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Ice Adhesion

Ice Adhesion
Author: Chang-Hwan Choi
Publisher: John Wiley & Sons
Total Pages: 704
Release: 2020-11-13
Genre: Technology & Engineering
ISBN: 1119640504

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This unique book presents ways to mitigate the disastrous effects of snow/ice accumulation and discusses the mechanisms of new coatings deicing technologies. The strategies currently used to combat ice accumulation problems involve chemical, mechanical or electrical approaches. These are expensive and labor intensive, and the use of chemicals raises serious environmental concerns. The availability of truly icephobic surfaces or coatings will be a big boon in preventing the devastating effects of ice accumulation. Currently, there is tremendous interest in harnessing nanotechnology in rendering surfaces icephobic or in devising icephobic surface materials and coatings, and all signals indicate that such interest will continue unabated in the future. As the key issue regarding icephobic materials or coatings is their durability, much effort is being spent in developing surface materials or coatings which can be effective over a long period. With the tremendous activity in this arena, there is strong hope that in the not too distant future, durable surface materials or coatings will come to fruition. This book contains 20 chapters by subject matter experts and is divided into three parts— Part 1: Fundamentals of Ice Formation and Characterization; Part 2: Ice Adhesion and Its Measurement; and Part 3: Methods to Mitigate Ice Adhesion. The topics covered include: factors influencing the formation, adhesion and friction of ice; ice nucleation on solid surfaces; physics of ice nucleation and growth on a surface; condensation frosting; defrosting properties of structured surfaces; relationship between surface free energy and ice adhesion to surfaces; metrology of ice adhesion; test methods for quantifying ice adhesion strength to surfaces; interlaboratory studies of ice adhesion strength; mechanisms of surface icing and deicing technologies; icephobicities of superhydrophobic surfaces; anti-icing using microstructured surfaces; icephobic surfaces: features and challenges; bio-inspired anti-icing surface materials; durability of anti-icing coatings; durability of icephobic coatings; bio-inspired icephobic coatings; protection from ice accretion on aircraft; and numerical modeling and its application to inflight icing.


Effects of Strain Rate Variation on the Shear Adhesion Strength of Impact Ice

Effects of Strain Rate Variation on the Shear Adhesion Strength of Impact Ice
Author: Rebekah Douglass
Publisher:
Total Pages:
Release: 2019
Genre:
ISBN:

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In-flight ice accretion on fixed-wing aircraft and rotorcraft can be catastrophic if not mitigated. Most modern ice protection systems are active systems, which require electrical or mechanical power to remove accreted ice. Despite their proven capability to protect aircraft from ice accretion, these methods can reduce the aerodynamic efficiency of the vehicle and increase its weight, cost, and complexity. Scientists and engineers now seek passive, erosion-resistant materials and coatings with low ice adhesion strength. Ideally, such materials, when applied to vulnerable components of an aircraft, would cause any ice to shed off the surface under normal aerodynamic loading. To aid in the development of low-ice-adhesion-strength materials, the growth and structural behavior of impact ice in a wide range of atmospheric conditions must be characterized. Facilities such as the NASA Icing Research Tunnel (IRT), the Anti-Icing Materials International Laboratory (AMIL), and the Penn State Adverse Environment Research Testing Systems (AERTS) laboratory, to name a few, have spent decades investigating the relationship between ice adhesion strength, temperature, surface roughness, airspeed, and other parameters. The structural behavior of ice has been examined under pure shear, tension, and compression, and mixed-mode loading. However, one important loading consideration that has not been widely investigated on atmospheric ice is strain rate. Very few published ice adhesion studies report the strain rate applied to the ice samples. Several previous studies of laboratory-prepared ice in compression revealed that ice undergoes a ductile-to-brittle transition under high strain rate conditions, and that the adhesion strength is a power function of the strain rate. Other studies, in which lab-prepared ice was loaded in pure shear, reported similar trends. It is unclear whether the same behavior can be expected of dynamically-accreted atmospheric impact ice. Knowledge of the relationship between impact ice adhesion strength and strain rate is important because it can be used to design future ice protection systems, and it may dictate the appropriate course of action for a pilot flying through icing conditionsfor instance, whether a helicopter pilot should increase the rotor speed rapidly or slowly to induce shedding of the ice. NASA Glenn Research Center funded the design and construction of a new centrifuge-style ice adhesion test rig (AJ2) by the Penn State AERTS lab. The ice is accreted dynamically by spinning flat metal test coupons at high speed inside a simulated icing cloud environment, so the water droplet sizes and impact speed are representative of in-flight icing, without the need for a wind tunnel. The rig motor allows for user-defined acceleration rates, so the strain rate on the ice can be controlled. The adhesion strength of the ice is calculated from the voltage output of strain gauges mounted on the cantilever beams holding the test coupons. Unlike other small-scale adhesion test methods, AJ2 allows researchers to collect real-time adhesion data and control the testing environment without any direct interaction with the ice, thus preserving the fidelity of the data. As per NASA requirements, ballistic and structural analysis was performed on the rig to verify its safety. The design and analysis of the AJ2 rig is described in detail in this paper. Many experiments were performed at Penn State to investigate how the adhesion strength of impact ice related to the strain rate applied to it. Stainless steel test coupons of known surface roughness were tested in a range of environmental temperatures. The strain rates applied to the ice ranged between 5x10-7 and 5x10-5 s-1. It was discovered that a similar power function exists between strain rate and adhesion strength as found in the freezer-ice studies described in the literature. Despite scatter in the data, regression analysis determined the trends to be statistically significant. The data suggests that strain rate has a stronger effect on adhesion strength for smoother surfaces as opposed to rougher surfaces. The power 1/n for a coupon roughness of 64 nm (Sa) was double that of the 80-nm coupon; this was the case for both tested temperatures. Similarly, lower temperatures caused a higher power 1/n and coefficient c in the power function. The variation of the coefficient with temperature is consistent with Glens power law for the creep of glacier ice in compression. However, Glen did not observe a variation of the power with temperature. The value of n in the current study ranged from 2.5 for the smoothest sample at the coldest temperature, to 9.7 for the roughest sample at the warmest temperature. In most cases, n was within the range of previously-reported values in literature (1.5 to 6). These findings suggest that the creep behavior of atmospheric impact ice in shear is similarbut not identicalto freezer ice in compression. The proven strain rate testing capabilities of the AJ2 rig will aid icing research efforts by yielding baseline prediction data for future design of ice-resistant materials.


