Micromechanical Modeling Of Interphase And Interface Effects In Polymer Nanocomposites Via An Augmented Mori Tanaka Approach PDF Download

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Interface / Interphase in Polymer Nanocomposites

Interface / Interphase in Polymer Nanocomposites
Author: Anil N. Netravali
Publisher: John Wiley & Sons
Total Pages: 448
Release: 2016-11-29
Genre: Technology & Engineering
ISBN: 1119185181

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Significant research has been done in polymeric nanocomposites and progress has been made in understanding nanofiller-polymer interface and interphase and their relation to nanocomposite properties. However, the information is scattered in many different publication media. This is the first book that consolidates the current knowledge on understanding, characterization and tailoring interfacial interactions between nanofillers and polymers by bringing together leading researchers and experts in this field to present their cutting edge research. Eleven chapters authored by senior subject specialists cover topics including: Thermodynamic mechanisms governing nanofiller dispersion, engineering of interphase with nanofillers Role of interphase in governing the mechanical, electrical, thermal and other functional properties of nanocomposites, characterization and modelling of the interphase Effects of crystallization on the interface, chemical and physical techniques for surface modification of nanocellulose reinforcements Electro-micromechanical and nanoindentation techniques for interface evaluation, molecular dynamics (MD) simulations to quantify filler-matrix adhesion and nanocomposite mechanical properties.


Mechanics of Particle- and Fiber-Reinforced Polymer Nanocomposites

Mechanics of Particle- and Fiber-Reinforced Polymer Nanocomposites
Author: Sumit Sharma
Publisher: John Wiley & Sons
Total Pages: 320
Release: 2021-02-22
Genre: Technology & Engineering
ISBN: 1119653630

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Learn to model your own problems for predicting the properties of polymer-based composites Mechanics of Particle- and Fiber-Reinforced Polymer Nanocomposites: Nanoscale to Continuum Simulations provides readers with a thorough and up-to-date overview of nano, micro, and continuum approaches for the multiscale modeling of polymer-based composites. Covering nanocomposite development, theoretical models, and common simulation methods, the text includes a variety of case studies and scripting tutorials that enable readers to apply and further develop the supplied simulations. The book describes the foundations of molecular dynamics and continuum mechanics methods, guides readers through the basic steps required for multiscale modeling of any material, and correlates the results between the experimental and theoretical work performed. Focused primarily on nanocomposites, the methods covered in the book are applicable to various other materials such as carbon nanotubes, polymers, metals, and ceramics. Throughout the book, readers are introduced to key topics of relevance to nanocomposite materials and structures—supported by journal articles that discuss recent developments in modeling techniques and in the prediction of mechanical and thermal properties. This timely, highly practical resource: Explains the molecular dynamics (MD) simulation procedure for nanofiber and nanoparticle reinforced polymer composites Compares results of experimental and theoretical results from mechanical models at different length scales Covers different types of fibers and matrix materials that constitute composite materials, including glass, boron, carbon, and Kevlar Reviews models that predict the stiffness of short-fiber composites, including the self-consistent model for finite-length fibers, bounding models, and the Halpin-Tsai equation Describes various molecular modeling methods such as Monte Carlo, Brownian dynamics, dissipative particle dynamics, and lattice Boltzmann methods Highlights the potential of nanocomposites for defense and space applications Perfect for materials scientists, materials engineers, polymer scientists, and mechanical engineers, Mechanics of Particle- and Fiber-Reinforced Polymer Nanocomposites is also a must-have reference for computer simulation scientists seeking to improve their understanding of reinforced polymer nanocomposites.


Micromechanically Based Multiscale Material Modeling of Polymer Nanocomposites

Micromechanically Based Multiscale Material Modeling of Polymer Nanocomposites
Author: Jaesang Yu
Publisher:
Total Pages:
Release: 2011
Genre: Micromechanics
ISBN:

