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| Author | : John C. Chadwick |
| Publisher | : John Wiley & Sons |
| Total Pages | : 592 |
| Release | : 2011-06-09 |
| Genre | : Science |
| ISBN | : 3527636005 |
Download Homogeneous Catalysts Book in PDF, ePub and Kindle
This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.
| Author | : Sumit Bhaduri |
| Publisher | : John Wiley & Sons |
| Total Pages | : 291 |
| Release | : 2014-09-08 |
| Genre | : Science |
| ISBN | : 1118872479 |
Download Homogeneous Catalysis Book in PDF, ePub and Kindle
Over the last decade, the area of homogeneous catalysis with transition metal has grown in great scientific interest and technological promise, with research in this area earning three Nobel Prizes and filing thousands of patents relating to metallocene and non-metallocene single site catalysts, asymmetric catalysis, carbon-carbon bond forming metathesis and cross coupling reactions. This text explains these new developments in a unified, cogent, and comprehensible manner while also detailing earlier discoveries and the fundamentals of homogeneous catalysis. Serving as a self-study guide for students and all chemists seeking to gain entry into this field, it can also be used by experienced researchers from both academia and industry for referring to leading state of the art review articles and patents, and also as a quick self-study manual in an area that is outside their immediate expertise. The book features: • Topics including renewable feed stocks (biofuel, glycerol), carbon dioxide based processes (polycarbonates), fluorous solvents, ionic liquid, hydroformylation, polymerization, oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (case studies), and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues • Extensive references to cutting edge research with application potential and leading patents • Tables and illustrations to help explain difficult concepts
| Author | : Piet W.N.M. van Leeuwen |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 413 |
| Release | : 2006-08-02 |
| Genre | : Science |
| ISBN | : 1402020007 |
Download Homogeneous Catalysis Book in PDF, ePub and Kindle
No available as softcover No other book available that gives insight into so many reactions of importance, while the field of homogeneous catalysis is becoming more and more important to organic chemists, industrial chemists, and academia. Gives real insight in the many new and old reactions of importance, based on the author's extensive experience in both teaching and industrial practice. Provide background to chemists trained in a different discipline and graduate and masters students who take catalysis as a main or secondary topic.
| Author | : Pierluigi Barbaro |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 470 |
| Release | : 2010-09-02 |
| Genre | : Science |
| ISBN | : 9048136962 |
Download Heterogenized Homogeneous Catalysts for Fine Chemicals Production Book in PDF, ePub and Kindle
Table 1 E factors (tonnes of waste generated per tonne of product manufactured [7] Industry segment Annual product tonnage E factor 6 8 Oil refining 10 –10 Approx. 0. 1 4 6 Bulk chemicals 10 –10
| Author | : Feliu Maseras |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 373 |
| Release | : 2006-04-11 |
| Genre | : Science |
| ISBN | : 0306477181 |
Download Computational Modeling of Homogeneous Catalysis Book in PDF, ePub and Kindle
Recent results on a wide array of catalytic processes are collected in this volume. The book illustrates the importance of computational modelling in homogeneous catalysis by providing up-to-date reviews of its application to a variety of reactions of industrial interest.
| Author | : S. Ted Oyama |
| Publisher | : Elsevier |
| Total Pages | : 524 |
| Release | : 2011-10-13 |
| Genre | : Technology & Engineering |
| ISBN | : 0080558011 |
Download Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis Book in PDF, ePub and Kindle
The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. Comprehensive listing of epoxide products Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts Analysis of the general strengths and weaknesses of varied catalytic systems Detailed description of the mechanisms of reaction for classical and emerging catalysts
| Author | : Can Li |
| Publisher | : John Wiley & Sons |
| Total Pages | : 860 |
| Release | : 2014-04-03 |
| Genre | : Technology & Engineering |
| ISBN | : 3527675922 |
Download Bridging Heterogeneous and Homogeneous Catalysis Book in PDF, ePub and Kindle
There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions. This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis. Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations. With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.
| Author | : Gheorghe Duca |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 484 |
| Release | : 2012-06-15 |
| Genre | : Science |
| ISBN | : 364224629X |
Download Homogeneous Catalysis with Metal Complexes Book in PDF, ePub and Kindle
The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.
| Author | : R. Ugo |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 350 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 9400963637 |
Download Aspects of Homogeneous Catalysis Book in PDF, ePub and Kindle
1. INTRODUCTION Although quite spectacular results have been obtained in the last few decades in the field of homogeneous transition metal catalyzed transformations of olefins and alkynes [1], reactions which could lead to heterocycles have been partly neglected. An obvious reason for this is that substrates containing heteroatoms such as N, 0 or S could coordinate the metal and suppress the catalytic activity. Nevertheless, some interesting early examples of transition-metal-catalyzed syntheses of heterocyclic compounds have been reported and these have been reviewed by C. W. Bird [2] . More recently the incorporation of CO , which enables esters and lactones 2 to be synthesized from olefinic starting materials, has begun to attract attention (see, for example, ref. [3]). The dominant role of palladium as the catalyst for the formation of O-containing heterocycles has been suggested to be associated with the relatively low strength of the Pd-O bond. Among the first examples of a nitrogen-containing heterocycle to be formed by homogeneous catalysis is the triazine shown in Equation 1 which is the product of the trimerization of benzonitrile in the presence of iron penta carbonyl or Raney nickel [4] .
| Author | : Radovan Sebesta |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 301 |
| Release | : 2011-11-02 |
| Genre | : Science |
| ISBN | : 1849733422 |
Download Enantioselective Homogeneous Supported Catalysis Book in PDF, ePub and Kindle
Immobilization of chiral catalysts is an important tool for improving overall efficiency of catalytic processes. However, heterogeneous catalysts often suffer from decreased activities and supported but still homogeneous catalysts can help overcome this issue. This book covers the most important concepts of homogeneous supported catalysis with an emphasis on enantioselective processes. It describes the state-of-the-art and latest developments in each area whilst critically evaluating the strengths and weaknesses of this important method. The book encompasses ionically-tagged catalysts, supported organocatalysts, supported ionic liquid phases, catalysis using soluble polymers, catalytic dendrimers, fluorous catalysts, water soluble catalysts and non-covalent immobilization methods. Potential developments and ideas for the future are also highlighted. There is a growing demand for effective and recyclable catalysts so this book, covering all the important methods in the field of supported homogeneous catalysis, will appeal to many researchers in academia and industry.
