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Analytical Methods for Biomass Characterization and Conversion

Analytical Methods for Biomass Characterization and Conversion
Author: David C. Dayton
Publisher: Elsevier
Total Pages: 260
Release: 2019-11-05
Genre: Science
ISBN: 0128156066

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Analytical Methods for Biomass Characterization and Conversion is a thorough resource for researchers, students and professors who investigate the use of biomass for fuels, chemicals and products. Advanced analytical chemistry methods and techniques can now provide detailed compositional and chemical measurements of biomass, biomass conversion process streams, intermediates and products. This volume from the Emerging Issues in Analytical Chemistry series brings together the current knowledge on each of these methods, including spectroscopic methods (Fourier Transform Infrared Spectroscopy, Near-infrared Spectroscopy, Solid State Nuclear Magnetic Resonance), pyrolysis (Gas Chromatography/Mass Spectrometry), Liquid Chromatography/High Performance Liquid Chromatography, Liquid Chromatography/Mass Spectrometry, and so on. Authors David C. Dayton and Thomas D. Foust show how these can be used for measuring biomass composition and for determining the composition of intermediates with regard to subsequent processing for biofuels, bio-chemicals and bio-based products. Covers the broad range of techniques and applications that have been developed and perfected in the last decade Highlights specific analyses required for understanding biomass conversion to select intermediates Provides references to seminal books, review articles and technical articles that go into greater depth, serving as a basis for further study


Biomass Modification, Characterization and Process Monitoring Analytics to Support Biofuel and Biomaterial Production

Biomass Modification, Characterization and Process Monitoring Analytics to Support Biofuel and Biomaterial Production
Author: Robert Henry
Publisher: Frontiers Media SA
Total Pages: 158
Release: 2016-06-09
Genre: Biotechnology
ISBN: 2889198677

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The conversion of lignocellulosic biomass into renewable fuels and other commodities has provided an appealing alternative towards supplanting global dependence on fossil fuels. The suitability of multitudes of plants for deconstruction to useful precursor molecules and products is currently being evaluated. These studies have probed a variety of phenotypic traits, including cellulose, non-cellulosic polysaccharide, lignin, and lignin monomer composition, glucose and xylose production following enzymatic hydrolysis, and an assessment of lignin-carbohydrate and lignin-lignin linkages, to name a few. These quintessential traits can provide an assessment of biomass recalcitrance, enabling researchers to devise appropriate deconstruction strategies. Plants with high polysaccharide and lower lignin contents have been shown to breakdown to monomeric sugars more readily. Not all plants contain ideal proportions of the various cell wall constituents, however. The capabilities of biotechnology can alleviate this conundrum by tailoring the chemical composition of plants to be more favorable for conversion to sugars, fuels, etc. Increases in the total biomass yield, cellulose content, or conversion efficiency through, for example, a reduction in lignin content, are pathways being evaluated to genetically improve plants for use in manufacturing biofuels and bio-based chemicals. Although plants have been previously domesticated for food and fiber production, the collection of phenotypic traits prerequisite for biofuel production may necessitate new genetic breeding schemes. Given the plethora of potential plants available for exploration, rapid analytical methods are needed to more efficiently screen through the bulk of samples to hone in on which feedstocks contain the desired chemistry for subsequent conversion to valuable, renewable commodities. The standard methods for analyzing biomass and related intermediates and finished products are laborious, potentially toxic, and/or destructive. They may also necessitate a complex data analysis, significantly increasing the experimental time and add unwanted delays in process monitoring, where delays can incur in significant costs. Advances in thermochemical and spectroscopic techniques have enabled the screening of thousands of plants for different phenotypes, such as cell-wall cellulose, non-cellulosic polysaccharide, and lignin composition, lignin monomer composition, or monomeric sugar release. Some instrumental methods have been coupled with multivariate analysis, providing elegant chemometric predictive models enabling the accelerated identification of potential feedstocks. In addition to the use of high-throughput analytical methods for the characterization of feedstocks based on phenotypic metrics, rapid instrumental techniques have been developed for the real-time monitoring of diverse processes, such as the efficacy of a specific pretreatment strategy, or the formation of end products, such as biofuels and biomaterials. Real-time process monitoring techniques are needed for all stages of the feedstocks-to-biofuels conversion process in order to maximize efficiency and lower costs by monitoring and optimizing performance. These approaches allow researchers to adjust experimental conditions during, rather than at the conclusion, of a process, thereby decreasing overhead expenses. This Frontiers Research Topic explores options for the modification of biomass composition and the conversion of these feedstocks into to biofuels or biomaterials and the related innovations in methods for the analysis of the composition of plant biomass, and advances in assessing up- and downstream processes in real-time. Finally, a review of the computational models available for techno-economic modeling and lifecycle analysis will be presented.


