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Modern Aspects of Electrochemistry 45

Modern Aspects of Electrochemistry 45
Author: Ralph E. White
Publisher: Springer Science & Business Media
Total Pages: 351
Release: 2009-08-12
Genre: Science
ISBN: 144190655X

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This volume maintains the series’ high standards, containing chapters covering topics such as the cathodic reduction of nitrate, and including discussion of product selectivity, current efficiency, and the thermodynamics and kinetics for the reactions studied.


Modern Aspects of Electrochemistry 42

Modern Aspects of Electrochemistry 42
Author: Constantinos G. Vayenas
Publisher: Springer Science & Business Media
Total Pages: 434
Release: 2008-03-08
Genre: Science
ISBN: 0387494898

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This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.


Modern Aspects of Electrochemistry

Modern Aspects of Electrochemistry
Author: John O'M. Bockris
Publisher: Springer Science & Business Media
Total Pages: 498
Release: 2012-12-06
Genre: Science
ISBN: 1461303273

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No. 29 offers new insights into the energies of activation of electrode reactions and the interfacial behavior of proteins.


Modern Aspects of Electrochemistry

Modern Aspects of Electrochemistry
Author: J. O'M Bockris
Publisher:
Total Pages: 328
Release: 2014-09-01
Genre:
ISBN: 9781468409147

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Modern Aspects of Electrochemistry

Modern Aspects of Electrochemistry
Author: B. E. Conway
Publisher: Springer Science & Business Media
Total Pages: 497
Release: 2012-12-06
Genre: Science
ISBN: 1461574439

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As the subject of electrochemistry moves into the final quarter of the century, a number of developed areas can be assessed in depth while some new areas provide quantitatively and qualitatively novel data and results. The first chapter, by Kebarle, deals with an example of the latter type of field in which new information of the energetics and equilibria of reactions between ions and solvent molecules is studied in the gas phase and provides interesting basic information for treatments of ions in solution, i.e., ionic solvation. Chapter 2, by Hamann, discusses the behavior of electrolyte solutions under high pressures, a matter of intrinsic interest in relation to ion-solvent interaction and the structural aspects of the properties of ionic solutions, especially in water. This topic is also of current interest with regard to the physical chemistry of the marine environment, especially at great depths. In the article by Bloom and Snook (Chapter 3), models for treatments of molten salt systems are examined quantitatively in relation to the structure of molten ionic liquids and to the statistical mechanical approaches that can be meaningfully made to interpret their properties and electrochemical behavior.


Modern Aspects of Electrochemistry 41

Modern Aspects of Electrochemistry 41
Author: Constantinos G. Vayenas
Publisher: Springer Science & Business Media
Total Pages: 308
Release: 2007-05-06
Genre: Science
ISBN: 0387461086

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Volume 41 of the prominent series Modern Aspects of Electrochemistry covers a range of topics in Electrochemistry and Electrochemical Engineering. The topics include the second chapter on the survey of experimental techniques and devices of solid state electrochemistry begun by Professor Joachim Maier in Volume 39. Chapter two contains a review of synthesis and characterization of nanoporous carbons and their electrochemical applications. The next chapter reviews and discusses the use of graphs in the study of chemical reaction network. The book also reviews and discusses mathematical models of three dimensional electrode structures.


Modern Aspects of Electrochemistry No. 20

Modern Aspects of Electrochemistry No. 20
Author: John O'M. Bockris
Publisher: Springer Science & Business Media
Total Pages: 528
Release: 2013-11-11
Genre: Science
ISBN: 1468487620

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Starts with the most fundamental aspects of the subject and work to the more complex. Topics treated include the electron overlap contribution to the double layer potential difference; the electron transfer theory; farzdaic rectification; photoelectrochemical reduction of CO 2; aluminum in aqueous s


Modern Aspects of Electrochemistry

Modern Aspects of Electrochemistry
Author: J. O'M. Bockris
Publisher: Springer Science & Business Media
Total Pages: 335
Release: 2012-12-06
Genre: Science
ISBN: 1461574528

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The first chapter in the present volume takes up a well-known theme in modern context: the ideas concerning non-Stokesian mechanisms of ion transport. We are happy that one of the great pioneers of modern electrochemistry, T. Erdey-Gniz, in collaboration with S. Lengyel, has consented to write this article for us. Along with it is a solution-oriented article in spectroscopic vein, namely, that by A. Covington and K. E. Newman on the analysis of solution constituents by means of nuclear magnetic resonance studies. Progress in the electrochemistry of the double layer has perked up, and the advances have been triggered from critical experiments, one showing that fluoride ions are specifically adsorbed, and the other showing that the position of maximum disorder of the water molecules occurs at a charge opposite to that needed for interpreta tions of capacitance humps in terms of water molecules. M. A. Habib, who has contributed to the theory in this area, reviews the con sequences of these changes in information. The rise in the price of energy toward a situation in which sources other than the fossil fuels become economical implies much for the fuel cell and electrocatalysis. It has long been known that electrocatalysis in real situations was more than a consideration of exchange current densities, and a gap remains in the formulation of the theory of supports for such catalysts, although Boudart has stressed so much the vital nature of them. P. Stonehart and K. A. Kinoshita describe progress in this area.


Modern Aspects of Electrochemistry

Modern Aspects of Electrochemistry
Author: Brian E. Conway
Publisher: Springer Science & Business Media
Total Pages: 376
Release: 2013-11-09
Genre: Science
ISBN: 1461317916

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This volume of Modern Aspects of Electrochemistry contains six chapters. The first four chapters are about phenomena of interest at the microscopic level and the last two are on phenomena at the macroscopic level. In the first chapter, Uosaki and Kita review various theoretical models that have been presented to describe the phenomena that occur at an electrolyte/ semiconductor interface under illumination. In the second chapter, Orazem and Newman discuss the same phenomena from a different point of view. In Chapter 3, Bogus lavsky presents state-of-the-art considerations of transmembrane potentials and other aspects of active transport in biological systems. Next, Burke and Lyons present a survey of both the theoretical and the experimental work that has been done on hydrous oxide films on several metals. The last two chapters cover the topics of the production of chlorine and caustic and the phenomena of electrolytic gas evol ution. In Chapter 5, Hine et al. describe the engineering aspects of the three processes used in the chi or-alkali industry, and in Chapter 6, Sides reviews the macroscopic phenomena of nucleation, growth, and detachment of bubbles, and the effect of bubbles on the conduc tivity of and mass transfer in electrolytes.