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Kinetics of Silica-phase Transitions

Kinetics of Silica-phase Transitions
Author: Christopher J. Duffy
Publisher:
Total Pages: 22
Release: 1993
Genre: Phase transformations (Statistical physics)
ISBN:

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Kinetics of Silica-phase Transitions

Kinetics of Silica-phase Transitions
Author:
Publisher:
Total Pages: 23
Release: 1993
Genre:
ISBN:

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In addition to the stable silica polymorph quartz, several metastable silica phases are present in Yucca Mountain. The conversion of these phases to quartz is accompanied by volume reduction and a decrease in the aqueous silica activity, which may destabilize clinoptilolite and mordenite. The primary reaction sequence for the silica phases is from opal or glass to disordered opal-CT, followed by ordering of the opal-CT and finally by the crystallization of quartz. The ordering of opal-CT takes place in the solid state, whereas the conversion of opal-CT takes place through dissolution-reprecipitation involving the aqueous phase. It is proposed that the rate of conversion of opal-CT to quartz is controlled by diffusion of defects out of a disordered surface layer formed on the crystallizing quartz. The reaction rates are observed to be dependent on temperature, pressure, degree of supersaturation, and pH. Rate equations selected from the literature appear to be consistent with observations at Yucca Mountain.


Kinetics of Phase Transitions

Kinetics of Phase Transitions
Author: Sanjay Puri
Publisher: CRC Press
Total Pages: 356
Release: 2009-03-24
Genre: Science
ISBN: 1420008366

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Providing a comprehensive introduction with the necessary background material to make it accessible for a wide scientific audience, Kinetics of Phase Transitions discusses developments in domain-growth kinetics. This book combines pedagogical chapters from leading experts in this area and focuses on incorporating various experimentally releva


Kinetic Processes

Kinetic Processes
Author: Kenneth A. Jackson
Publisher: John Wiley & Sons
Total Pages: 424
Release: 2006-03-06
Genre: Technology & Engineering
ISBN: 3527604952

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The formation of solids is governed by kinetic processes, which are closely related to the macroscopic behaviour of the resulting materials. With the main focus on ease of understanding, the author begins with the basic processes at the atomic level to illustrate their connections to material properties. Diffusion processes during crystal growth and phase transformations are examined in detail. Since the underlying mathematics are very complex, approximation methods typically used in practice are the prime choice of approach. Apart from metals and alloys, the book places special emphasis on the growth of thin films and bulk crystals, which are the two main pillars of modern device and semiconductor technology. All the presented phenomena are tied back to the basic thermodynamic properties of the materials and to the underlying physical processes for clarity.


Kinetics of First Order Phase Transitions

Kinetics of First Order Phase Transitions
Author: Vitaly V. Slezov
Publisher: John Wiley & Sons
Total Pages: 429
Release: 2009-07-10
Genre: Science
ISBN: 9783527627776

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Filling a gap in the literature, this crucial publication on the renowned Lifshitz-Slezov-Wagner Theory of first-order phase transitions is authored by one of the scientists who gave it its name. Prof Slezov spent decades analyzing this topic and obtained a number of results that form the cornerstone of this rapidly developing branch of science. Following an analysis of unresolved problems together with proposed solutions, the book develops a theoretical description of the overall course of first-order phase transformations, starting from the nucleation state right up to the late stages of coarsening. In so doing, the author illustrates the results by way of numerical computations and experimental applications. The outline of the general results is performed for segregation processes in solutions and the results used in the analysis of a variety of different topics, such as phase formation in multi-component solutions, boiling in one- and multi-component liquids, vacancy cluster evolution in solids with and without influence of radiation, as well as phase separation in helium at low temperatures. The result is a detailed overview of the theoretical description of the whole course of nucleation-growth processes and applications for a wide audience of scientists and students.