Handbook on Characterization of Biomass, Biowaste and Related By-products

Handbook on Characterization of Biomass, Biowaste and Related By-products
Author: Ange Nzihou
Publisher: Springer Nature
Total Pages: 1394
Release: 2020-02-17
Genre: Technology & Engineering
ISBN: 3030350207

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This book provides authoritative information, techniques and data necessary for the appropriate understanding of biomass and biowaste (understood as contaminated biomass) composition and behaviour while processed in various conditions and technologies. Numerous techniques for characterizing biomass, biowaste and by-product streams exist in literature. However, there lacks a reference book where these techniques are gathered in a single book, although such information is in increasingly high demand. This handbook provides a wealth of characterization methods, protocols, standards, databases and references relevant to various biomass, biowaste materials and by-products. It specifically addresses sampling and preconditioning methods, extraction techniques of elements and molecules, as well as biochemical, mechanical and thermal characterization methods. Furthermore, advanced and innovative methods under development are highlighted. The characterization will allow the analysis, identification and quantification of molecules and species including biomass feedstocks and related conversion products. The characterization will also provide insight into physical, mechanical and thermal properties of biomass and biowaste as well as the resulting by-products.


Pyrolysis of Biomass

Pyrolysis of Biomass
Author: Shurong Wang
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 445
Release: 2016-12-05
Genre: Technology & Engineering
ISBN: 3110386127

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With the development of societies fossil energy is no longer the only energy resource, and increasing attention had been paid to alternative energy. Biomass is considered to be one of the alternatives due to efficiency and low cost. This book presents biomass pyrolysis behavior for three main components: Cellulose, Hemicellulose and Lignin, and discusses the influence of mineral salts , zeolite catalysts and metal oxide on their pyrolysis.


Biomass Resource Demand Characterization Study

Biomass Resource Demand Characterization Study
Author:
Publisher:
Total Pages: 4
Release: 2015
Genre:
ISBN:

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Competing demands for U.S. biomass resources and resulting impacts on regional feedstock availability could have a significant impact on the ability of the biofuels industry to transition to lower cost feedstocks, such as wood, agricultural residues, and energy crops, as well as on the ability of U.S. electric utilities and consumers to meet Renewable Portfolio Standards (RPS) and transition to lower carbon-footprint sources of electricity. Promulgation of regulations that place a cost on CO2 emissions from fossil fuels will also impact this situation as biomass to power applications become increasingly cost competitive. This increased competition for biomass feedstocks could create technical and economic risks for the Government, industry, and investors, and has the potential to impede commercialization of bio-energy in the U.S. at a meaningful scale.


Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterization and Analysis

Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterization and Analysis
Author: Rafael Kandiyoti
Publisher: Elsevier
Total Pages: 365
Release: 2006-04-06
Genre: Science
ISBN: 0080463606

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The first strand involves a critical overview of the design of experimental methods used for examining the thermal behaviour of solid fuels [pyrolysis, liquefaction and gasification], while the second will emphasise chemical structures and molecular mass distributions of coal derived tars, extracts and pitches, petroleum-derived asphaltenes, and biomass derived heavy hydrocarbon liquids.Two major, interdependent strands in the study of fossil and renewable fuel utilisation are focused on within this text:(i) Thermal characterisation of solid fuels including various ranks of coals, biomass and waste, and, (ii) The analytical characterisation of heavy hydrocarbon liquids, covering coal, petroleum and biomass derived heavy fractions. Two major, interdependent strands in the study of fossil and renewable fuel utilisation are focused on within this text: (i) Thermal characterisation of solid fuels including various ranks of coals, biomass and waste, and, (ii) The analytical characterisation of heavy hydrocarbon liquids, covering coal, petroleum and biomass derived heavy fractions.