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Advances in Lithium Isotope Geochemistry

Advances in Lithium Isotope Geochemistry
Author: Paul Tomascak
Publisher: Springer
Total Pages: 205
Release: 2015-12-01
Genre: Science
ISBN: 3319014307

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This work summarizes the historical progression of the field of lithium (Li) isotope studies and provides a comprehensive yet succinct overview of the research applications toward which they have been directed. In synthesizing the historical and current research, the volume also suggests prospective future directions of study. Not even a full decade has passed since the publication of a broadly inclusive summary of Li isotope research around the globe (Tomascak, 2004). In this short time, the use of this isotope system in the investigation of geo- and cosmochemical questions has increased dramatically, due, in part, to the advent of new analytical technology at the end of the last millennium. Lithium, as a light element that forms low-charge, moderate-sized ions, manifests a number of chemical properties that make its stable isotope system useful in a wide array of geo- and cosmochemical research fields.


Lithium Isotopes

Lithium Isotopes
Author: Philip A. E. Pogge von Strandmann
Publisher: Cambridge University Press
Total Pages: 51
Release: 2021-08-26
Genre: Science
ISBN: 1108997627

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Lithium isotopes are a relatively novel tracer of present and past silicate weathering processes. Given that silicate weathering is the primary long-term method by which CO2 is removed from the atmosphere, Li isotope research is going through an exciting phase. We show the weathering processes that fractionate dissolved and sedimentary Li isotope ratios, focusing on weathering intensity and clay formation. We then discuss the carbonate and silicate archive potential of past seawater δ7Li. These archives have been used to examine Li isotope changes across both short and long timescales. The former can demonstrate the rates at which the climate is stabilised from perturbations via weathering, a fundamental piece of the puzzle of the long-term carbon cycle.


Encyclopedia of Geochemistry

Encyclopedia of Geochemistry
Author: William M. White
Publisher: Springer
Total Pages: 1680
Release: 2018-07-24
Genre: Science
ISBN: 9783319393117

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The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.


Managing Critical Isotopes

Managing Critical Isotopes
Author: David C. Trimble
Publisher:
Total Pages: 31
Release: 2013-11-17
Genre:
ISBN: 9781457849619

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About 13% of our nation's electricity is produced by pressurized water reactors that rely on lithium-7, an isotope of lithium produced and exported solely by China and Russia, for their safe operation. Lithium-7 is added to the water that cools the reactor core to prevent the cooling water from becoming acidic. Without it, the cooling water's acidity would increase the rate of corrosion of pipes and other infrastructure -- possibly causing them to fail. Utilities that operate the pressurized water reactors have experienced little difficulty obtaining lithium-7, but there are risks of relying on two producers. This report reviewed the supply and domestic demand for lithium-7 and how risks are being managed. It examines (1) what is known about the supply and demand of lithium-7; (2) what federal agencies are responsible for managing supply risks; and (3) alternative options to mitigate a potential shortage. Figure. This is a print on demand report.


Compilation of Minimum and Maximum Isotope Ratios of Selected Elements in Naturally Occurring Terrestrial Materials and Reagents

Compilation of Minimum and Maximum Isotope Ratios of Selected Elements in Naturally Occurring Terrestrial Materials and Reagents
Author: Tyler B. Coplen
Publisher:
Total Pages: 114
Release: 2002
Genre: Geochemistry
ISBN:

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Documented variations in the isotopic compositions of some chemical elements are responsible for expanded uncertainties in the standard atomic weights published by the Commission on Atomic Weights and Isotopic Abundances of the International Union of Pure and Applied Chemistry. This report summarizes reported variations in the isotopic compositions of 20 elements that are due to physical and chemical fractionation processes (not due to radioactive decay) and their effects on the standard atomic weight uncertainties. For 11 of those elements (hydrogen, lithium, boron, carbon, nitrogen, oxygen, silicon, sulfur, chlorine, copper, and selenium), standard atomic weight uncertainties have been assigned values that are substantially larger than analytical uncertainties because of common isotope abundance variations in materials of natural terrestrial origin. For 2 elements (chromium and thallium), recently reported isotope abundance variations potentially are large enough to result in future expansion of their atomic weight uncertainties. For 7 elements (magnesium, calcium, iron, zinc, molybdenum, palladium, and tellurium), documented isotope-abundance variations in materials of natural terrestrial origin are too small to have a significant effect on their standard atomic weight uncertainties.