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The Effective Continuum Micromechanics Analysis Code (EC-MAC) was developed for predicting effective properties of composites containing multiple distinct nanoheterogeneities (fibers, spheres, platelets, voids, etc.) each with an arbitrary number of coating layers based upon either the modified Mori-Tanaka method (MTM) and self consistent method (SCM). This code was used to investigate the effect of carbon nanofiber morphology (i.e., hollow versus solid cross-section), nanofiber waviness, and both nanofiber-resin interphase properties and dimensions on bulk nanocomposite elastic moduli. For a given nanofiber axial force-displacement relationship, the elastic modulus for hollow nanofibers can significantly exceed that for solid nanofibers resulting in notable differences in bulk nanocomposite properties. The development of a nanofiber-resin interphase had a notable effect on the bulk elastic moduli. Consistent with results from the literature, small degrees of nanofiber waviness resulted in a significant decrease in effective composite properties. Key aspects of nanofiber morphology were characterized using transmission electron microscopy (TEM) images for VGCNF/vinyl ester (VE) nanocomposites. Three-parameter Weibull probability density functions were generated to describe the statistical variation in nanofiber outer diameters, wall thicknesses, relative wall thicknesses, visible aspect ratios, and visible waviness ratios. Such information could be used to establish more realistic nanofiber moduli and strengths obtained from nanofiber tensile tests, as well as to develop physically motivated computational models for predicting nanocomposite behavior. This study represents one of the first attempts to characterize the distribution of VGCNF features in real thermoset nanocomposites. In addition, the influence of realistic nanoreinforcement geometries, distinct elastic properties, and orientations on the effective elastic moduli was addressed. The effect of multiple distinct heterogeneities, including voids, on the effective elastic moduli was investigated. For the composites containing randomly oriented wavy vapor grown carbon nanofibers (VGCNFs) and voids, the predicted moduli captured the essential character of the experimental data, where the volume fraction of voids was approximated as a nonlinear function of the volume fraction of reinforcements. This study should facilitate the development of multiscale materials design by providing insight into the relationships between nanomaterial morphology and properties across multiple spatial scales that lead to improved macroscale performance.


Multi-fidelity Modeling of Interfacial Micromechanics for Off-Aligned Polymer/Carbon Nanotube Nanocomposites

Multi-fidelity Modeling of Interfacial Micromechanics for Off-Aligned Polymer/Carbon Nanotube Nanocomposites
Author: Reed Kopp
Publisher:
Total Pages:
Release: 2016
Genre:
ISBN:

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Recent initiatives to stimulate development of next-generation rotorcraft featuring leap-ahead improvements in speed, payload, range, and durability, such as Clean Sky and Future Vertical Lift, have revitalized research efforts directed toward advanced, unconventional designs that emphasize lower operations and sustainment costs. Accordingly, soft-inplane damperless bearingless and hingeless rotor concepts have garnered significant interest. However, soft-inplane designs are susceptible to aeromechanical instabilities, such as air and ground resonance, which can potentially induce catastrophic blade vibrations without sufficient blade damping. To ensure stability, current composite blades typically require auxiliary damping sources that incur weight, volume, complexity, and maintenance penalties. Alternatively, one promising approach for achieving new lightweight, low vibration rotorcraft structures is passive damping engineered intrinsically into a structure via polymeric nanocomposites.In this study, a multi-fidelity modeling effort is employed to investigate the interfacial load transfer micromechanics, including strain energy storage and dissipation, of an off-aligned discontinuously-reinforced polymer/carbon nanotube nanocomposite. The effects of off-alignment angle on nanocomposite mechanical properties is of primary interest. The methodology in this study is separated into two independent modeling tracks: a simplified analytical micromechanics model and a high-fidelity 3D finite element model. Both model types explore transverse fixed and transverse free boundary conditions applied to the representative volume element, which correspond to applied strain and applied stress external loading conditions, respectively. Each model accounts for interfacial shear stress variations along the azimuthal direction of the nano-inclusion surface that are a result of nonzero and non-right alignment angles with respect to the applied loading. The analytical micromechanics models examine non-embedded fiber conditions, for which matrix end material effects are neglected, in the preslip and postslip regimes and embedded fiber conditions, for which matrix end material effects are included, in the preslip regime. The non-embedded micromechanics model is based on principles from an extended Cox model for discontinuous fiber reinforcement and generalized shear lag analysis for off-aligned discontinuous fibers; furthermore, the energy dissipation, which is based on principles of a simple amplitude-dependent friction damper, is assumed to be caused only by interfacial slip friction between constituents and is functionally dependent on the interfacial shear force acting over slipped portions of the matrix/nano-inclusion interface. In order to isolate the effects of azimuthal interfacial shear stress variation, a comparison of the current non-embedded model with an alternative non-embedded analytical model that employs an interfacial shear magnitude approach is performed. The embedded analytical micromechanics model is based on principles from a modified Cox model that extends the non-embedded approach to account for finite matrix end material and nonzero fiber end normal stress. The finite element model is implemented in the preslip regime for an embedded fiber with limited off-alignment angle range.The material properties employed by each model reflect those of a realistic multi-walled carbon nanotube/poly-ether-ether-ketone nanocomposite architecture. In the preslip regime, the FEM and analytical model predictions for interfacial shear and nano-inclusion normal stress distributions generally display good agreement, which is improved by including inclusion end stress effects in the analytical models. For the transverse fixed boundary condition, the non-embedded analytical model predicts reduced interfacial slip damping capacity as off-alignment increases, with initiation of slip becoming impossible at relatively high off-alignment angles. However, for the transverse free boundary condition, the non-embedded analytical model predicts that zero interfacial slip damping occurs comparatively at more moderate off-alignment angles, with nonzero damping occurring at both lower and higher off-alignment angles. The phenomena of extrema in interfacial slip damping with respect to alignment angle is due to the relative strain behavior between nanocomposite constituents caused by elastic stiffness mismatch. The alternative azimuthal magnitude non-embedded analytical model generally underpredicts storage modulus and greatly overpredicts loss modulus (for nonzero and non-right off-alignments) compared with the corresponding properties predicted by the current non-embedded analytical model because the alternative azimuthal magnitude approach assumes a greater interfacial slip surface area for a given off-alignment angle and strain magnitude compared to the current approach. Overall, the results demonstrate that nano-inclusion alignment angle substantially affects nanocomposite stiffness and interfacial damping and that azimuthal variation of the interfacial shear is a critical feature of nanocomposite mechanics. The outcome of this multi-fidelity modeling study is an array of qualified nanocomposite mechanical property prediction methods spanning a wide range of practical off-alignment angles, applied dynamic strain amplitudes and static strain magnitudes, loading and fiber embedment conditions, and nano-inclusion geometries and concentrations.


