Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download One Dimensional And Two Dimensional Phosphorus 31 Nuclear Magnetic Resonance Spectroscopy PDF full book. Access full book title One Dimensional And Two Dimensional Phosphorus 31 Nuclear Magnetic Resonance Spectroscopy.
| Author | : Jeanne Marie Van Divender |
| Publisher | : |
| Total Pages | : 404 |
| Release | : 1983 |
| Genre | : Adenosine triphosphate |
| ISBN | : |
| Author | : David G. Gorenstein |
| Publisher | : Academic Press |
| Total Pages | : 619 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0080918417 |
Phosphorous-31 NMR: Principles and Applications focuses on the evolution of phosphorus-31 nuclear magnetic resonance (NMR) as a widely applied spectroscopic probe of the structure and dynamics of phosphorus-containing compounds. The selection first offers information on the principles and empirical observations of phosphorus-31 chemical shifts and the principles and applications of phosphorus-31 spin-spin coupling constants. Discussions focus on introduction and basic principles, directly bonded phosphorus coupling constants, and two-bond and three-bond coupling constants. The text then ponders on phosphorus-31 NMR of enzyme complexes and paramagnetic probes of enzyme complexes with phosphorus-containing compounds. The manuscript elaborates on the use of chiral thiophosphates and the stereochemistry of enzymatic phosphoryl transfer and DNA and RNA conformations. Topics include helix-coil transitions, sequence dependence of double-stranded DNA conformations, dynamic behavior of RNA and DNA, biological and genetic significance, and stereochemical problems studied with chiral thiophosphates. The conformation and dynamics of nucleic acids and phosphoproteins, relaxation behavior of nucleic acids, and theory and applications of solid-state phosphorus-31 NMR to nucleic acids are also discussed. The selection is a valuable reference for readers interested in the principles and applications of phosphorus-31 nuclear magnetic resonance.
| Author | : Louis D. Quin |
| Publisher | : VCH Publishers |
| Total Pages | : 484 |
| Release | : 1994 |
| Genre | : Science |
| ISBN | : |
Presents advances in 31P NMR and coupling effects of the past six years (since VCH published its first jointly edited monograph on the subject). A wide cross-section of experts contribute a concise account of their use of 31P NMR in their own area of expertise, giving major emphasis to the research results they have obtained since the earlier monograph appeared. The volume is divided into nine sections: chemical shift theory; conformational analysis of phosphorus-containing ring systems; compounds with three-, four-, and five-coordinate phosphorus; low-coordinate phosphorus compounds; metal complexes of phosphorus ligands; biological phosphorus systems; mechanism elucidation in phosphorus chemistry; analytical and interpretive aspects; and NMR with solid phosphorus-containing systems. Annotation copyright by Book News, Inc., Portland, OR
| Author | : John C. Tebby |
| Publisher | : CRC Press |
| Total Pages | : 1140 |
| Release | : 2017-11-22 |
| Genre | : Science |
| ISBN | : 1351362038 |
To fully utilize Nuclear Magnetic Resonance (NMR) spectroscopy, a comprehensive and well-organized compilation of NMR data is necessary. While compilations have been available for other important NMR nuclei, such as carbon and fluorine, no comprehensive collection of data has been prepared for phosphorus-until now. The CRC Handbook of Phosphorus-31 Nuclear Magnetic Resonance Data provides a collection of 31P NMR chemical shifts for nearly 20,000 organic and inorganic phosphorus compounds. Each class of phosphorus compound is discussed. Bond types, stereochemistry (with the exception of metal complexes), media, important coupling constants, and data sources are included. The information is systematically organized according to coordination state, the atoms bound to phosphorus, and their connectivities. A comprehensive series of bar charts is also included to allow structure types to be assigned to chemical shift data. This handbook is an invaluable resource for all scientists working with phosphorus compounds, including chemists, biochemists, medical researchers, and pharmaceutical chemists.
| Author | : Viktor Iaroshenko |
| Publisher | : John Wiley & Sons |
| Total Pages | : 586 |
| Release | : 2019-04-22 |
| Genre | : Science |
| ISBN | : 3527335722 |
Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.
