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Molecular Chemistry of the Transition Elements

Molecular Chemistry of the Transition Elements
Author: François Mathey
Publisher:
Total Pages: 256
Release: 1996-11-21
Genre: Science
ISBN:

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Using a systematic and theoretical approach, this outstanding textbook offers a succinct introduction to the underlying principles of organometallic chemistry--with a strong emphasis on reactions mechanisms. It links theory with the chemical properties of the compounds, enabling students to classify the variety of compounds and to understand the basic reaction mechanisms of diverse classes of compounds. Chapters with selected applications help students to transfer the theoretical knowledge to real life chemistry. Contains numerous examples.


The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals
Author: Robert H. Crabtree
Publisher: John Wiley & Sons
Total Pages: 600
Release: 2005-06-14
Genre: Science
ISBN: 0471718750

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Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.


Chemistry Of Transition Elements

Chemistry Of Transition Elements
Author: M. Satake & Y. Mido
Publisher: Discovery Publishing House
Total Pages: 230
Release: 2010
Genre:
ISBN: 9788171412433

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Contents: The Properties of Transition Elements, Titanium, Zirconium and Hafnium Group IV A, Vanadium, Niobium and Tantalum Group V A, Chromium, Molybdenum and Tungsten Group VI A, Manganese, Technetium and Rhenium Group VII A, Iron, Cobalt and Nickel, The Platinum Metals, Copper, Silver and Gold Group IB, Analytical and Biological Aspects of Transition Metals, Coordination Compounds, Lanthanides & Actinides.


Transition Metals in Supramolecular Chemistry

Transition Metals in Supramolecular Chemistry
Author: L. Fabbrizzi
Publisher: Springer Science & Business Media
Total Pages: 445
Release: 2013-03-09
Genre: Science
ISBN: 9401583803

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Since the pioneering publications on coordination chemistry by Lehn and Pedersen in the late 1960s, coupled with the more orthodox interest from the transition metal chemists on template reactions (Busch, 1964), the field of supramolecular chemistry has grown at an astonishing rate. The use of transition metals as essential constituents of multi-component assemblies has been especially sharp in recent years, since the metals are prone to quick and reversible redox changes, and there is a wide variety of metal--ligand interactions. Such properties make supramolecular complexes of transition metal ions suitable candidates for exploration as light--energy converters and signal processors. Transition Metals in Supramolecular Chemistry focuses on the following main topics: (1) metal controlled organization of novel molecular assemblies and shapes; (2) design of molecular switches and devices operating through metal centres; (3) supramolecular catalysts that mimic metalloenzymes; (4) metal-containing sensory reagents and supramolecular recognition; and (5) molecular materials that display powerful electronic, optoelectronic and magnetic properties.


Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules
Author: Louis S. Hegedus
Publisher: University Science Books
Total Pages: 358
Release: 1999
Genre: Science
ISBN: 9781891389047

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This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.


Organometallic Chemistry of the Transition Elements

Organometallic Chemistry of the Transition Elements
Author: Florian P. Pruchnik
Publisher: Springer Science & Business Media
Total Pages: 767
Release: 2013-06-29
Genre: Science
ISBN: 1489920765

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Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.


Transition Metal Compounds

Transition Metal Compounds
Author: Daniel Khomskii
Publisher: Cambridge University Press
Total Pages: 501
Release: 2014-10-23
Genre: Science
ISBN: 1107020174

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This book describes all aspects of the physics of transition metal compounds, providing a comprehensive overview of this diverse class of solids. Set within a modern conceptual framework, this is an invaluable, up-to-date resource for graduate students, researchers and industrial practitioners in solid-state physics and chemistry, materials science, and inorganic chemistry.


Molecular Orbitals of Transition Metal Complexes

Molecular Orbitals of Transition Metal Complexes
Author: Yves Jean
Publisher: Oxford University Press on Demand
Total Pages: 288
Release: 2005-03-24
Genre: Science
ISBN: 0198530935

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This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.


Transition Metal Organometallic Chemistry

Transition Metal Organometallic Chemistry
Author: Francois Mathey
Publisher: Springer
Total Pages: 0
Release: 2013-05-04
Genre: Science
ISBN: 9789814451086

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This book serves as a concise guide to essential topics in Transition Metal Organometallic Chemistry for senior undergraduate and graduate students; it blends qualitative theoretical approach with experimental description of the facts. Its content emphasizes on the orbital description of M-L bonds; the electronic structures of the main types of organometallic complexes (ML2 to ML6); main types of organometallic reactions; organometallic compound synthesis, analytical characterization and the reactivity and lastly the applications of transition metals in homogeneous catalysis.


Cluster Chemistry

Cluster Chemistry
Author: Guillermo Gonzalez-Moraga
Publisher: Springer Science & Business Media
Total Pages: 310
Release: 2013-11-09
Genre: Science
ISBN: 3642859267

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Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.