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Relative Susceptibility of Titanium Alloys to Hot-salt Stress-corrosion

Relative Susceptibility of Titanium Alloys to Hot-salt Stress-corrosion
Author: Hugh R. Gray
Publisher:
Total Pages: 68
Release: 1971
Genre: Corrosion and anti-corrosives
ISBN:

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Susceptibility of titanium alloys to hot-salt stress-corrosion cracking increased as follows: Ti-2Al-11Sn-5Zr-0.2Si(679), Ti-6Al-2Sn-4Zr-2Mo(6242), Ti-6Al-4V(64), Ti-6Al-4V-3Co(643), Ti-8Al-1Mo-1V(811), and Ti-13V-11Cr-3A1(13-11-3). The Ti-5Al-6Sn-2Zr-1Mo-0.25Si(5621S) alloy was both the least and most susceptible depending on heat treatment. Such rankings can be drastically altered by heat-to-heat and processing variations. Residual compressive stresses and cyclic exposures also reduce susceptibility to stress-corrosion. Simulated turbine-engine compressor environmental variables such as air velocity, pressure, dewpoint, salt concentration, and salt deposition temperature have only minor effects. Detection of substantial concentrations of hydrogen in all corroded alloys confirmed the existence of a hydrogen embrittlement mechanism.--P. [i].


An Electrochemical Model for Hot-salt Stress-corrosion of Titanium Alloys

An Electrochemical Model for Hot-salt Stress-corrosion of Titanium Alloys
Author: Marvin Garfinkle
Publisher:
Total Pages: 44
Release: 1972
Genre: Metals
ISBN:

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An electrochemical model of hot-salt stress-corrosion cracking of titanium alloys is proposed based on an oxygen-concentration cell. Hydrogen embrittlement is proposed as the direct cause of cracking, the hydrogen being generated as the results of the hydrolysis of complex halides formed at the shielded anode of the electrochemical cell. The model found to be consistent with the diverse observations made both in this study and by many investigators in this field.