are a well-recognized downside to the drug discovery process, with the resultant high levels of inefficiency and waste producing a negative environmental impact. Sustainable and Green Approaches in Medicinal Chemistry 2e reveals how medicinal chemistry can play a direct role in addressing this issue. After providing essential context to the growth of green chemistry in relation to drug discovery, the book goes on to identify a broad range of practical techniques and useful insights, revealing how medicinal chemistry techniques can be used to improve efficiency, mitigate failure and increase the environmental benignity of the entire drug discovery process. Drawing on the knowledge of a global team of experts, Sustainable and Green Approaches in Medicinal Chemistry, Second Edition encourages the growth of green medicinal chemistry, and supports medicinal chemists, drug discovery researchers, pharmacologists and all those in related fields across both academia and industry in integrating these approaches into their own work. This second volume of the second edition includes the development of nanoparticles and nanocomposites, as well as the application of ultrasound and microwave-induced methods; studies solventless synthesis; defines the role of steroids; studies reactions in aqueous solution; identifies enzyme-mediated reactions; investigates ionic liquids and deep eutectic solvents; explores natural products; investigates solid supports; realizes the effects of salts; focuses on combinatorial chemistry; develops one-pot methods; analyzes multi-component reactions; investigates dipole moment values; and examines computer-assisted methods. Highlights the need for adoption of sustainable and green chemistry pathways in drug development Reveals risk factors associated with the drug development process and the ways sustainable approaches can help address these Identifies novel and cost effective green medicinal chemistry approaches for improved efficiency and sustainability

Named Organic Reactions

Named Organic Reactions
Author: Thomas Laue
Publisher: John Wiley & Sons
Total Pages: 320
Release: 2005-08-19
Genre: Science
ISBN: 0470026448
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This Second edition contains consise information on 134 carefully chosen named organic reactions - the standard set of undergraduate and graduate synthetic organic chemistry courses. Each reaction is detailed with clearly drawn mechanisms, references from the primary literature, and well-written accounts covering the mechanical aspects of the reactions, and the details of side reactions and substrate limitations. For the 2nd edition the complete text has been revised and updated, and four new reactions have been added: Baylis-Hillmann Reaction, Sonogashira Reaction, Pummerer Reaction, and the Swern Oxidation und Cyclopropanation. An essential text for students preparing for exams in organic chemistry.