Kinetic Phase Diagrams

Kinetic Phase Diagrams
Author: Zdeněk Chvoj
Publisher: Elsevier Publishing Company
Total Pages: 640
Release: 1991
Genre: Materials
ISBN:

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The present theoretical and experimental knowledge of the time evolution of a system during solidification, not only in equilibrium, but also in nonequilibrium conditions, is summarized in this book. Such knowledge is of fundamental importance for the determination of the constitution of materials or of the technological conditions necessary to prepare materials with a desired structure. Emphasizing the importance of kinetic phase diagrams, the authors focus the attention of the reader on the problems connected with nonequilibrium conditions, that are encountered during real phase transformations. A critical review of phenomenological and statistical theories of phase transformations and of mass and heat transport enables the reader to determine the range of applicability of concrete models for the description of the evolution of a given system. The book is supplemented with several less-known methods and results of phase characterization, including a detailed account of the Soviet school of T.A. Cherepanova which is not well known in the West. The text also covers the modern research area of glasses and their preparation.


Kinetics of Phase Transitions

Kinetics of Phase Transitions
Author: John Kevin McCoy
Publisher:
Total Pages: 217
Release: 1980
Genre: Phase transformations (Statistical physics)
ISBN:

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Phase Transitions in Solids Under High Pressure

Phase Transitions in Solids Under High Pressure
Author: Vladimir Davydovich Blank
Publisher: CRC Press
Total Pages: 455
Release: 2013-10-25
Genre: Science
ISBN: 1466594241

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The use of high-pressure techniques has become popular for studying the nature of substances and phenomena occurring in them, especially as a means of obtaining new materials (synthesis under high pressure) and processing known materials (hydroextrusion). A product of many years of research by the authors and their colleagues, Phase Transitions in Solids under High Pressure discusses the relationships of phase transformations in solids under high pressure, the mechanism of these transformations, crystal geometry, the effect of deformation, the conditions of formation, and preservation of the high-pressure phases under normal pressure. The book begins with an introduction that describes the relationship of the thermodynamics of phase transformations and the kinetics of the transformations. This is followed by a chapter explaining the equipment and mostly original procedures for investigating phase transformation in solids under high hydrostatic and quasi-hydrostatic pressures. The book covers phase transformations under high pressure in a wide temperature range in the elements carbon, silicon, germanium, titanium, zirconium, iron, gallium, and cerium as well as in titanium- and iron-based alloys and AIBVII, AIIBVI, and AIIIBV compounds. In addition, the book examines the kinetics of phase transformations in iron-based alloys in isobaric–isothermal conditions. The authors present results for phase transformations in deformation under high pressure, describe several non-trivial effects associated with phase transformations under high pressure, and analyze the kinetics and hysteresis of high-temperature and low-temperature phase transformations. They conclude by describing the role of investigations under high pressure for determining general relationships governing phase transformations in solids.


Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials, Volume 151

Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials, Volume 151
Author: Gregoire Nicolis
Publisher: John Wiley & Sons
Total Pages: 352
Release: 2012-05-22
Genre: Science
ISBN: 111816783X

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The Advances in Chemical Physics series—the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics. This volume explores: Kinetics and thermodynamics of fluctuation-induced transitions in multistable systems (G. Nicolis and C. Nicolis) Dynamical rare event simulation techniques for equilibrium and nonequilibrium systems (Titus S. van Erp) Confocal depolarized dynamic light scattering (M. Potenza, T. Sanvito, V. Degiorgio, and M. Giglio) The two-step mechanism and the solution-crystal spinodal for nucleation of crystals in solution (Peter G. Vekilov) Experimental studies of two-step nucleation during two-dimensional crystallization of colloidal particles with short-range attraction (John R. Savage, Liquan Pei, and Anthony D. Dinsmore) On the role of metastable intermediate states in the homogeneous nucleation of solids from solution (James F. Lutsko) Effects of protein size on the high-concentration/low-concentration phase transition (Patrick Grosfils) Geometric constraints in the self-assembly of mineral dendrites and platelets (John J. Kozak) What can mesoscopic level in situ observations teach us about kinetics and thermodynamics of protein crystallization? (Mike Sleutel, Dominique Maes, and Alexander Van Driessche) The ability of silica to induce biomimetic crystallization of calcium carbonate (Matthias Kellermeier, Emilio Melero-GarcÍa, Werner Kunz, and Juan Manuel GarcÍa-Ruiz)


Kinetics of Phase Transformations: Volume 205

Kinetics of Phase Transformations: Volume 205
Author: Michael O. Thompson
Publisher:
Total Pages: 500
Release: 1992-02-28
Genre: Science
ISBN:

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The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.