Hydrolysis And Substitution Reactions Of Some Platinum Iv Complexes PDF Download

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On Being Well-coordinated

On Being Well-coordinated
Author: Fred Basolo
Publisher: World Scientific
Total Pages: 654
Release: 2003
Genre: Science
ISBN: 9812380876

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This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.


SUBSTITUTION & REDOX REACTIONS

SUBSTITUTION & REDOX REACTIONS
Author: 羅政藩
Publisher: Open Dissertation Press
Total Pages: 192
Release: 2017-01-27
Genre: Science
ISBN: 9781374755567

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This dissertation, "Substitution and Redox Reactions of Some Binuclear Platinum (II) and Platinum (III) Complexes" by 羅政藩, Chang-fan, Lo, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123190 Subjects: Platinum Substitution reactions Oxidation-reduction reaction


Synthesis, Properties and Reaction Mechanisms of Platinum Metal Compounds

Synthesis, Properties and Reaction Mechanisms of Platinum Metal Compounds
Author: Fred Basolo
Publisher:
Total Pages: 6
Release: 1963
Genre:
ISBN:

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Research on the chemistry of metals called noble or platinum metals is reviewed: (1) New Linkage Isomers. Making use of studies on the mechanism of formation of the Co(III) linkage isomers (NH3)5Co-ONO (2) (nitrito) and (NH3)5Co NO2 (2) (nitro), analogous isomers for Rh(III), Ir(III) and Pt(IV) were synthesized and studied. (2) Chloroamminerhodium(III) Complexes. Several new complexes of Rh(III) were prepared and kinet ic study made of their acid and base hydrolysis. (3) Carboxylatopentamminemetal(III) Complexes. Compounds of the type M(NH3)5(RCOO) (2), where MCo(III), Rh(III), Ir(III) and RCOO( - ) CH3COO( - ), (CH3)3CCOO( - ), CF3COO( - ), where syn thesized. Kinetic studies show that the rate of hydrolysis of these complexes is acid catalyzed. (4) (Acidoamminegold(III) Complexes. Solution chemistry of the new compounds Au(dien)X X (where dien NH2CH2CH2NHCH2CH2NH2 and X Cl( - ), Br( - ), I( - )) was investigated in some detail. (Author).


Proceedings. Chemistry Section

Proceedings. Chemistry Section
Author: Akademii͡a nauk SSSR.
Publisher:
Total Pages: 750
Release: 1960
Genre: Chemistry
ISBN:

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Advances in Inorganic Chemistry and Radiochemistry

Advances in Inorganic Chemistry and Radiochemistry
Author:
Publisher: Academic Press
Total Pages: 475
Release: 1961-01-01
Genre: Science
ISBN: 0080578527

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Advances in Inorganic Chemistry and Radiochemistry