Ice Adhesion Strength Modeling Based on Surface Morphology Variations

Ice Adhesion Strength Modeling Based on Surface Morphology Variations
Author: Taylor Knuth
Publisher:
Total Pages:
Release: 2015
Genre:
ISBN:

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A physics-based analytical model to predict the adhesion shear strength of impact ice on varying surface morphologies was developed and validated experimentally. The model focuses on the surface morphology effects on ice adhesion strength. As super-cooled water droplets, having a typical median volume diameter ranging from 10 to 80 [mu]m, impact and freeze on the leading edges of aircraft, it is hypothesized that the small drops expand and clamp to surface discontinuities, contributing to the ice adhesion strength of the material. The derivation of a Newtonian mechanics model to calculate the forces required for the removal of ice that has expanded and clamped inside macro surface structures is presented. The model requires knowledge of the macro-scale (10-6 m) surface geometry. Newtonian mechanics accounted for the expansion and clamping of freezing ice including temperature dependent ice properties. The model is dependent on Young's modulus, the thermal coefficient of expansion of ice, and the coefficient of static friction between ice and the adhering substrate. All of these properties are dependent on the variation of temperature. The research validated the developed model experimentally. Firstly, the individual parameters as functions of temperature were obtained from literature review and experimental measurements. Previous research revealed the correlation with temperature of the Young's modulus and the thermal coefficient of expansion for ice. The relationship for the thermal coefficient of expansion found is valid for temperatures ranging between -193.15 and 6.85 °C (-315.67 and 44.33 °F). The Young's modulus temperature relationship was obtained from tests presented in the literature that used sea ice. Secondly, the static coefficient of friction is dependent on the surface interaction between the accreted ice and the surface material. Through bench top testing, it was determined that the coefficient of friction of ice is also dependent on temperature. The coefficient of friction was experimentally acquired for a mercaptan and amine blended epoxy (Great Planes 30 Minute Pro Two-Part) applied to an aluminum substrate. The coefficient of friction varied from 0.046 with a standard deviation of 0.015 at -5.8 °C (21.6 °F) to 0.190 with a standard deviation of 0.019 at -15.7 °C (3.7 °F), a change of 420%, and is dependent on loading conditions and the test environment.The final phase of the research was the experimental validation of the ice adhesion model through adhesion strength testing on the Adverse Environment Rotor Test Stand (AERTS). To conduct validation testing, controlled surfaces were created. The surfaces were coated with the same mercaptan and amine epoxy blend to create a surface that approached a Ra of zero. The actual surface roughness measured was a Ra of 0.01 [mu]m (3.94 x 10-7 in.). This pristine coating provided a baseline against other surface of the same coating that had controlled surface roughness. The epoxy surfaces were ablated using a laser at differing intensities to create surfaces with varying roughness depths. The laser etched the coatings at 0.35, 0.6, and 1.2 W, each with a respective surface roughness of 1.13, 1.95, and 5.11 Ra (4.45 x 10-5, 7.68 x 10-5, and 2.01 x 10-4 in.). All of these coatings were tested within the Federal Aviation Regulation Part 25 and Part 29 Appendix C icing envelope to recreate realistic environmental icing conditions. The pristine surface was had an adhesion strength of 4.11 psi (28.3 kPa) with a standard deviation of 0.75 psi (5.17 kPa) at -8 °C (17.6 °F) and 7.99 psi (55.1 kPa) with a standard deviation of 0.94 psi (6.48 kPa) at -16 °C (3.2 °F). While, for example, the coating with the most severe ablation (Ra of 5.11 [mu]m) was had an adhesion strength of 22.7 psi (156.8 kPa) with a standard deviation of 2.70 psi (18.62 kPa) at -8 °C and 42.4 psi (292.5 kPa) with a standard deviation of 3.45 psi (23.79 kPa) at -16 °C. These measured values were then compared to the model predictions. The maximum discrepancy between prediction and experimental results was 9% for the 25 experimental tests conducted using the 1.2 W ablation surface.


