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Interface properties of amorphous/crystalline silicon heterojunctions

Interface properties of amorphous/crystalline silicon heterojunctions
Author: Sara Olibet
Publisher: Sudwestdeutscher Verlag Fur Hochschulschriften AG
Total Pages: 252
Release: 2009-09
Genre:
ISBN: 9783838109718

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Solar cells based on monocrystalline silicon (c-Si) can potentially achieve high sunlight energy conversion efficiencies and thus could reach grid parity despite the high cost of c-Si. The efficiency of standard c-Si solar cells featuring diffused emitters and aluminum back surface fields (BSF) is limited by interface recombination. Alternatively the growth of intrinsic/doped amorphous silicon (a- Si: H) layer stacks on c-Si effectively passivates the c-Si surface and simultaneously forms the emitter and BSF. Such Si heterojunction (HJ) solar cells can use thin c-Si wafers, benefit from low production cost of a-Si: H layers and enable the highest efficiencies. The focus of this work is the study of interfaces in a-Si: H/c-Si heterostructures, particularly the electronic quality of the a-Si: H/c-Si heterointerface and its effect on the subsequent a- Si: H/c-Si HJ solar cell fabrication. Interface recombination modeling by considering the amphoteric nature of Si dangling bonds is in excellent agreement with measurements, and provides insight into the microscopic passivation mechan


Physics and Technology of Amorphous-Crystalline Heterostructure Silicon Solar Cells

Physics and Technology of Amorphous-Crystalline Heterostructure Silicon Solar Cells
Author: Wilfried G. J. H. M. van Sark
Publisher: Springer Science & Business Media
Total Pages: 588
Release: 2011-11-16
Genre: Technology & Engineering
ISBN: 3642222757

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Today’s solar cell multi-GW market is dominated by crystalline silicon (c-Si) wafer technology, however new cell concepts are entering the market. One very promising solar cell design to answer these needs is the silicon hetero-junction solar cell, of which the emitter and back surface field are basically produced by a low temperature growth of ultra-thin layers of amorphous silicon. In this design, amorphous silicon (a-Si:H) constitutes both „emitter“ and „base-contact/back surface field“ on both sides of a thin crystalline silicon wafer-base (c-Si) where the electrons and holes are photogenerated; at the same time, a-Si:H passivates the c-Si surface. Recently, cell efficiencies above 23% have been demonstrated for such solar cells. In this book, the editors present an overview of the state-of-the-art in physics and technology of amorphous-crystalline heterostructure silicon solar cells. The heterojunction concept is introduced, processes and resulting properties of the materials used in the cell and their heterointerfaces are discussed and characterization techniques and simulation tools are presented.


Amorphous Silicon / Crystalline Silicon Heterojunction Solar Cells

Amorphous Silicon / Crystalline Silicon Heterojunction Solar Cells
Author: Wolfgang Rainer Fahrner
Publisher: Springer Science & Business Media
Total Pages: 119
Release: 2013-04-23
Genre: Technology & Engineering
ISBN: 364237039X

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Amorphous Silicon/Crystalline Silicon Solar Cells deals with some typical properties of heterojunction solar cells, such as their history, the properties and the challenges of the cells, some important measurement tools, some simulation programs and a brief survey of the state of the art, aiming to provide an initial framework in this field and serve as a ready reference for all those interested in the subject. This book helps to “fill in the blanks” on heterojunction solar cells. Readers will receive a comprehensive overview of the principles, structures, processing techniques and the current developmental states of the devices. Prof. Dr. Wolfgang R. Fahrner is a professor at the University of Hagen, Germany and Nanchang University, China.


Silicon Heterojunction Solar Cells

Silicon Heterojunction Solar Cells
Author: W.R. Fahrner
Publisher: Trans Tech Publications Ltd
Total Pages: 208
Release: 2006-08-15
Genre: Technology & Engineering
ISBN: 3038131024

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The world of today must face up to two contradictory energy problems: on the one hand, there is the sharply growing consumer demand in countries such as China and India. On the other hand, natural resources are dwindling. Moreover, many of those countries which still possess substantial gas and oil supplies are politically unstable. As a result, renewable natural energy sources have received great attention. Among these, solar-cell technology is one of the most promising candidates. However, there still remains the problem of the manufacturing costs of such cells. Many attempts have been made to reduce the production costs of “conventional” solar cells (manufactured from monocrystalline silicon using diffusion methods) by instead using cheaper grades of silicon, and simpler pn-junction fabrication. That is the ‘hero’ of this book; the heterojunction solar cell.