Handbook of Stable Isotope Analytical Techniques

Handbook of Stable Isotope Analytical Techniques
Author: Pier A. de Groot
Publisher: Elsevier
Total Pages: 1258
Release: 2004-10-27
Genre: Science
ISBN: 9780080533278

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(Parent with price) Volume I contains subjective reviews, specialized and novel technique descriptions by guest authors. Part 1 includes contributions on purely analytical techniques and Part 2 includes matters such as development of mass spectrometers, stability of ion sources, standards and calibration, correction procedures and experimental methods to obtain isotopic fractionation factors. Volume II will be available in 2005.


Handbook of Environmental Isotope Geochemistry

Handbook of Environmental Isotope Geochemistry
Author: Mark Baskaran
Publisher: Springer Science & Business Media
Total Pages: 944
Release: 2011-10-13
Genre: Science
ISBN: 3642106374

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Applications of radioactive and stable isotopes have revolutionized our understanding of the Earth and near-earth surface processes. The utility of the isotopes are ever-increasing and our sole focus is to bring out the applications of these isotopes as tracers and chronometers to a wider audience so that they can be used as powerful tools to solve environmental problems. New developments in this field remain mostly in peer-reviewed journal articles and hence our goal is to synthesize these findings for easy reference for students, faculty, regulators in governmental and non-governmental agencies, and environmental companies. While this volume maintains its rigor in terms of its depth of knowledge and quantitative information, it contains the breadth needed for wide variety problems and applications in the environmental sciences. This volume presents all of the newer and older applications of isotopes pertaining to the environmental problems in one place that is readily accessible to readers. This book not only has the depth and rigor that is needed for academia, but it has the breadth and case studies to illustrate the utility of the isotopes in a wide variety of environments (atmosphere, oceans, lakes, rivers and streams, terrestrial environments, and sub-surface environments) and serves a large audience, from students and researchers, regulators in federal, state and local governments, and environmental companies.


Geochemistry of Non-Traditional Stable Isotopes

Geochemistry of Non-Traditional Stable Isotopes
Author: Clark M. Johnson
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 472
Release: 2018-12-17
Genre: Science
ISBN: 1501509365

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The goal for Volume 55 of Reviews in Mineralogy and Geochemistry was to bring together a summary of the isotope geochemistry of non-traditional stable isotope systems as is known through 2003 for those elements that have been studied in some detail, and which have a variety of geochemical properties. In addition, recognizing that many of these elements are of interest to workers who are outside the traditional stable isotope fields, we felt it was important to include discussions on the broad isotopic variations that occur in the solar system, theoretical approaches to calculating isotopic fractionations, and the variety of analytical methods that are in use. We hope, therefore, that this volume proves to be useful to not only the isotope specialist, but to others who are interested in the contributions that these non-traditional stable isotopes may make toward understanding geochemical and biological cycles. The review chapters in this volume were the basis for a two-day short course on nontraditional stable isotopes held prior (May 15-16, 2004) to the spring AGU/CGU Meeting in Montreal, Canada.


Isotopes

Isotopes
Author: Rob Ellam
Publisher: Oxford University Press
Total Pages: 153
Release: 2016
Genre: Science
ISBN: 0198723628

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Isotopes are used in many areas of science and technology, including medicine, archaeology, and nuclear physics. They are central to our understanding of the Earth's past and current processes. Here, Rob Ellam explains the importance and applications of stable and radioactive isotopes.


Non-Traditional Stable Isotopes

Non-Traditional Stable Isotopes
Author: Fang-Zhen Teng
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 901
Release: 2017-03-06
Genre: Science
ISBN: 3110545632

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The development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.