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High Resolution Electronic Spectroscopy of Small Molecules

High Resolution Electronic Spectroscopy of Small Molecules
Author: Geoffrey Duxbury
Publisher: CRC Press
Total Pages: 310
Release: 2017-08-02
Genre: Science
ISBN: 1482245612

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Over recent years electronic spectroscopy has developed significantly, with key applications in atmospheric chemistry, astrophysics and astrochemistry. High Resolution Electronic Spectroscopy of Small Molecules explores both theoretical and experimental approaches to understanding the electronic spectra of small molecules, and explains how this information translates to practice. Professors Geoffrey Duxbury and Alexander Alijah present the links between spectroscopy and photochemistry, and discuss theoretical treatments of the interaction between different electronic states. They provide a thorough discussion of experimental techniques, and explore practical applications. This book will be an indispensable reference for graduate students and researchers in physics and chemistry working on theoretical and practical aspects of electronic spectra, as well as atmospheric scientists, photochemists, kineticists and professional spectroscopists.


High-Resolution Spectroscopy of Small Molecules in the Gaseous State

High-Resolution Spectroscopy of Small Molecules in the Gaseous State
Author: G. Wilse Robinson
Publisher:
Total Pages: 8
Release: 1970
Genre:
ISBN:

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A summary of the author's research is given. It includes the analysis of the formaldehyde singlet-triplet spectrum, techniques for the study of very weak transitions in gas phase molecules, a moderately well-resolved vibronic spectrum of benzene near 2000 Angstroms, and the affect of intermolecular interactions on the measured intensities of the red and infrared electronic transitions of 02.


High-Resolution Spectroscopy of Transient Molecules

High-Resolution Spectroscopy of Transient Molecules
Author: Eizi Hirota
Publisher: Springer
Total Pages: 236
Release: 1985-05-01
Genre: Science
ISBN: 9783540153023

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It is a great challenge in chemistry to clarify every detail of reaction processes. In older days chemists mixed starting materials in a flask and took the resul tants out of it after a while, leaving all the intermediate steps uncleared as a sort of black box. One had to be content with only changing temperature and pressure to accelerate or decelerate chemical reactions, and there was almost no hope of initiating new reactions. However, a number of new techniques and new methods have been introduced and have provided us with a clue to the examination of the black box of chemical reaction. Flash photolysis, which was invented in the 1950s, is such an example; this method has been combined with high-resolution electronic spectroscopy with photographic recording of the spectra to provide a large amount of precise and detailed data on transient molecules which occur as intermediates during the course of chemical reac tions. In 1960 a fundamentally new light source was devised, i. e. , the laser. When the present author and coworkers started high-resolution spectroscopic stud ies of transient molecules at a new research institute, the Institute for Molecu lar Science in Okazaki in 1975, the time was right to exploit this new light source and its microwave precursor in order to shed light on the black box.


Handbook of High-resolution Spectroscopy

Handbook of High-resolution Spectroscopy
Author: Martin Quack
Publisher: John Wiley & Sons
Total Pages: 2236
Release: 2011-09-26
Genre: Science
ISBN: 0470066539

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The field of High-Resolution Spectroscopy has been considerably extended and even redefined in some areas. Combining the knowledge of spectroscopy, laser technology, chemical computation, and experiments, Handbook of High-Resolution Spectroscopy provides a comprehensive survey of the whole field as it presents itself today, with emphasis on the recent developments. This essential handbook for advanced research students, graduate students, and researchers takes a systematic approach through the range of wavelengths and includes the latest advances in experiment and theory that will help and guide future applications. The first comprehensive survey in high-resolution molecular spectroscopy for over 15 years Brings together the knowledge of spectroscopy, laser technology, chemical computation and experiments Brings the reader up-to-date with the many advances that have been made in recent times Takes the reader through the range of wavelengths, covering all possible techniques such as Microwave Spectroscopy, Infrared Spectroscopy, Raman Spectroscopy, VIS, UV and VUV Combines theoretical, computational and experimental aspects Has numerous applications in a wide range of scientific domains Edited by two leaders in this field Provides an overview of rotational, vibration, electronic and photoelectron spectroscopy Volume 1 - Introduction: Fundamentals of Molecular Spectroscopy Volume 2 - High-Resolution Molecular Spectroscopy: Methods and Results Volume 3 - Special Methods & Applications


High-Resolution Spectroscopy of Transient Molecules

High-Resolution Spectroscopy of Transient Molecules
Author: Eizi Hirota
Publisher: Springer
Total Pages: 0
Release: 2011-12-15
Genre: Science
ISBN: 9783642824791

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It is a great challenge in chemistry to clarify every detail of reaction processes. In older days chemists mixed starting materials in a flask and took the resul tants out of it after a while, leaving all the intermediate steps uncleared as a sort of black box. One had to be content with only changing temperature and pressure to accelerate or decelerate chemical reactions, and there was almost no hope of initiating new reactions. However, a number of new techniques and new methods have been introduced and have provided us with a clue to the examination of the black box of chemical reaction. Flash photolysis, which was invented in the 1950s, is such an example; this method has been combined with high-resolution electronic spectroscopy with photographic recording of the spectra to provide a large amount of precise and detailed data on transient molecules which occur as intermediates during the course of chemical reac tions. In 1960 a fundamentally new light source was devised, i. e. , the laser. When the present author and coworkers started high-resolution spectroscopic stud ies of transient molecules at a new research institute, the Institute for Molecu lar Science in Okazaki in 1975, the time was right to exploit this new light source and its microwave precursor in order to shed light on the black box.


Jet Spectroscopy and Molecular Dynamics

Jet Spectroscopy and Molecular Dynamics
Author: J.M. Hollas
Publisher: Springer Science & Business Media
Total Pages: 447
Release: 2012-12-06
Genre: Science
ISBN: 9401113149

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Recent years have seen an explosion in the volume of work carried out using supersonic jets of molecules following the discovery that the technique could provide information on structure and dynamics of a very high quality otherwise impossible to obtain. Written and edited by a first class team of authors, acknowledged world leaders in their subjects, this book describes applications in detail along with analysis of data recorded and background theory. Physical chemists and chemical physicists will find this unique book an essential concentrated source of information and reference.


High Resolution Vacuum Ultraviolet Spectroscopy of Small Molecules

High Resolution Vacuum Ultraviolet Spectroscopy of Small Molecules
Author: W. H. Parkinson
Publisher:
Total Pages: 6
Release: 1977
Genre:
ISBN:

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A 6.65 metre vacuum spectrograph has been installed and a wavelength resolution of 0.005 A attained. Absorption spectra of N2 below 1000 A have been rotationally analyzed, and homogeneous perturbations identified; rotational line broadening in certain bands indicates the presence of predissociation at about 105/cm above the N2D+N2D dissociation limit. The absorption spectra of binary rare gas mixtures have been photographed and interpreted in terms of transitions within van der Waals molecules, from their bound ground electronic states to bound or free excited electronic states near the first and second atomic resonance levels of xenon and krypton. (Author).