High-Efficiency Crystalline Silicon Solar Cells

High-Efficiency Crystalline Silicon Solar Cells
Author: Eun-Chel Cho
Publisher: MDPI
Total Pages: 90
Release: 2021-01-06
Genre: Technology & Engineering
ISBN: 3039436295

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This book is composed of 6 papers. The first paper reports a novel technique for the selective emitter formation by controlling the surface morphology of Si wafers. Selective emitter (SE) technology has attracted renewed attention in the Si solar cell industry to achieve an improved conversion efficiency of passivated-emitter rear-contact (PERC) cells. In the second paper, the temperature dependence of the parameters was compared through the PERC of the industrial-scale solar cells. As a result of their analysis, PERC cells showed different temperature dependence for the fill factor loss as temperatures rose. The third paper reports the effects of carrier selective front contact layer and defect state of hydrogenated amorphous silicon passivation layer/n-type crystalline silicon interface. The results demonstrated the effects of band offset determined by band bending at the interface of the passivation layer and carrier selective front contact layer. In addition, the nc-SiOx: H CSFC layer not only reduces parasitic absorption loss but also has a tunneling effect and field-effect passivation. The fourth paper reports excimer laser annealing of hydrogenated amorphous silicon film for TOPCon solar cell application. This paper analyzes the crystallization of a-Si:H via excimer laser annealing (ELA) and compared this process with conventional thermal annealing. The fifth paper reports the contact mechanism between Ag–Al and Si and the change in contact resistance (Rc) by varying the firing profile. Rc was measured by varying the belt speed and peak temperature of the fast-firing furnace. The sixth paper reports a silicon tandem heterojunction solar cell based on a ZnO/Cu2O subcell and a c-Si bottom subcell using electro-optical numerical modeling. The buffer layer affinity and mobility together with a low conduction band offset for the heterojunction are discussed, as well as spectral properties of the device model.


Properties of Interfaces in Amorphous

Properties of Interfaces in Amorphous
Author:
Publisher:
Total Pages:
Release:
Genre:
ISBN:

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The main focus of this work is the study of interfaces in amorphous/crystalline silicon (a-Si:H/c-Si) heterostructures, especially the investigation of the a-Si:H/c-Si heterointerface's electronic quality and its effect on the consecutive a-Si:H/c-Si heterojunction (HJ) solar cell fabrication. c-Si based solar cells have the potential for achieving high conversion efficiencies, but the standard simple fabrication processes lead to medium module efficiencies. Thin-film Si based technologies offer the prospect of low-cost fabrication but yield lower efficiencies. a-Si:H/c-Si HJ solar cells combine the advantages of both technologies, i.e., the high efficiency potential of c-Si and the low fabrication cost of a-Si:H. In this way the c-Si cost becomes reasonable because it is possible to use very thin wafers to produce highly efficient solar cells. The electronic quality of the heterostructure interface was evaluated experimentally with photogenerated carrier lifetime measurements. In this study, carrier recombination at the interface is the step limiting photogenerated carriers' lifetime. In the theoretical part of this work, c-Si surface recombination is modeled by considering for the first time the amphoteric nature of Si dangling bonds. For this, a model previously established for bulk a-Si:H recombination, is extended to the description of the c-Si surface recombination through amphoteric defects. Its differences and similarities compared to existing interface recombination models are discussed. This new model is currently the simplest that allows an understanding of the largest set of experimentally observed behaviors of passivation layers on c-Si. The potential of the model's applicability to passivation by silicon dioxide (SiOsub2/sub) and silicon nitride (SiNsubx


Heterojunction Solar Cells (a-Si/c-Si)

Heterojunction Solar Cells (a-Si/c-Si)
Author: Thomas Mueller
Publisher: Logos Verlag Berlin GmbH
Total Pages: 280
Release: 2009
Genre: Technology & Engineering
ISBN: 3832522913

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The main focus of the present work is related to the optimization of heterojunction solar cells. The key roles in obtaining high efficient heterojunction solar cells are mainly the plasma enhanced chemical vapor deposition of very low defect layers, and the sufficient surface passivation of all interfaces. In heterojunction solar cells, the a-Si: H/c-Si hetero-interface is of significant importance, since the hetero-interface characteristics directly affect the junction properties and thus solar cell efficiency. In this work, the deposition and film properties of various hydrogenated amorphous silicon alloys, such as a-SiC: H, a-SiO_x: H, and muc-Si: H (standard a-Si: H is used as reference), are employed. Special attention is paid to (i) the front and back surface passivation of the bulk material by high-quality wide-gap amorphous silicon suboxides (a-SiO_x: H), and (ii) the influence of wide-gap high-quality a-Si- and muc-Si-based alloys for use as emitter and back-surface-


Silicon Based Thin Film Solar Cells

Silicon Based Thin Film Solar Cells
Author: Roberto Murri
Publisher: Bentham Science Publishers
Total Pages: 524
Release: 2013-03-20
Genre: Technology & Engineering
ISBN: 160805456X

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Silicon Based Thin Film Solar Cells explains concepts related to technologies for silicon (Si) based photovoltaic applications. Topics in this book focus on ‘new concept’ solar cells. These kinds of cells can make photovoltaic power production an economically viable option in comparison to the bulk crystalline semiconductor technology industry. A transition from bulk crystalline Si solar cells toward thin-film technologies reduces usage of active material and introduces new concepts based on nanotechnologies. Despite its importance, the scientific development and understanding of new solar cells is not very advanced, and educational resources for specialized engineers and scientists are required. This textbook presents the fundamental scientific aspects of Si thin films growth technology, together with a clear understanding of the properties of the material and how this is employed in new generation photovoltaic solar cells. The textbook is a valuable resource for graduate students working on their theses, young researchers and all people approaching problems and fundamental aspects of advanced photovoltaic conversion.