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Heterogeneous Gold Catalysts and Catalysis

Heterogeneous Gold Catalysts and Catalysis
Author: Zhen Ma
Publisher: Royal Society of Chemistry
Total Pages: 288
Release: 2014-09-10
Genre: Science
ISBN: 184973917X

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Once considered an inert element, gold has recently gained attention as a catalyst. With hundreds of papers being published each year, this book presents a comprehensive review of this rapidly-evolving field, with contributions by leading experts across the globe. Going through the chapters citing the primary literature, the reader will gain a thorough background to the use of gold in catalysis, as well as the latest methods for the preparation of gold catalysts. Other chapters demonstrate the characterisation and modelling of gold-catalysed reactions, with consideration given to both the fundamentals and commercial applications of this emerging group of catalysts.Written to be accessible by postgraduates and newcomers to the field, this book will also benefit experienced researchers and therefore be an essential reference in the laboratory.


Catalysis By Gold

Catalysis By Gold
Author: Geoffrey C Bond
Publisher: World Scientific
Total Pages: 383
Release: 2006-08-15
Genre: Science
ISBN: 1908979852

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Gold has traditionally been regarded as inactive as a catalytic metal. However, the advent of nanoparticulate gold on high surface area oxide supports has demonstrated its high catalytic activity in many chemical reactions. Gold is active as a heterogeneous catalyst in both gas and liquid phases, and complexes catalyse reactions homogeneously in solution. Many of the reactions being studied will lead to new application areas for catalysis by gold in pollution control, chemical processing, sensors and fuel cell technology. This book describes the properties of gold, the methods for preparing gold catalysts and ways to characterise and use them effectively in reactions. The reaction mechanisms and reasons for the high activities are discussed and the applications for gold catalysis considered./a


New and Future Developments in Catalysis

New and Future Developments in Catalysis
Author: Ana Primo
Publisher: Elsevier Inc. Chapters
Total Pages: 45
Release: 2013-07-13
Genre: Science
ISBN: 0128081678

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Gold Catalysis

Gold Catalysis
Author: Laura Prati
Publisher: CRC Press
Total Pages: 521
Release: 2016-01-05
Genre: Science
ISBN: 9814669296

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Since the first report on alcohol oxidation in 1998, many studies have highlighted some peculiarity of gold with respect to other metals. Some analogies have been found between gas and liquid phases, but the big challenge to operate in a condensed phase lies in the role of the solvent in tuning the reactant-catalyst contact. Liquid-phase oxidation


Heterogeneous Catalysis at Nanoscale for Energy Applications

Heterogeneous Catalysis at Nanoscale for Energy Applications
Author: Franklin Tao
Publisher: John Wiley & Sons
Total Pages: 358
Release: 2015-02-09
Genre: Science
ISBN: 1118843525

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This book presents both the fundamentals concepts and latest achievements of a field that is growing in importance since it represents a possible solution for global energy problems. It focuses on an atomic-level understanding of heterogeneous catalysis involved in important energy conversion processes. It presents a concise picture for the entire area of heterogeneous catalysis with vision at the atomic- and nano- scales, from synthesis, ex-situ and in-situ characterization, catalytic activity and selectivity, to mechanistic understanding based on experimental exploration and theoretical simulation. The book: Addresses heterogeneous catalysis, one of the crucial technologies employed within the chemical and energy industries Presents the recent advances in the synthesis and characterization of nanocatalysts as well as a mechanistic understanding of catalysis at atomic level for important processes of energy conversion Provides a foundation for the potential design of revolutionarily new technical catalysts and thus the further development of efficient technologies for the global energy economy Includes both theoretical studies and experimental exploration Is useful as both a textbook for graduate and undergraduate students and a reference book for scientists and engineers in chemistry, materials science, and chemical engineering


Heterogeneous Catalysis

Heterogeneous Catalysis
Author: Georgiĭ Konstantinovich Boreskov
Publisher: Nova Publishers
Total Pages: 254
Release: 2003
Genre: Science
ISBN: 9781590338643

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Table of contents


Bridging Heterogeneous and Homogeneous Catalysis

Bridging Heterogeneous and Homogeneous Catalysis
Author: Can Li
Publisher: John Wiley & Sons
Total Pages: 860
Release: 2014-04-03
Genre: Technology & Engineering
ISBN: 3527675922

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There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions. This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis. Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations. With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.


Principles and Practice of Heterogeneous Catalysis

Principles and Practice of Heterogeneous Catalysis
Author: John Meurig Thomas
Publisher: John Wiley & Sons
Total Pages: 768
Release: 2015-02-09
Genre: Science
ISBN: 352731458X

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This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved.


Gold Catalysis: An Homogeneous Approach

Gold Catalysis: An Homogeneous Approach
Author: Veronique Michelet
Publisher: World Scientific
Total Pages: 564
Release: 2014-06-20
Genre: Science
ISBN: 1783265558

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Research on designing new catalytic systems has been one of the most important fields in modern organic chemistry. One reason for this is the predominant contribution of catalysis to the concepts of atom economy and green chemistry in the 21st century. Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Teles, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. This book presents the major advances in homogeneous catalysis, emphasizing the methodologies that create carbon-carbon and carbon-heteroatom bonds, the applications that create diversity and synthesize natural products, and the recent advances and challenges in asymmetric catalysis and computational research.It provides readers with in-depth information about homogeneous gold-catalyzed reactions and presents several explanations for the scientific design of a catalyst. Readers will be able to understand the entire gold area and find solutions to problems in catalysis.Gold Catalysis — An Homogeneous Approach is part of the Catalytic Science Series and features prominent authors who are experts in their respective fields.