Novel Nanophosphors For High Efficiency Fluorescent Lamps PDF Download

This is the Final Report of the Novel Nanophosphors for High Efficiency Fluorescent Lamps, Department of Energy (DOE). The overall goal of this three-year program is to develop novel hybrid phosphors by coating commercially available lamp phosphors with highly stable wide band-gap nanocrystalline phosphors (NCP). The prime technical approach is the development of NCP quantum-splitting phosphor (QSP) and ultra-violet (UV) emitting phosphors with quantum efficiencies exceeding that of the conventional phosphors at 185 nm. The novel hybrid phosphors will increase the efficiency of the fluorescent lamps by up to 32%, enabling total energy savings of 0.26 quads, the reduction in the U.S. energy bill by $6.5 billion and the reduction of the annual carbon emission by 4.1 billion kilogram. Our work started by investigating through modeling calculations the requirement for the particle size of the NCP. Our work to develop suitable nanocrystalline phosphors started with the known oxide quantum splitting and UV emitting phosphors. We demonstrated several synthesis techniques for the production of high quality nanocrystalline materials that crystallizes in the desired phase and with the desired particle size. In collaboration with our subcontractor we demonstrated the feasibility for the manufacture of NC phosphors. We also demonstrated novel techniques of coating the NCP on the surface of micron sized phosphors. Our chief achievement pertains to the successful testing of the coated hybrid phosphor systems in linear fluorescent lamps. In linear fluorescent lamp tests, we have demonstrated up to 7% increase in the efficacy of hybrid phosphors over the conventional (uncoated) phosphors. We have also demonstrated the improvement in the lumen maintenance of the coated phosphors. A hybrid phosphor system based on the commercial red emitting phosphor, Y2O3:Eu{sup 3+} did not show the anticipated improvement in lamp efficacy. We explored the reasons for this observation, which are detailed in this report. Within the program we have carried out fundamental investigations into the physical processes that determine the quantum splitting behavior of the Pr{sup 3+} ion in solids. Specifically, we have investigated the quantum splitting luminescence of this ion in the LaPO4, SrAl12O19 and LiLaP4O12 host lattices. In this final report we summarize the technical work completed under the Program, summarize our findings about the performance limits of the various technologies we investigated, and outline promising paths for future work.