| Author | : Olaf Kühl |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 138 |
| Release | : 2008-08-22 |
| Genre | : Science |
| ISBN | : 3540791183 |
Nuclear Magnetic Resonance is a powerful tool, especially for the identification of 1 13 hitherto unknown organic compounds. H- and C-NMR spectroscopy is known and applied by virtually every synthetically working Organic Chemist. Con- quently, the factors governing the differences in chemical shift values, based on chemical environment, bonding, temperature, solvent, pH, etc. , are well understood, and specialty methods developed for almost every conceivable structural challenge. Proton and carbon NMR spectroscopy is part of most bachelors degree courses, with advanced methods integrated into masters degree and other graduate courses. In view of this universal knowledge about proton and carbon NMR spectr- copy within the chemical community, it is remarkable that heteronuclear NMR is still looked upon as something of a curiosity. Admittedly, most organic compounds contain only nitrogen, oxygen, and sulfur atoms, as well as the obligatory hydrogen and carbon atoms, elements that have an unfavourable isotope distribution when it comes to NMR spectroscopy. Each of these three elements has a dominant isotope: 14 16 32 16 32 N (99. 63% natural abundance), O (99. 76%), and S (95. 02%), with O, S, and 34 14 S (4. 21%) NMR silent. N has a nuclear moment I = 1 and a sizeable quadrupolar moment that makes the NMR signals usually very broad and dif cult to analyse.
| Author | : Daniel L. Purich |
| Publisher | : Elsevier |
| Total Pages | : 811 |
| Release | : 1999-10-26 |
| Genre | : Science |
| ISBN | : 0080521932 |
Biochemical kinetics refers to the rate at which a reaction takes place. Kinetic mechanisms have played a major role in defining the metabolic pathways, the mechanistic action of enzymes, and even the processing of genetic material. The Handbook of Biochemical Kinetics provides the "underlying scaffolding" of logic for kinetic approaches to distinguish rival models or mechanisms. The handbook also comments on techniques and their likely limitations and pitfalls, as well as derivations of fundamental rate equations that characterize biochemical processes. Key Features* Over 750 pages devoted to theory and techniques for studying enzymic and metabolic processes* Over 1,500 definitions of kinetic and mechanistic terminology, with key references* Practical advice on experimental design of kinetic experiments* Extended step-by-step methods for deriving rate equations* Over 1,000 enzymes, complete with EC numbers, reactions catalyzed, and references to reviews and/or assay methods* Over 5,000 selected references to kinetic methods appearing in the Methods in Enzymology series* 72-page Wordfinder that allows the reader to search by keywords* Summaries of mechanistic studies on key enzymes and protein systems* Over 250 diagrams, figures, tables, and structures
| Author | : |
| Publisher | : Academic Press |
| Total Pages | : 3716 |
| Release | : 2016-09-22 |
| Genre | : Science |
| ISBN | : 0128032251 |
This third edition of the Encyclopedia of Spectroscopy and Spectrometry, Three Volume Set provides authoritative and comprehensive coverage of all aspects of spectroscopy and closely related subjects that use the same fundamental principles, including mass spectrometry, imaging techniques and applications. It includes the history, theoretical background, details of instrumentation and technology, and current applications of the key areas of spectroscopy. The new edition will include over 80 new articles across the field. These will complement those from the previous edition, which have been brought up-to-date to reflect the latest trends in the field. Coverage in the third edition includes: Atomic spectroscopy Electronic spectroscopy Fundamentals in spectroscopy High-Energy spectroscopy Magnetic resonance Mass spectrometry Spatially-resolved spectroscopic analysis Vibrational, rotational and Raman spectroscopies The new edition is aimed at professional scientists seeking to familiarize themselves with particular topics quickly and easily. This major reference work continues to be clear and accessible and focus on the fundamental principles, techniques and applications of spectroscopy and spectrometry. Incorporates more than 150 color figures, 5,000 references, and 300 articles for a thorough examination of the field Highlights new research and promotes innovation in applied areas ranging from food science and forensics to biomedicine and health Presents a one-stop resource for quick access to answers and an in-depth examination of topics in the spectroscopy and spectrometry arenas
| Author | : John G. Verkade |
| Publisher | : Wiley-VCH |
| Total Pages | : 746 |
| Release | : 1987 |
| Genre | : Science |
| ISBN | : |
| Author | : Terence N. Mitchell |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 216 |
| Release | : 2007-08-01 |
| Genre | : Science |
| ISBN | : 3540721959 |
This practice-oriented textbook shows how to utilize the huge variety of NMR experiments available today in addition to standard experiments. Intended as a practical guide for students and laboratory personnel, it treats theoretical aspects only to the extent necessary to understand the experiments and to interpret the results. The book is significantly revised and expanded for the 2nd edition, and now includes the nuclei 1H/2H, 13C, 31P, 17O, 15N, 19F, 29Si, 77Se, 113Cd, 117Sn/119Sn, 195Pt, 207Pb and a new chapter on solid state NMR. An expanded set of 50 graded problems offers invaluable help for students, practitioners and laboratory personnel alike.