Ice Accretion and Icing Technology

Ice Accretion and Icing Technology
Author: Robert J Flemming
Publisher: SAE International
Total Pages: 122
Release: 2015-04-16
Genre: Technology & Engineering
ISBN: 0768081203

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The effects of inflight atmospheric icing can be devastating to aircraft. Universities and industry have been hard at work to respond to the challenge of maintaining flight safety in all weather conditions. Proposed changes in the regulations for operation in icing conditions are sure to keep this type of research and development at its highest level. This is especially true for the effects of ice crystals in the atmosphere, and for the threat associated with supercooled large drop (SLD) icing. This collection of ten SAE International technical papers brings together vital contributions to the subject. Icing on aircraft surfaces would not be a problem if a material were discovered that prevented the freezing and accretion of supercooled drops. Many options that appeared to have promising icephobic properties have had serious shortfalls in durability. This title addresses, among other topics, the measurement techniques and the drop physics that apply to icing, certification for flight through ice crystal clouds and in supercooled large drops, improvements in predictive techniques, scaling methods, test facilities and techniques, and rotorcraft icing.


Toward Polymer Coatings with Easy Ice Release

Toward Polymer Coatings with Easy Ice Release
Author: Chenyu Wang
Publisher:
Total Pages: 157
Release: 2014
Genre: Deicing chemicals
ISBN:

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Minimizing adhesion of ice has been the subject of extensive studies for applications such aircraft wings, wind turbine blades spacecraft, power transmission wires, while a growing interest concerns coatings for aerospace applications. The work described here describes progress for coatings and ice release test method development over the last few years. Major achievements include: (1) New Rigid Adherent-Resistant Elastomers (RARE), (2) A new Epoxied Cylinder (EC) adhesion test, (3) Validation of an ice release test, and (4) Study of ice adhesion strength on coating thickness for a PDM.S. elastomer. Rigid Adhesion-Resistance Elastomers (RARE) are comprised of 3F 1 terminated with triethoxysilane moieties and linear 3F polyurethane (U-3F). Hybrid compositions U-3F-x are designated by polyurethane weight percent "x". Interestingly, RARE coatings spontaneously "self-stratify" during coating deposition and cure. Cured RARE coatings are comprised of (1) a nanoscale surface layer with low work of adhesion, (2) a low modulus mesoscale and (3) a tough U-3F bulk, where "Mesoscale" is defined as a near surface region with a depth ~ 1000 nm. An EC adhesion test was developed to evaluate the fouling release characteristics of RARE. EC adhesion testing was devised by using the commercially available instrument, TA RSA-3. The TA RSA-3 is well suited for these tests as the 3.5 kg load cell facilitates accurate measurements. This test gives peak force (Ps) for EC removal. A striking compositional dependence was found for EC adhesion. A U-3F-50 hybrid coating had the lowest adhesion (Ps = 0.078 MPa) with good toughness (6.2 MPa). Bulk and surface characterization together with adhesion measurements established U-3F-x hybrid coatings, and U-3F-50 in particular, as new fluorous rigid adherent-resistant elastomers (RARE) that are tough, oil resistant, and optically transparent. Inspired by the Epoxied Cylinder (EC) adhesion test, a laboratory method for ice adhesion measurement with a commercially available instrument was established in the Wynne Laboratory. This is the first laboratory ice adhesion test that does not require a custom built apparatus. The temperature controlled chamber on TA RSA-3 is an enabling feature that is essential for the test. The method involves removal of an ice cylinder from a polymer coating with a probe and the determination of peak removal force (Ps). To validate the test method, the strength of ice adhesion was determined for a prototypical glassy polymer, poly(methyl methacrylate). The distance of the probe from the PMMA surface has been identified as a critical variable for Ps. The new test provides a readily available platform for investigating fundamental surface characteristics affecting ice adhesion. In addition to the ice release test, PMMA coatings were characterized using DSC, DCA and TM-AFM. This new laboratory ice release test was then employed to obtain the thickness dependence of ice adhesion for Sylgard 184, a filled polydimethylsiloxane elastomer. A correlation between ice adhesion and coating thickness (t) was found, that follows a relationship developed by Kendall over 40 years ago for removal of a rigid object from an elastomer. In particular, a nearly linear relationship between peak removal stress (Ps) and 1/t1/2 was found, with Ps decreasing from 550 kPa to 100 kPa with coating thickness increasing from 12[micro]m to 800[micro]m. While work of adhesion, which is related to surface free energy, is recognized as an important factor that can affect ice release, the results reported herein show that coating thickness can override this single parameter for elastomeric substrates. Base on the result, a general model is proposed for the removal of ice from low modulus elastomers (~10 MPa).