Nano- and Micro-mechanics of Polymer Blends and Composites

Nano- and Micro-mechanics of Polymer Blends and Composites
Author: József Karger-Kocsis
Publisher: Hanser Gardner Publications
Total Pages: 604
Release: 2009
Genre: Science
ISBN: 9781569904350

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The aim of this book is to give a state-of-art overview on aspects of micro- and nanomechanics of polymers, polymeric blends and composites. Major issues tackled are the followings: experimental techniques to study the mechanical performance of polymer systems especially in respect with molecular, supermolecular and filler architectures on suitable model materials; prediction methods of the mechanical performance (short and long term properties); modeling tools and approaches. All these aspects will be highlighted on polymeric systems of both academic and practical relevance. The outcome should be a reference book keeping its actuality for, at least, the next decade.


Nano- and Micro-mechanics of Polymer Blends and Composites

Nano- and Micro-mechanics of Polymer Blends and Composites
Author: József Karger-Kocsis
Publisher: Hanser Verlag
Total Pages: 604
Release: 2009
Genre: Micromechanics
ISBN: 9783446413238

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The book gives a state-of-art overview on all aspects of micro- and nanomechanics of polymers, polymeric blends, and composites. Major issues tackled include experimental techniques to study the mechanical performance of polymer systems, especially with respect to molecular, supermolecular and filler architectures on suitable model materials; prediction methods for the mechanical performance (short and long term properties); modeling tools and approaches. All these aspects are highlighted for polymeric systems of both academic and practical relevance.


Functionalization of Graphene

Functionalization of Graphene
Author: Vasilios Georgakilas
Publisher: John Wiley & Sons
Total Pages: 507
Release: 2014-04-03
Genre: Science
ISBN: 352767277X

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All set to become the standard reference on the topic, this book covers the most important procedures for chemical functionalization, making it an indispensable resource for all chemists, physicists, materials scientists and engineers entering or already working in the field. Expert authors share their knowledge on a wide range of different functional groups, including organic functional groups, hydrogen, halogen, nanoparticles and polymers.


Sustainable Polymer Composites and Nanocomposites

Sustainable Polymer Composites and Nanocomposites
Author: Inamuddin
Publisher: Springer
Total Pages: 1424
Release: 2019-02-01
Genre: Technology & Engineering
ISBN: 3030053997

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This book presents emerging economical and environmentally friendly polymer composites that are free of the side effects observed in traditional composites. It focuses on eco-friendly composite materials using granulated cork, a by-product of the cork industry; cellulose pulp from the recycling of paper residues; hemp fibers; and a range of other environmentally friendly materials procured from various sources. The book presents the manufacturing methods, properties and characterization techniques of these eco-friendly composites. The respective chapters address classical and recent aspects of eco-friendly polymer composites and their chemistry, along with practical applications in the biomedical, pharmaceutical, automotive and other sectors. Topics addressed include the fundamentals, processing, properties, practicality, drawbacks and advantages of eco-friendly polymer composites. Featuring contributions by experts in the field with a variety of backgrounds and specialties, the book will appeal to researchers and students in the fields of materials science and environmental science. Moreover, it fills the gap between research work in the laboratory and practical applications in related industries.