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Principles of High Resolution NMR in Solids

Principles of High Resolution NMR in Solids
Author: M. Mehring
Publisher: Springer Science & Business Media
Total Pages: 352
Release: 2012-12-06
Genre: Science
ISBN: 3642687563

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The field of Nuclear Magnetic Resonance (NMR) has developed at a fascinating pace during the last decade. It always has been an extremely valuable tool to the organic chemist by supplying molecular "finger print" spectra at the atomic level. Unfortunately the high resolution achievable in liquid solutions could not be obtained in solids and physicists and physical chemists had to live with unresolved lines open to a wealth of curve fitting procedures and a vast amount of speculations. High resolution NMR in solids seemed to be a paradoxon. Broad structure less lines are usually encountered when dealing with NMR in solids. Only with the recent advent of mUltiple pulse, magic angle, cross-polarization, two-dimen sional and multiple-quantum spectroscopy and other techniques during the last decade it became possible to resolve finer details of nuclear spin interactions in solids. I have felt that graduate students, researchers and others beginning to get involved with these techniques needed a book which treats the principles, theo retical foundations and applications of these rather sophisticated experimental techniques. Therefore I wrote a monograph on the subject in 1976. Very soon new ideas led to the developement of "two-dimensional spectroscopy" and "multiple-quantum spectroscopy", topics which were not covered in the first edition of my book. Moreover an exponential growth of literature appeared in this area of research leaving the beginner in an awkward situation of tracing back from a current article to the roots of the experiment.


High-resolution NMR Techniques in Organic Chemistry

High-resolution NMR Techniques in Organic Chemistry
Author: T. Claridge
Publisher: Elsevier
Total Pages: 408
Release: 1999-12-24
Genre: Science
ISBN: 9780080427997

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From the initial observation of proton magnetic resonance in water and in paraffin, the discipline of nuclear magnetic resonance has seen unparalleled growth as an analytical method. Modern NMR spectroscopy is a highly developed, yet still evolving, subject which finds application in chemistry, biology, medicine, materials science and geology. In this book, emphasis is on the more recently developed methods of solution-state NMR applicable to chemical research, which are chosen for their wide applicability and robustness. These have, in many cases, already become established techniques in NMR laboratories, in both academic and industrial establishments. A considerable amount of information and guidance is given on the implementation and execution of the techniques described in this book.


Structure of High-Resolution NMR Spectra

Structure of High-Resolution NMR Spectra
Author: P.L. Corio
Publisher: Elsevier
Total Pages: 561
Release: 2012-12-02
Genre: Science
ISBN: 032314599X

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Structure of High-Resolution NMR Spectra provides the principles, theories, and mathematical and physical concepts of high-resolution nuclear magnetic resonance spectra. The book presents the elementary theory of magnetic resonance; the quantum mechanical theory of angular momentum; the general theory of steady state spectra; and multiple quantum transitions, double resonance and spin echo experiments. Physicists, chemists, and researchers will find the book a valuable reference text.


Nuclear Magnetic Resonance Spectroscopy

Nuclear Magnetic Resonance Spectroscopy
Author: Frank A. Bovey
Publisher: Elsevier
Total Pages: 668
Release: 1988-11-01
Genre: Science
ISBN: 0080916996

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Nuclear Magnetic Resonance Spectroscopy, Second Edition focuses on two-dimensional nuclear magnetic resonance (NMR) spectroscopy, high resolution NMR of solids, water suppression, multiple quantum spectroscopy, and NMR imaging. The selection first takes a look at the fundamental principles and experimental methods. Discussions focus on the NMR phenomenon, dipolar broadening and spin-spin relaxation, nuclear electric quadrupole relaxation, saturation, magnetic shielding and chemical shift, magnetic field, transitions between the nuclear energy levels, and resolution and sensitivity considerations. The manuscript then ponders on chemical shift, coupling of nuclear spins, and nuclear relaxation and chemical rate processes. Topics include spin lattice relaxation, spin-spin relaxation, spin decoupling and associated techniques, and description and analysis of spin systems. The text examines two-dimensional NMR spectroscopy, macromolecules, and NMR of solids, including magic angle spinning, cross polarization, proton dipolar broadening, biopolymers, and chain motion in macromolecules. The selection is a valuable source of data for readers interested in nuclear magnetic resonance spectroscopy.


High Resolution Nuclear Magnetic Resonance Spectroscopy

High Resolution Nuclear Magnetic Resonance Spectroscopy
Author: J. W. Emsley
Publisher: Elsevier
Total Pages: 543
Release: 2013-10-22
Genre: Science
ISBN: 1483184080

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High Resolution Nuclear Magnetic Resonance Spectroscopy, Volume 2 provides a comprehensive coverage of the theories and methods for analysis of high resolution spectra. The title also presents a discourse on other variables that affect the spectra. The text first details the correlations of 1H resonance spectral parameters with molecular structure, and then proceeds to tackling the 19F nuclear magnetic resonance studies. Next, the selection deals with the NMR spectra of nuclei other than hydrogen fluoride. The text also provides data sets, such as nuclear properties, T-values, and chemical shifts. The book will be of great use to scientists who utilize nuclear magnetic resonance in their work.


High-Resolution NMR Techniques in Organic Chemistry

High-Resolution NMR Techniques in Organic Chemistry
Author: Timothy D.W. Claridge
Publisher: Newnes
Total Pages: 400
Release: 2009
Genre: Mathematics
ISBN: 0080546285

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"Nuclear Magnetic Resonance (NMR) Spectroscopy remains the foremost analytical technique for the structure elucidation of organic molecules and an indispensable tool for the synthetic, medicinal and natural product chemist. New techniques continue to emerge and the application of NMR methods continues to expand. High-Resolution NMR Techniques in Organic Chemistry is designed for use in academic and industrial NMR facilities, as a text for graduate-level NMR courses, and as an accessible reference for the chemist's or spectroscopist's desk."--BOOK JACKET.