Ice Adhesion

Ice Adhesion
Author: K. L. Mittal
Publisher:
Total Pages: 675
Release: 2020
Genre: Ice mechanics
ISBN: 9781523137008

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Progress in Adhesion and Adhesives

Progress in Adhesion and Adhesives
Author: K. L. Mittal
Publisher: John Wiley & Sons
Total Pages: 515
Release: 2015-07-27
Genre: Technology & Engineering
ISBN: 1119162327

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This book is based on the 13 review articles written by subject experts and published in 2014 in the Journal Reviews of Adhesion and Adhesives. The rationale for publication of this book is that currently the RAA has limited circulation, so this book provides broad exposure and dissemination of the concise, critical, illuminating, and thought-provoking review articles. The subjects of the reviews fall into 4 general areas: 1. Polymer surface modification 2. Biomedical, pharmaceutical and dental fields 3. Adhesives and adhesive joints 4. General Adhesion Aspects The topics covered include: Adhesion of condensed bodies at microscale; imparting adhesion property to silicone material; functionally graded adhesively bonded joints; synthetic adhesives for wood panels; adhesion theories in wood adhesive bonding; adhesion and surface issues in biocomposites and bionanocomposites; adhesion phenomena in pharmaceutical products and applications of AFM; cyanoacrylate adhesives in surgical applications; ways to generate monosort functionalized polyolefin surfaces; nano-enhanced adhesives; bonding dissimilar materials in dentistry; flame treatment of polymeric materials—relevance to adhesion; and mucoadhesive polymers for enhancing retention of ocular drug delivery.


Progress in Adhesion and Adhesives, Volume 6

Progress in Adhesion and Adhesives, Volume 6
Author: K. L. Mittal
Publisher: John Wiley & Sons
Total Pages: 914
Release: 2021-08-24
Genre: Technology & Engineering
ISBN: 111984665X

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With the voluminous research being published, it is difficult, if not impossible, to stay abreast of current developments in a given area. The review articles in this book consolidate information to provide an alternative way to follow the latest research activity and developments in adhesion science and adhesives. With the ever-increasing amount of research being published, it is a Herculean task to be fully conversant with the latest research developments in any field, and the arena of adhesion and adhesives is no exception. Thus, topical review articles provide an alternate and very efficient way to stay abreast of the state-of-the-art in many subjects representing the field of adhesion science and adhesives. The 19 chapters in this Volume 6 follow the same order as the review articles originally published in RAA in the year 2020 and up to June 2021. The subjects of these 19 chapters fall in the following areas: Adhesives and adhesive joints Contact angle Reinforced polymer composites Bioadhesives Icephobic coatings Adhesives based on natural resources Polymer surface modification Superhydrophobic surfaces The topics covered include: hot-melt adhesives; adhesively-bonded spar-wingskin joints; contact angle hysteresis; fiber/matrix adhesion in reinforced thermoplastic composites; bioadhesives in biomedical applications; mucoadhesive pellets for drug delivery applications; bio-inspired icephobic coatings; wood adhesives based on natural resources; adhesion in biocomposites; vacuum UV surface photo-oxidation of polymers and other materials; vitrimers and their relevance to adhesives; superhydrophobic surfaces by microtexturing; structural acrylic adhesives; mechanically durable water-repellent surfaces; mussel-inspired underwater adhesives; and cold atmospheric pressure plasma technology for modifying polymers. Audience This book will be valuable and useful to researchers and technologists in materials science, nanotechnology, physics, surface and colloid chemistry in multiple disciplines in academia, industry, various research institutes and other organizations.