Kinetics Of Ligand Substitution For Platinumii Complexes PDF Download
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Author | : Clifford Bruce Colvin |
Publisher | : |
Total Pages | : 212 |
Release | : 1962 |
Genre | : Chemical kinetics |
ISBN | : |
Download Kinetics of Ligand Substitution for Platinum(II) Complexes Book in PDF, ePub and Kindle
Author | : Daniel Patrick McDonald |
Publisher | : |
Total Pages | : 230 |
Release | : 1974 |
Genre | : |
ISBN | : |
Download Kinetic Studies of the Ligand Substitution Reactions of Square Planar Platinum(II) Complexes Containing Ligands with Group IV Elements Book in PDF, ePub and Kindle
Author | : |
Publisher | : |
Total Pages | : |
Release | : 1970 |
Genre | : |
ISBN | : |
Download LIGAND SUBSTITUTION REACTIONS OF PLATINUM(II) COMPLEXES. CHLORO(DIETHYLENETRIAMINE)PLATINUM(II)-CHLORIDE EXCHANGE. Book in PDF, ePub and Kindle
Kinetics of the isotopic exchange of chloride in cholro-(diethylenetriamine)platinum(II) chloride has been studied using chlorine-36 as the tracer, employing an ion exchange quenching technique and activity determination by a liquid scintillation system. The aquation equilibrium constant was determined by means of titrations of the acidic proton on the H$sub 2$0 ligand formed according to the reaction: [Pt(dien)Cl$sup +$] + H$sub 2$0 = [Pt(dien)H$sub 2$0$sup 2+$] + Cl$sup -$; K$sub eq.$ (author).
Author | : John Ralph Paxson |
Publisher | : |
Total Pages | : 168 |
Release | : 1970 |
Genre | : Chemical kinetics |
ISBN | : |
Download Ligand Substitution Reactions of Platinum (II) Complexes Book in PDF, ePub and Kindle
Author | : George Fox Vandergrift |
Publisher | : |
Total Pages | : 204 |
Release | : 1972 |
Genre | : Chemical kinetics |
ISBN | : |
Download Ligand Substitution of Platinum(II) Complexes Book in PDF, ePub and Kindle
Author | : Richard Ward |
Publisher | : |
Total Pages | : |
Release | : 1974 |
Genre | : |
ISBN | : |
Download Studies of the Kinetics of Substitution in Platinum (II) Complexes, and Related Subjects Book in PDF, ePub and Kindle
Author | : Cooper Harold Langford |
Publisher | : |
Total Pages | : 130 |
Release | : 1966 |
Genre | : Science |
ISBN | : |
Download Ligand Substitution Processes Book in PDF, ePub and Kindle
The subject of the mechanistic study of ligand substitution reactions is currently undergoing an exciting growth. New fast-reaction techniques have removed the upper limit on rates that can be measured, and extension to less familiar central metal atoms has begun in earnest. This might seem the wrong moment for review of the field. As yet, definitive treatment is possible only for those complexes involving monodentate ligands with cobalt(III) and platinurn(II). But, because information is so extensive for these systems, it is clear that they are functioning as models from which concepts and experiments are generated for application over the fast-growing range of the subject. We believe that this is an important moment to reopen debate on fundamentals so that concepts will be most felicitously formulated to aid growth of understanding. This monograph is centrally concerned with three aspects of those fundamentals. We have attempted to develop an approach to classification of ligand substitution reactions that is adapted to what seem to have emerged as the characteristic features of these reactions and is susceptible to operational tests. (We do recognize that any such scheme of ideas is necessarily obsolescent once it is formulated since new experiments will certainly follow immediately.) We have tried to evaluate the basis for making generalizations about ligand substitution processes and to formulate tests to show whether new reactions fall within familiar patterns. Finally, we have sought to base the models of ligand substitution processes in the language of molecular-orbital theory. We believe that MO theory is most useful, because it may be used to correlate rate data on complexes with the extensive information available from spectral and magnetic studies, yet differs from crystal-field theory in providing a natural place for consideration of the bonding electrons, which must be a principal determinant of reaction processes. To keep this essay within bounds, we assume familiarity with the elements of experimental kinetics, transition-state theory, and the simple molecular-orbital theory of complexes. Introductory physical chemistry, some familiarity with the study of reaction mechanisms, and mastery of one of the qualitative treatments of MO theory as applied to transition-metal complexes should provide sufficient background. Thus, we hope that this book will be useful to students, relatively early in their careers, who wish to explore this field.
Author | : Isaac Masika Wekesa |
Publisher | : |
Total Pages | : |
Release | : 2014 |
Genre | : Ligands |
ISBN | : |
Download The Influence of Ligand Moiety on the Substitution Behaviour of Mononuclear Platinum (II) Complexes Book in PDF, ePub and Kindle
Author | : |
Publisher | : Krishna Prakashan Media |
Total Pages | : 1092 |
Release | : |
Genre | : |
ISBN | : |
Download Advanced Inorganic Chemistry: Vollume II Book in PDF, ePub and Kindle
Author | : Jeff Leigh |
Publisher | : Royal Society of Chemistry |
Total Pages | : 416 |
Release | : 2007-10-31 |
Genre | : Science |
ISBN | : 1847551483 |
Download Modern Coordination Chemistry Book in PDF, ePub and Kindle
Coordination chemistry, as we know it today, has been shaped by major figures from the past, one of whom was Joseph Chatt. Beginning with a description of Chatt's career presented by co-workers, contemporaries and students, this fascinating book then goes on to show how many of today's leading practitioners in the field, working in such diverse areas as phosphines, hydrogen complexes, transition metal complexes and nitrogen fixation, have been influenced by Chatt. The reader is then brought right up-to-date with the inclusion of some of the latest research on these topics, all of which serves to underline Chatt's continuing legacy. Intended as a permanent record of Chatt's life, work and influence, this book will be of interest to lecturers, graduate students, researchers and science historians.